GB956642A - Process for the production of cold-hardening reaction lacquers - Google Patents
Process for the production of cold-hardening reaction lacquersInfo
- Publication number
- GB956642A GB956642A GB2192462A GB2192462A GB956642A GB 956642 A GB956642 A GB 956642A GB 2192462 A GB2192462 A GB 2192462A GB 2192462 A GB2192462 A GB 2192462A GB 956642 A GB956642 A GB 956642A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methacrylate
- allyl
- methylmethacrylate
- hardening
- initial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
Abstract
Cold-hardening reaction lacquers are produced by partially polymerizing methylmethacrylate in the presence of a chain-transfer agent and a catalyst and in the presence of allyl acrylate or allyl methacrylate until a syrupy initial polymer is formed which may then be hardened. The syrupy initial polymer may before being applied to the surface to be coated, be brought to a suitable viscosity by adding monomeric methylmethacrylate. The initial polymerization may be effected in the presence of plasticising monomers or mixtures thereof such as ethyl-, butyl-, decyl- or ethylhexyl-acrylate and ethylhexyl-, butyl- or decyl-methacrylate. Preferably 2 to 20% by weight of the allyl compound, and up to 20% by weight of the plasticising monomers, based on the monomer mixture, are used. In the initial polymerization the catalyst may be azodiisobutyric acid dinitrile and the chain-transfer agent may be a mercaptan or an ester of mercaptoacetic acid. The preferred catalyst systems for the hardening of the initial polymers are (a) a peroxidic compound and a tertiary amine which preferably contains at least one aromatic radical bonded directly to the nitrogen atom and (b) a diacyl peroxide, a monofunctional or a polyfunctional mercaptan and/or esters of mercaptoacetic acid and a tertiary anine which comtains at least one aromatic radical bonded directly to the nitrogen atom. Lists of peroxides, amines and mercaptans are given. Plasticisers, cross-linking agents, dye-stuffs, fillers e.g. highly dispersed metal or metalloid oxides which have been hardened pyrogenically, ultra-violet stabilisers, and paraffin or wax, may be added to the reaction lacquers before hardening. In the examples (1) methyl methacrylate is polymerized with allyl methacrylate in the presence of glycol dimercaptoacetate and azodiisobutyric acid dinitrile and the syrup obtained after dilution with monomeric methylmethacrylate is hardened with diisopropylol-p-toluidine and benzoyl peroxide paste (in dibutyl phthalate). (2) methyl methacrylate, ethylmethacrylate, ethylhexyl methacrylate and allyl methacrylate are copolymerized and before hardening as in Ex. (1), paraffin may be added; (5) methylmethacrylate, ethylmethacrylate, ethylhexylmethacrylate and allyl acrylate are copolymerized.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED36267A DE1221750B (en) | 1961-06-06 | 1961-06-06 | Process for the production of cold-curing, solvent-free coatings |
Publications (1)
Publication Number | Publication Date |
---|---|
GB956642A true GB956642A (en) | 1964-04-29 |
Family
ID=7043033
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2192462A Expired GB956642A (en) | 1961-06-06 | 1962-06-06 | Process for the production of cold-hardening reaction lacquers |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE618516A (en) |
DE (1) | DE1221750B (en) |
GB (1) | GB956642A (en) |
NL (1) | NL278772A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2552094A1 (en) * | 1983-09-20 | 1985-03-22 | Roehm Gmbh | RADIOSENSITIVE POLYMERIC MATERIAL, PROCESS FOR THE PREPARATION THEREOF, AND USE THEREOF FOR THE MANUFACTURE OF SUPPORTS FOR THE EXECUTION OF TRACKS |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2310731A (en) * | 1939-10-31 | 1943-02-09 | Gen Electric | Interpolymers of diallyl itaconate and ethyl methacrylate |
US2446314A (en) * | 1944-05-15 | 1948-08-03 | Shell Dev | Process for the preparation of soluble polymers of unsaturated esters of polycarboxylic acids |
US2450682A (en) * | 1946-04-30 | 1948-10-05 | Gen Electric | Polymers of an unsaturated alkyd resin and an unsaturated halogenated compound and method of producing same |
-
0
- NL NL278772D patent/NL278772A/xx unknown
- BE BE618516D patent/BE618516A/xx unknown
-
1961
- 1961-06-06 DE DED36267A patent/DE1221750B/en active Pending
-
1962
- 1962-06-06 GB GB2192462A patent/GB956642A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2552094A1 (en) * | 1983-09-20 | 1985-03-22 | Roehm Gmbh | RADIOSENSITIVE POLYMERIC MATERIAL, PROCESS FOR THE PREPARATION THEREOF, AND USE THEREOF FOR THE MANUFACTURE OF SUPPORTS FOR THE EXECUTION OF TRACKS |
Also Published As
Publication number | Publication date |
---|---|
BE618516A (en) | |
NL278772A (en) | |
DE1221750B (en) | 1966-07-28 |
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