GB957276A - Process for the production of chlorine derivatives of alpha-picoline and novel 2-(trichloromethyl) pyridines - Google Patents
Process for the production of chlorine derivatives of alpha-picoline and novel 2-(trichloromethyl) pyridinesInfo
- Publication number
- GB957276A GB957276A GB4330662A GB4330662A GB957276A GB 957276 A GB957276 A GB 957276A GB 4330662 A GB4330662 A GB 4330662A GB 4330662 A GB4330662 A GB 4330662A GB 957276 A GB957276 A GB 957276A
- Authority
- GB
- United Kingdom
- Prior art keywords
- trichloromethyl
- pyridine
- compositions
- chlorine
- picoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KAQJMEHRXVENSF-UHFFFAOYSA-N 2-(trichloromethyl)pyridine Chemical class ClC(Cl)(Cl)C1=CC=CC=N1 KAQJMEHRXVENSF-UHFFFAOYSA-N 0.000 title abstract 5
- 125000001309 chloro group Chemical class Cl* 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- BSKHPKMHTQYZBB-UHFFFAOYSA-N alpha-methylpyridine Natural products CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 12
- 238000005660 chlorination reaction Methods 0.000 abstract 6
- 239000000460 chlorine Substances 0.000 abstract 5
- 229910052801 chlorine Inorganic materials 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 4
- 239000003337 fertilizer Substances 0.000 abstract 4
- DCUJJWWUNKIJPH-UHFFFAOYSA-N nitrapyrin Chemical compound ClC1=CC=CC(C(Cl)(Cl)Cl)=N1 DCUJJWWUNKIJPH-UHFFFAOYSA-N 0.000 abstract 4
- MSRGJVQTGNSQOZ-UHFFFAOYSA-N 2,3,5-trichloro-6-(trichloromethyl)pyridine Chemical compound ClC1=CC(Cl)=C(C(Cl)(Cl)Cl)N=C1Cl MSRGJVQTGNSQOZ-UHFFFAOYSA-N 0.000 abstract 3
- 239000011541 reaction mixture Substances 0.000 abstract 3
- YMBFWRZKTZICHS-UHFFFAOYSA-N 2,3,4,5-tetrachloro-6-(trichloromethyl)pyridine Chemical compound ClC1=NC(C(Cl)(Cl)Cl)=C(Cl)C(Cl)=C1Cl YMBFWRZKTZICHS-UHFFFAOYSA-N 0.000 abstract 2
- ZHNXVFQAGRDLBV-UHFFFAOYSA-N 2,3-dichloro-6-(trichloromethyl)pyridine Chemical compound ClC1=CC=C(C(Cl)(Cl)Cl)N=C1Cl ZHNXVFQAGRDLBV-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- -1 ammonium ions Chemical class 0.000 abstract 2
- 239000001963 growth medium Substances 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 239000002689 soil Substances 0.000 abstract 2
- 239000007858 starting material Substances 0.000 abstract 2
- FOXDMOFYUBDIFD-UHFFFAOYSA-N 2-(dichloromethyl)pyridine Chemical class ClC(Cl)C1=CC=CC=N1 FOXDMOFYUBDIFD-UHFFFAOYSA-N 0.000 abstract 1
- OMSBSIXAZZRIRW-UHFFFAOYSA-N 2-methylpyridine;hydrochloride Chemical compound Cl.CC1=CC=CC=N1 OMSBSIXAZZRIRW-UHFFFAOYSA-N 0.000 abstract 1
- YWSFDYUMEBEQNZ-UHFFFAOYSA-N 3,4,5-trichloro-2-(trichloromethyl)pyridine Chemical compound ClC1=CN=C(C(Cl)(Cl)Cl)C(Cl)=C1Cl YWSFDYUMEBEQNZ-UHFFFAOYSA-N 0.000 abstract 1
- MWFCRQNUHFSUNY-UHFFFAOYSA-N 3,6-dichloro-2-(trichloromethyl)pyridine Chemical compound ClC1=CC=C(Cl)C(C(Cl)(Cl)Cl)=N1 MWFCRQNUHFSUNY-UHFFFAOYSA-N 0.000 abstract 1
- 229920001817 Agar Polymers 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 abstract 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 abstract 1
- 239000008272 agar Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000002609 medium Substances 0.000 abstract 1
- 244000005700 microbiome Species 0.000 abstract 1
- 230000001069 nematicidal effect Effects 0.000 abstract 1
- 239000005645 nematicide Substances 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/61—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Fertilizers (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15262361A | 1961-11-15 | 1961-11-15 | |
| US15262461A | 1961-11-15 | 1961-11-15 | |
| US17787162A | 1962-03-06 | 1962-03-06 | |
| US21369162A | 1962-07-31 | 1962-07-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB957276A true GB957276A (en) | 1964-05-06 |
Family
ID=27496034
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4330662A Expired GB957276A (en) | 1961-11-15 | 1962-11-15 | Process for the production of chlorine derivatives of alpha-picoline and novel 2-(trichloromethyl) pyridines |
Country Status (5)
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4227001A (en) * | 1978-06-19 | 1980-10-07 | The Dow Chemical Company | Preparation of polychlorinated pyridines from 2,4-dichloro-6-(trichloro methyl)pyridine |
| US4256894A (en) * | 1978-04-24 | 1981-03-17 | The Dow Chemical Company | Preparation of chlorinated pyridines |
| US4331811A (en) * | 1981-03-12 | 1982-05-25 | The Dow Chemical Company | Preparation of 2,3-dichloro-5-trichloromethylpyridine |
| US4487935A (en) * | 1982-09-24 | 1984-12-11 | Kalama Chemical, Inc. | Production of mixtures rich in 6-chloro-2-trichloromethyl pyridine |
| US4497955A (en) * | 1982-09-24 | 1985-02-05 | Kalama Chemical, Inc. | Preparation of 2-chloro-5-trichloromethyl pyridine from lower chlorinated beta-picolines |
| US4517369A (en) * | 1982-09-29 | 1985-05-14 | Kalama Chemical, Inc. | Preparation of mixtures rich in 3,4,5,6-tetrachloro-2-trichloromethyl pyridine |
| US4564681A (en) * | 1982-09-24 | 1986-01-14 | Kalama Chemical, Inc. | Production of mixtures rich in 3-chloro-2-trichloromethyl pyridine |
| US4577027A (en) * | 1982-09-24 | 1986-03-18 | Kalama Chemical, Inc. | Production of polychlorinated pyridine mixtures by direct liquid phase chlorination of alpha-picoline |
-
0
- BE BE624800D patent/BE624800A/xx unknown
- NL NL285543D patent/NL285543A/xx unknown
-
1962
- 1962-11-14 DK DK491362A patent/DK108573C/da active
- 1962-11-15 DE DE19621445653 patent/DE1445653A1/de active Pending
- 1962-11-15 GB GB4330662A patent/GB957276A/en not_active Expired
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4256894A (en) * | 1978-04-24 | 1981-03-17 | The Dow Chemical Company | Preparation of chlorinated pyridines |
| US4227001A (en) * | 1978-06-19 | 1980-10-07 | The Dow Chemical Company | Preparation of polychlorinated pyridines from 2,4-dichloro-6-(trichloro methyl)pyridine |
| US4331811A (en) * | 1981-03-12 | 1982-05-25 | The Dow Chemical Company | Preparation of 2,3-dichloro-5-trichloromethylpyridine |
| US4487935A (en) * | 1982-09-24 | 1984-12-11 | Kalama Chemical, Inc. | Production of mixtures rich in 6-chloro-2-trichloromethyl pyridine |
| US4497955A (en) * | 1982-09-24 | 1985-02-05 | Kalama Chemical, Inc. | Preparation of 2-chloro-5-trichloromethyl pyridine from lower chlorinated beta-picolines |
| US4564681A (en) * | 1982-09-24 | 1986-01-14 | Kalama Chemical, Inc. | Production of mixtures rich in 3-chloro-2-trichloromethyl pyridine |
| US4577027A (en) * | 1982-09-24 | 1986-03-18 | Kalama Chemical, Inc. | Production of polychlorinated pyridine mixtures by direct liquid phase chlorination of alpha-picoline |
| US4517369A (en) * | 1982-09-29 | 1985-05-14 | Kalama Chemical, Inc. | Preparation of mixtures rich in 3,4,5,6-tetrachloro-2-trichloromethyl pyridine |
Also Published As
| Publication number | Publication date |
|---|---|
| BE624800A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| NL285543A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | |
| DE1445653A1 (de) | 1969-02-20 |
| DK108573C (da) | 1968-01-08 |
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