GB953904A - Process for colouring cellulose textile materials - Google Patents
Process for colouring cellulose textile materialsInfo
- Publication number
- GB953904A GB953904A GB23909/61A GB2390961A GB953904A GB 953904 A GB953904 A GB 953904A GB 23909/61 A GB23909/61 A GB 23909/61A GB 2390961 A GB2390961 A GB 2390961A GB 953904 A GB953904 A GB 953904A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- groups
- dyes
- group
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
- D06P3/666—Natural or regenerated cellulose using reactive dyes reactive group not directly attached to heterocyclic group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/443—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being alternatively specified
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/001—Dyes containing an onium group attached to the dye skeleton via a bridge
Abstract
The sodium salt of N-{b -[4-(11-hydroxy-31-sulpho - 6 - aminonaphth - 21 - ylazo) phenyl-sulphonyl] ethyl} pyridinium chloride is prepared by coupling diazotized N-[b -(4-amino-phenylsulphonyl) ethyl] pyridinium chloride with 2 - amino - 5 - naphthol - 7 - sulphonic acid in alkaline medium. The disodium salt of N-{b -[4-(11-hydroxy-81 - amino - 31:61 - disulphonaphth - 21 - ylyzo)-phenylsulphonyl] ethyl} pyridinium chloride is prepared in an analogous manner. A copper phthalocyanine dye containing 1.8-SO3Na groups, 0.7-SO2NH2 groups and 1.5 <FORM:0953904/C3/1> groups per molecule is obtained by reacting an aqueous paste of copper phthalocyanine tetra-3 - sulphonchloride with b - chloroethylamine at pH 8, acidifying and quarternating with pyridine in aqueous medium. Copper phthalocyanine dyes are prepared by quarternating the dyestuff of Examples 1 and 7 of Specification 826,689 with (a) pyridine and (b) 1:4 - diazabicyclo - (2:2:2) - octane. Mixtures of dyes.-Any of the above type of dye may be used in admixture with the corresponding unquarternated dye e.g. a mixture of the disodium salts of 4(21-hydroxy-31:61-disulphonaphth - 11 - ylazo) phenylsulphon - N-b - chloroethylamide with 4 - {b - [41 - (211 - hydroxy - 311:611 - disulphonaphth - 111 - ylazo)-phenylsulphonamido] ethyl} - 1 - aza - 4 - azo-nia - bicyclo - (2:2:2) - octane chloride and mixtures of the phthalocyanine dyes in Examples 1 and 7 of Specification 826,689 with any of the above phthalocyamines. Specifications 740,553, 845,567, 852,960, 867,546, 870,047, 881,737, 882,750, 885,059, 885,549 and 885,681 also are referred to.ALSO:Cellulose textile materials are dyed or printed, in conjunction with a treatment with an acidbinding agent, with (a) a dyestuff which contains at least one group of the formula <FORM:0953904/D1-D2/1> wherein n is 1 or 2, A is an alkylene radical which may be substituted, X is -CO-, -SO2, -NHCO-, -CONH- or -SO2N(R)- wherein R is H or a hydrocarbon radical which may be substituted, and V1, V2 and V3 each represent a hydrocarbon or heterocyclic radical or at least two of them join with the N to form a heterocyclic ring containing either single or double bonds, provided that the dye contains at least as many -SO3 H and/or -COOH groups as groups of formula I or (b) a mixture of a dyestuff containing at least one group of formula I and a dyestuff which contains at least one -SO3H and/or -COOH group and at least one group of the formula <FORM:0953904/D1-D2/2> wherein Q is -Cl, -Br or a sulphate ester group or a group -S-Z wherein Z is a hydrocarbon or heterocyclic radical which may be substituted or a group of the formula <FORM:0953904/D1-D2/3> wherein R1 and R2 each represent a hydrocarbon or heterocyclic radical which may be substituted or R1 and R2 form a heterocyclic ring together with the N and n is 1 or 2. Each of the groups of formulae I and II is attached to a carbon atom of an aryl nucleus in the dyestuff which may be of the mono- or polyazo, nitro, anthraquinone, polycyclic vat or phthalocyanine series and may contain coordinately bound Cu, Cr or Co. Many radicals are specified. The dyes or dye mixtures may be applied from a dyebath or by padding or printing and the acid binding agent may be applied before, during or after the dyeing operation. Fixation may be achieved in the dyebath by adding the acid binding agent or by dry heating or steaming the impregnated material. Many acid binding agents are specified. The dyebaths or print pastes may further contain sodium chloride or sulphate, urea, dispersing agents surfactants, sodium alginate and/or an emulsion of trichlorethylene in water. The specified cellulose materials are cotton, linen, viscose rayon, polynosic rayons and high wet modulus rayons. Mixtures of dyes containing groups of formula I and dyes containing groups of formula II may be prepared by mixing or grinding the said dyes together in the desired proportions or by coprecipitating them from aqueous solutions or alternatively by merely adding the two sorts of dye to the dyebath. The preferred proportion is 75-90% of dyes containing groups of formula II. Examples are given. Specifications 740,553, 826,689, 845,567, 852,960, 867,546, 870,047, 881,737, 882,750, 885,059, 885,547 and 885,681 are referred to.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB23909/61A GB953904A (en) | 1961-07-03 | 1961-07-03 | Process for colouring cellulose textile materials |
CH794262A CH397595A (en) | 1961-07-03 | 1962-07-02 | Process for dyeing or printing cellulosic textile materials |
FR902839A FR1335075A (en) | 1961-07-03 | 1962-07-03 | Coloring of cellulosic textiles |
BE619731D BE619731A (en) | 1961-07-03 | 1962-07-03 | NEW COLORING PROCESS |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB23909/61A GB953904A (en) | 1961-07-03 | 1961-07-03 | Process for colouring cellulose textile materials |
GB736362 | 1962-02-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB953904A true GB953904A (en) | 1964-04-02 |
Family
ID=26241372
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB23909/61A Expired GB953904A (en) | 1961-07-03 | 1961-07-03 | Process for colouring cellulose textile materials |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE619731A (en) |
CH (1) | CH397595A (en) |
FR (1) | FR1335075A (en) |
GB (1) | GB953904A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4845209A (en) * | 1984-12-06 | 1989-07-04 | Adam Jean Marie | Cationic phthalocyanine compounds |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1619479A1 (en) * | 1966-06-10 | 1971-07-15 | Bayer Ag | Process for dyeing fully synthetic and semi-synthetic fiber materials |
CH684194A5 (en) * | 1991-01-26 | 1994-07-29 | Sandoz Ag | Pigments in the form of intermolecular salts of zwitterionic dyes. |
-
1961
- 1961-07-03 GB GB23909/61A patent/GB953904A/en not_active Expired
-
1962
- 1962-07-02 CH CH794262A patent/CH397595A/en unknown
- 1962-07-03 FR FR902839A patent/FR1335075A/en not_active Expired
- 1962-07-03 BE BE619731D patent/BE619731A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4845209A (en) * | 1984-12-06 | 1989-07-04 | Adam Jean Marie | Cationic phthalocyanine compounds |
Also Published As
Publication number | Publication date |
---|---|
BE619731A (en) | 1963-01-03 |
CH397595A (en) | 1965-03-31 |
FR1335075A (en) | 1963-08-16 |
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