GB958458A - Improvements in or relating to oxychlorination of hydrocarbons - Google Patents

Improvements in or relating to oxychlorination of hydrocarbons

Info

Publication number
GB958458A
GB958458A GB14510/62A GB1451062A GB958458A GB 958458 A GB958458 A GB 958458A GB 14510/62 A GB14510/62 A GB 14510/62A GB 1451062 A GB1451062 A GB 1451062A GB 958458 A GB958458 A GB 958458A
Authority
GB
United Kingdom
Prior art keywords
copper
catalyst
chloride
contain
alumina
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB14510/62A
Inventor
Clifford William Capp
David James Hadley
Patricia Eileen Waight
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL135031D priority Critical patent/NL135031C/xx
Priority to NL290661D priority patent/NL290661A/xx
Priority to BE630963D priority patent/BE630963A/xx
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Priority to GB14510/62A priority patent/GB958458A/en
Priority to FR929703A priority patent/FR1352448A/en
Priority to DED41320A priority patent/DE1284411B/en
Publication of GB958458A publication Critical patent/GB958458A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/154—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of saturated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Chlorinated hydrocarbons are produced by contacting a feed containing ethane, hydrogen chloride and molecular oxygen in the vapour phase at elevated temperature with a catalyst comprising copper deposited on activated alumina, the alumina having been subjected prior to deposition, to a heat treatment at a temperature between 500 DEG and 1,400 DEG C. The catalyst may be copper, copper oxide or copper chloride which may be applied to the support in any suitable manner. The catalyst/alumina mixture should preferably contain 0.5-10% by weight of copper in free or combined form. The catalyst may also contain an alkali and/or alkaline earth metal in combined form in an amount preferably of 0.5-5% by weight. Suitable compounds are, for example, the hydroxides, chlorides, carbonates, aluminates or nitrates of sodium, potassium or magnesium. The catalysts may also contain iron or a rare earth metal. The reaction temperature is preferably in the range 200-500 DEG C. The main products are vinyl chloride, ethyl chloride and 1,1 and 1,2-dichlorethanes. The dichlorethanes may be further pyrolyzed to give vinyl chloride and hydrogen chloride which may be recycled to the process. By-products include dichlorethylenes, trichloroethanes, tetrachloroethane and pentachloroethane.
GB14510/62A 1962-04-14 1962-04-14 Improvements in or relating to oxychlorination of hydrocarbons Expired GB958458A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
NL135031D NL135031C (en) 1962-04-14
NL290661D NL290661A (en) 1962-04-14
BE630963D BE630963A (en) 1962-04-14
GB14510/62A GB958458A (en) 1962-04-14 1962-04-14 Improvements in or relating to oxychlorination of hydrocarbons
FR929703A FR1352448A (en) 1962-04-14 1963-03-29 Improved process for the oxychlorination of hydrocarbons
DED41320A DE1284411B (en) 1962-04-14 1963-04-08 Process for the production of monochloroethane and vinyl chloride in addition to 1,2-dichloroethane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB14510/62A GB958458A (en) 1962-04-14 1962-04-14 Improvements in or relating to oxychlorination of hydrocarbons

Publications (1)

Publication Number Publication Date
GB958458A true GB958458A (en) 1964-05-21

Family

ID=10042502

Family Applications (1)

Application Number Title Priority Date Filing Date
GB14510/62A Expired GB958458A (en) 1962-04-14 1962-04-14 Improvements in or relating to oxychlorination of hydrocarbons

Country Status (4)

Country Link
BE (1) BE630963A (en)
DE (1) DE1284411B (en)
GB (1) GB958458A (en)
NL (2) NL135031C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3209964A1 (en) * 1981-03-19 1982-11-11 Imperial Chemical Industries Plc, London Process for the preparation of chlorinated hydrocarbons
US4910354A (en) * 1986-06-27 1990-03-20 Solvay & Cie (Societe Anonyme) Process for the oxychlorination of ethylene and catalyst compositions for the oxychlorination
CN111556787A (en) * 2018-02-23 2020-08-18 株式会社Lg化学 Catalyst for use in process for oxychlorination of hydrocarbon, method for preparing the same, and method for preparing oxychlorinated compound of hydrocarbon using the same

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3046407A1 (en) * 1980-12-10 1982-07-15 Basf Ag, 6700 Ludwigshafen CARRIER CATALYST CONTAINING COPPER AND ALKALI METALS AND THE USE THEREOF FOR PRODUCING 1,2-DICHLORETHANE BY OXICHLORATION OF ETHANE
AU8168782A (en) * 1981-03-19 1982-09-23 Imperial Chemical Industries Plc Production of monochlorinated compounds

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2752402A (en) * 1950-10-06 1956-06-26 Dow Chemical Co Oxychlorination of hydrocarbons

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3209964A1 (en) * 1981-03-19 1982-11-11 Imperial Chemical Industries Plc, London Process for the preparation of chlorinated hydrocarbons
US4910354A (en) * 1986-06-27 1990-03-20 Solvay & Cie (Societe Anonyme) Process for the oxychlorination of ethylene and catalyst compositions for the oxychlorination
US5315051A (en) * 1986-06-27 1994-05-24 Solvay (Societe Anonyme) Process for the oxychlorination of ethylene and catalyst compositions for the oxychlorination
CN111556787A (en) * 2018-02-23 2020-08-18 株式会社Lg化学 Catalyst for use in process for oxychlorination of hydrocarbon, method for preparing the same, and method for preparing oxychlorinated compound of hydrocarbon using the same
EP3730211A4 (en) * 2018-02-23 2021-01-06 Lg Chem, Ltd. Catalyst for oxychlorination process of hydrocarbon, method for producing same, and method for manufacturing oxychlorinated compound of hydrocarbon by using same
JP2021509353A (en) * 2018-02-23 2021-03-25 エルジー・ケム・リミテッド A catalyst for the oxychlorolation process of hydrocarbons, a method for producing the same, and a method for producing an oxychloroization compound for hydrocarbons using the catalyst.

Also Published As

Publication number Publication date
DE1284411B (en) 1968-12-05
NL135031C (en) 1900-01-01
NL290661A (en) 1900-01-01
BE630963A (en) 1900-01-01

Similar Documents

Publication Publication Date Title
US2378859A (en) Splitting-off of hydrogen halide from halogenated hydrocarbons
GB1115732A (en) Oxychlorination of hydrocarbons and a catalyst therefor
US3927131A (en) Dehydrohalogenation of halogenated hydrocarbons
GB958458A (en) Improvements in or relating to oxychlorination of hydrocarbons
GB1091329A (en) Catalyst
GB1012423A (en) Production of chlorinated hydrocarbons
US2327174A (en) Preparation of halogenated olefins
GB1039369A (en) Catalytic conversion of ethane to vinyl chloride
GB941353A (en) Chemical process and catalyst
GB959244A (en) Chlorination of hydrocarbons
US3268602A (en) Process for the dehydrohalogenation of halogenated hydrocarbons
GB921254A (en) Improvements in and relating to fluorination
US2374923A (en) Manufacture of unsaturated halogenated compounds
West et al. The Peroxide-Induced Exchange of Hydrogen and Chlorine between Saturated Hydrocarbons and Polychloroalkanes1
GB1198730A (en) Preparation of 1,2-Dichloroethane, Pentachloroethane, 1,1,2-Trichloroethane, 1,1,2,2-Tetrachloroethane by Oxychlorination of Ethylene
GB1042491A (en) Process and catalysts for the hydrofluorination of acetylenic hydrocarbons
GB1357246A (en) Hydrofluorination catalysts methods of producing the same and their use
ES356672A1 (en) Procedure for the production of ethylene bicloride. (Machine-translation by Google Translate, not legally binding)
KR830003928A (en) Improved Alumina Supported Copper Catalyst Composition for Fluidized Bed Oxygen Chlorination of Hydrocarbons
ES361954A1 (en) Process for obtaining tetrachloroethanes
US3637872A (en) Dehydrochlorination process
GB1218414A (en) Fluidized bed process for the simultaneous preparation of 1,2-dichloroethane, 1,1,2-trichloroethane, 1,1,2,2-tetrachloroethane and pentachloroethane
GB1331846A (en) Catalyst comprising a graphite-copper 22 chloride intercalation compounds and a method of producing the same
GB1439171A (en) Oxyhalogenation process
GB1104661A (en) Improvements in or relating to the production of vinyl chloride