GB956455A - Formazane dyestuffs, their production and use - Google Patents

Formazane dyestuffs, their production and use

Info

Publication number
GB956455A
GB956455A GB1638560A GB1638560A GB956455A GB 956455 A GB956455 A GB 956455A GB 1638560 A GB1638560 A GB 1638560A GB 1638560 A GB1638560 A GB 1638560A GB 956455 A GB956455 A GB 956455A
Authority
GB
United Kingdom
Prior art keywords
dyes
amino
sulphonic acid
specified
moles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1638560A
Inventor
Wilhelm Kraus Jun
Willy Steinemann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandoz AG
Original Assignee
Sandoz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandoz AG filed Critical Sandoz AG
Publication of GB956455A publication Critical patent/GB956455A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B33/00Disazo and polyazo dyes of the types A->K<-B, A->B->K<-C, or the like, prepared by diazotising and coupling
    • C09B33/02Disazo dyes
    • C09B33/16Disazo dyes from other coupling components
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B50/00Formazane dyes; Tetrazolium dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/002Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the linkage of the reactive group being alternatively specified
    • C09B62/018Formazane dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The invention comprises formazane dyes and their metal complex compounds which in the metal free form are of formula <FORM:0956455/C3/1> wherein A and B are identical isocyclic aromatic radicals, R is an aryl radical and X1 and X2 are identical groups capable of metal complex formation and occupying positions adjacent to the nitrogen bridge. The dyes are prepared by coupling, in an alkaline medium, 2 moles of a diazo compound of an isocyclic aromatic amine which contains in an adjacent position to the diazo group a metallisable group or a substituent convertible thereto under metallizing conditions, with 1 mole of a methylarylketone and metallizing the dye obtained if desired in substance or on the fibre. The metallization may be carried out by customary methods using copper, nickel, cobalt or zinc compounds. The dyes may be used to colour any natural or synthetic fibre but are preferably used to dye wool, silk and synthetic polyamides. In examples, 2 moles of a diazo compound of the amines specified below are coupled with 1 mole of the ketone also specified and treated with copper, cobalt or nickel yielding agents: 2-aminobenzoic acid, 4 acetylaminoacetophenone; 2 amino phenol 4 sulphonic acid anilide, 1 - acetylnaphthalene; 4 - nitro - 2 - aminophenol, acetophenone; 1 - amino - 2 - naphthol - 4 - sulphonic acid, acetophenol; 1-amino-2-hydroxy-3 - carboethoxyamino - benzene - 5 - sulphonic acid, sodium salt of 3-phenyl-3-oxo-propionic acid. Acylamino groups in the dyes so produced may be saponified and condensed with polyhalo-triazines or -pyrimidines. Many alternative reactants are specified. Specifications 822,047 and 822,948 are referred to.
GB1638560A 1959-05-09 1960-05-09 Formazane dyestuffs, their production and use Expired GB956455A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH7307359A CH378441A (en) 1959-05-09 1959-05-09 Process for the production of azo dyes

Publications (1)

Publication Number Publication Date
GB956455A true GB956455A (en) 1964-04-29

Family

ID=4532338

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1638560A Expired GB956455A (en) 1959-05-09 1960-05-09 Formazane dyestuffs, their production and use

Country Status (2)

Country Link
CH (1) CH378441A (en)
GB (1) GB956455A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0374815A1 (en) * 1988-12-22 1990-06-27 Hoechst Aktiengesellschaft Complex copper formazane compounds, process for their preparation and their use as dyestuffs

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0374815A1 (en) * 1988-12-22 1990-06-27 Hoechst Aktiengesellschaft Complex copper formazane compounds, process for their preparation and their use as dyestuffs
US5028700A (en) * 1988-12-22 1991-07-02 Hoechst Aktiengesellschaft Copper-complex formazan compounds having a fiber-reactive group of the vinylsulfone series, suitable as dyestuffs

Also Published As

Publication number Publication date
CH378441A (en) 1964-06-15

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