GB963418A - Phosphorinanones and methods of preparing same - Google Patents
Phosphorinanones and methods of preparing sameInfo
- Publication number
- GB963418A GB963418A GB40459/62A GB4045962A GB963418A GB 963418 A GB963418 A GB 963418A GB 40459/62 A GB40459/62 A GB 40459/62A GB 4045962 A GB4045962 A GB 4045962A GB 963418 A GB963418 A GB 963418A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- substituted
- radical
- carbon atoms
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ALQHHUFONRFGMF-UHFFFAOYSA-N phosphinan-2-one Chemical class O=C1CCCCP1 ALQHHUFONRFGMF-UHFFFAOYSA-N 0.000 title abstract 2
- -1 alkyl radical Chemical class 0.000 abstract 12
- 125000004432 carbon atom Chemical group C* 0.000 abstract 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 6
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 5
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 150000005840 aryl radicals Chemical class 0.000 abstract 2
- GVFQLFXNYFKVCA-UHFFFAOYSA-N phosphinan-4-one Chemical class O=C1CCPCC1 GVFQLFXNYFKVCA-UHFFFAOYSA-N 0.000 abstract 2
- 101100305864 Alteromonas mediterranea (strain DSM 17117 / CIP 110805 / LMG 28347 / Deep ecotype) rph2 gene Proteins 0.000 abstract 1
- 101100135363 Yarrowia lipolytica (strain CLIB 122 / E 150) RIM101 gene Proteins 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 239000003254 gasoline additive Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical compound C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
- C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/26—Organic compounds containing phosphorus
- C10L1/2608—Organic compounds containing phosphorus containing a phosphorus-carbon bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
Abstract
The invention comprises 4-phosphorinanones of formula: <FORM:0963418/C1/1> wherein R is a substituted or unsubstituted, branched or straight chain alkyl radical having from 1 to 18 carbon atoms, a substituted or unsubstituted cycloalkyl radical, or a substituted or unsubstituted aryl radical; each of R1, R2, R3\h and R4 is one of the following; a hydrogen atom, a C1- 6 alkyl, phenyl, chloro-substituted phenyl, (C1- 6)-alkyl-substituted phenyl, or alkoxyalkyl radical of which the alkyl and alkoxy radicals contain from 1 to 6 carbon atoms; and each of R5 and R6 is a hydrogen atom or an alkyl radical containing from 1 to 6 carbon atoms: with the proviso that R1 to R6 are not all hydrogen atoms. They are prepared by reacting a divinyl ketone of formula: <FORM:0963418/C1/2> with a primary phosphine RPH2, e.g. at 80-200 DEG C. Suitable substituents for R when alkyl include alkoxy, phenyl and cyano and when aryl, halogen. The products may be used as gasoline additives (see Division C5).ALSO:Gasoline compositions comprise 4-phosphorinanones of formula <FORM:0963418/C4-C5/1> wherein R is a substituted or unsubstituted, branched or straight chain alkyl radical having from 1 to 18 carbon atoms, a substituted or unsubstituted cycloalkyl radical, or a substituted or unsubstituted aryl radical; each of R1, R2, R3 and R4 is one of the following: a hydrogen atom, a C1- 6 alkyl, phenyl, chloro-substituted phenyl, (C1- 6) - alkyl - substituted phenyl, or alkoxyalkyl radical of which the alkyl and alkoxy radicals contain from 1 to 6 carbon atoms; and each of R5 and R6 is a hydrogen atom or an alkyl radical containing from 1 to 6 carbon atoms: with the proviso that R1 to R6 are not all hydrogen atoms. (For preparation see Division C2.) Up to about 10 ml. or mg. of phosphorinanone may be used per gallon.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16140561A | 1961-12-22 | 1961-12-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB963418A true GB963418A (en) | 1964-07-08 |
Family
ID=22581055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB40459/62A Expired GB963418A (en) | 1961-12-22 | 1962-10-25 | Phosphorinanones and methods of preparing same |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR1339413A (en) |
| GB (1) | GB963418A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002064249A2 (en) * | 2001-02-09 | 2002-08-22 | Basf Aktiengesellschaft | Compound suitable for use as a catalyst or for producing a catalyst system derived from a bis-phosphorinane |
-
1962
- 1962-10-25 GB GB40459/62A patent/GB963418A/en not_active Expired
- 1962-11-23 FR FR916427A patent/FR1339413A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002064249A2 (en) * | 2001-02-09 | 2002-08-22 | Basf Aktiengesellschaft | Compound suitable for use as a catalyst or for producing a catalyst system derived from a bis-phosphorinane |
| WO2002064249A3 (en) * | 2001-02-09 | 2003-03-20 | Basf Ag | Compound suitable for use as a catalyst or for producing a catalyst system derived from a bis-phosphorinane |
| US7105689B2 (en) | 2001-02-09 | 2006-09-12 | Basf Aktiengesellschaft | Compound suitable for use as a catalyst or for producing a catalyst system derived from a bis-phosphorinane |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1339413A (en) | 1963-10-04 |
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