GB966000A - Process for the separation of a mixture in the liquid phase using a solid selective adsorbent - Google Patents
Process for the separation of a mixture in the liquid phase using a solid selective adsorbentInfo
- Publication number
- GB966000A GB966000A GB10685/63A GB1068563A GB966000A GB 966000 A GB966000 A GB 966000A GB 10685/63 A GB10685/63 A GB 10685/63A GB 1068563 A GB1068563 A GB 1068563A GB 966000 A GB966000 A GB 966000A
- Authority
- GB
- United Kingdom
- Prior art keywords
- line
- mixture
- slurry
- desorbent
- withdrawn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/06—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/10—Selective adsorption, e.g. chromatography characterised by constructional or operational features
- B01D15/18—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns
- B01D15/1807—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns using counter-currents, e.g. fluidised beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
- B01J47/10—Ion-exchange processes in general; Apparatus therefor with moving ion-exchange material; with ion-exchange material in suspension or in fluidised-bed form
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
- C01B32/306—Active carbon with molecular sieve properties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2215/00—Separating processes involving the treatment of liquids with adsorbents
- B01D2215/02—Separating processes involving the treatment of liquids with adsorbents with moving adsorbents
- B01D2215/021—Physically moving or fluidising the adsorbent beads or particles or slurry, excluding the movement of the entire columns
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A slurry of silica gel activated carbon or ion-exchanger, suspended in a carrying material, such as a non-aromatic hydrocarbon mixture, e.g. a paraffinic mixture, is introduced by means of a line 21 into the top of an adsorption rotating disc contacting apparatus 22. A feed mixture containing an impurity or other more readily adsorbed material is introduced into the lower portion of the apparatus 22 through a line 23 and contacts the descending adsorbent in a countercurrent manner. Since there exists a concentration gradient in the apparatus 22, the separated or purified mixture, essentially free from the impurity or other material and containing some carrying material can be withdrawn from the apparatus 22 as a side stream by means of a line 24, viz. at an optimum point in the apparatus 22 where the concentrations of more readily adsorbed components and of carrying liquid are at a minimum. The slurry of adsorbent with impurity or other material adsorbed therein is withdrawn from the bottom of the apparatus 22 by means of a line 25. This slurry will also contain some of the carrying material and a minor amount of the original mixture. The majority of the slurry-carrying material passes overhead and out of the apparatus 22 by means of a line 26 and is introduced as a desorbent into the bottom of a desorption rotating disc contacting apparatus 27. The slurry withdrawn from the apparatus 22 is introduced into the top of the apparatus 27 by means of a line 25. The rate of flow of desorbent introduced into the lower section of the apparatus 27 is so adjusted that there is essentially complete desorption of more readily adsorbed components from the adsorbent. The adsorbent slurry now free from these components and consisting essentially of the adsorbent and the desorbent (although it may contain some of the original mixture withdrawn from the apparatus 22 by means of the line 25) is then recycled to the adsorption <PICT:0966000/C1/1> apparatus 22 by means of the line 21. The overhead stream withdrawn from the apparatus 27 by means of a line 2 consists essentially of the impurity or other more readily adsorbed components and some desorbent and may also contain a minor amount of the original mixture. The desorbent may be removed from the more readily adsorbed components, e.g. by means of distillation (not shown). Fig. 2 of the drawing (not shown) is a schematic diagram of a further embodiment of the invention wherein the slurry-carrying desorbent material is withdrawn from the adsorption rotating disc contacting apparatus zone not separately from, but along with the purified mixture. Specification 659,241 is referred to.ALSO:<PICT:0966000/C4-C5/1> A slurry of adsorbent, such as silica gel, suspended in a carrying material, such as a non-aromatic hydrocarbon mixture, e.g. a paraffinic mixture, is introduced by means of a line 21 into the top of an adsorption rotating disc contacting apparatus 22. A feed mixture, such as a material to be subjected to an isomerization treatment, containing an impurity or other more readily adsorbed material, e.g. one or more aromatics, such as benzene, is introduced into the lower portion of the apparatus 22 through a line 23 and contacts the descending adsorbent in a countercurrent manner. Since there exists a concentration gradient in the apparatus 22, the separated or purified mixture, essentially free from the impurity or other material and containing some carrying material can be withdrawn from the apparatus 22 as a side stream by means of a line 24, viz. at an optimum point in the apparatus 22 where the concentrations of more readily adsorbed components and of carrying liquid are at a minimum. The slurry of adsorbent with impurity or other material adsorbed therein is withdrawn from the bottom of the apparatus 22 by means of a line 25. This slurry will also contain some of the carrying material and a minor amount of the original mixture. The majority of the slurry-carrying material passes overhead and out of the apparatus 22 by means of a line 26 and is introduced as a desorbent into the bottom of a desorption rotating disc contacting apparatus 27. The slurry withdrawn from the apparatus 22 is introduced into the top of the apparatus 27 by means of a line 25. The rate of flow of desorbent introduced into the lower section of the apparatus 27 is so adjusted that there is essentially complete desorption of more readily adsorbed components from the adsorbent. The adsorbent slurry now free from these components and consisting essentially of the adsorbent and the desorbent (although it may contain some of the original mixture withdrawn from the apparatus 22 by means of the line 25) is then recycled to the adsorption apparatus 22 by means of the line 21. The overhead stream withdrawn from the apparatus 27 by means of a line 2 consists essentially of the impurity or other more readily adsorbed components and some desorbent and may also contain a minor amount of the original mixture. The desorbent may be removed from the more readily adsorbed components, e.g. by means of distillation (not shown). Fig. 2 of the drawing is a schematic diagram of a further embodiment of the invention wherein the slurry-carrying desorbent material is withdrawn from the adsorption rotating disc contacting apparatus zone not separately from, but along with the purified mixture. The technique may be applied to ion-exchange molecular sieve separation and is particularly suitable for the separation of hydrocarbon mixtures, e.g. petroleum oils and fractions thereof. It further is especially advantageous for the separation of aromatic hydrocarbons, particularly benzene, from mixtures containing them, e.g. as an impurity. In this case, use is preferably made of an at least substantially paraffinic desorbent; "paraffin" is here meant to include not only alkanes, but also cycloparaffins or naphthenes. Among the various petroleum materials which can advantageously be treated according to the invention are, e.g., kerosene distillates (which may be dearomatized and desulphurized to produce a material of superior quality), gasolines (which may also be desulphurized and furthermore partially deparaffinized to produce a gasoline of higher octane number) diesel oils (which may be dearomatized to produce a product with high octane number), lubricating oils (which may be dearomatized and deasphaltized to give an oil of high quality); furthermore, narrow boiling aromatic, paraffinic, or elefinic-paraffinic fractions may be separated by the present method in order to produce pure aromatic, paraffinic, and/or olefinic compounds. It is also adaptable to the separation of a, normally gaseous, butene-butadiene liquid mixture by slightly increasing the operation pressures, so that the mixture becomes liquid. Also, a normally solid naphthalene fraction may be separated according to the invention by conducting the adsorption step at a moderately elevated temperature so as to melt the naphthalene material. Benzene may be removed from a mixture of C6 hydrocarbons containing contaminating amounts thereof so that the Friedel-Crafts type catalysts may be used in isomerization processes. Activated carbon is capable of selectively absorbing non-plar compounds, for example hydrocarbons, from polar compounds such as alcohols and ketones. Specification 659,241 is referred to.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US18045162A | 1962-03-19 | 1962-03-19 | |
US203051A US3376356A (en) | 1962-06-18 | 1962-06-18 | Sorption process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB966000A true GB966000A (en) | 1964-08-06 |
Family
ID=26876329
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB10685/63A Expired GB966000A (en) | 1962-03-19 | 1963-03-18 | Process for the separation of a mixture in the liquid phase using a solid selective adsorbent |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE629719A (en) |
DE (1) | DE1468627A1 (en) |
FR (1) | FR1353765A (en) |
GB (1) | GB966000A (en) |
NL (1) | NL290362A (en) |
-
0
- NL NL290362D patent/NL290362A/xx unknown
- FR FR1353765D patent/FR1353765A/en not_active Expired
- BE BE629719D patent/BE629719A/xx unknown
-
1963
- 1963-03-18 DE DE19631468627 patent/DE1468627A1/en active Pending
- 1963-03-18 GB GB10685/63A patent/GB966000A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR1353765A (en) | 1964-06-05 |
BE629719A (en) | |
NL290362A (en) | |
DE1468627A1 (en) | 1969-01-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2398101A (en) | Separation of hydrocarbons | |
US5454933A (en) | Deep desulfurization of distillate fuels | |
US3051646A (en) | Removal of sulfur materials from hydrocarbons | |
GB1126482A (en) | Separation of straight chain hydrocarbons from mixtures | |
US2731149A (en) | Continuous adsorption-desorption apparatus | |
US2831905A (en) | Gamma-butyrolactone as a selective solvent for hydrocarbons | |
GB771710A (en) | Processes for the separation of mixtures by means of adsorptive distillation | |
US3080311A (en) | Gas oil hydrocracking process to produce a high octane gasoline | |
US2987471A (en) | Separation of hydrocarbons | |
US2284583A (en) | Process for treating hydrocarbon oils with light hydrocarbons | |
US3053913A (en) | Separation of high molecular weight hydrocarbons with molecular sieves | |
US3054838A (en) | Method for separating n-hydrocarbons using molecular sieves | |
US2957927A (en) | Process for separating normal aliphatic hydrocarbons from hydrocarbon mixtures | |
US2764620A (en) | Adsorption process with heating in downstream end of adsorption column to selectively remove occluded liquids | |
ES318533A1 (en) | A procedure for the production of a current of high content of aromatic hydrocarbons. (Machine-translation by Google Translate, not legally binding) | |
US2646451A (en) | Continuous adsorption process | |
US4008150A (en) | Fractionation to remove a high-boiling material and a dissolved substance | |
US2696510A (en) | Continuous process for adsorbtion-desorption | |
GB966000A (en) | Process for the separation of a mixture in the liquid phase using a solid selective adsorbent | |
US2693495A (en) | Recovery of pure hydrocarbons | |
US2936325A (en) | Substituted amides as selective solvents for aromatic hydrocarbons | |
US2716144A (en) | Separation of aromatics from gasoline or kerosene fractions | |
US2717864A (en) | Partial hydrogenation of feed oils employed in catalytic cracking to produce motor fuels | |
US2848379A (en) | Treatment of high boiling catalytically cracked products with activated carbon | |
US2322673A (en) | Treating hydrocarbon fluids |