GB951423A - Preparation of 1-alkyl-1-alkoxy-3-aryl ureas - Google Patents
Preparation of 1-alkyl-1-alkoxy-3-aryl ureasInfo
- Publication number
- GB951423A GB951423A GB43760/61A GB4376061A GB951423A GB 951423 A GB951423 A GB 951423A GB 43760/61 A GB43760/61 A GB 43760/61A GB 4376061 A GB4376061 A GB 4376061A GB 951423 A GB951423 A GB 951423A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aryl
- methyl
- alkoxy
- alkyl
- isocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000013877 carbamide Nutrition 0.000 title abstract 3
- 239000012948 isocyanate Substances 0.000 abstract 3
- -1 aryl isocyanate Chemical class 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 239000007858 starting material Substances 0.000 abstract 2
- IQHSSYROJYPFDV-UHFFFAOYSA-N 2-bromo-1,3-dichloro-5-(trifluoromethyl)benzene Chemical group FC(F)(F)C1=CC(Cl)=C(Br)C(Cl)=C1 IQHSSYROJYPFDV-UHFFFAOYSA-N 0.000 abstract 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
- C07C273/1854—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1-Alkyl-1-alkoxy-3-aryl ureas are prepared by reacting a 1-hydroxy-3-aryl urea with dimethyl or diethyl sulphate under alkaline conditions. The starting materials may be obtained by reacting the aryl isocyanate with hydroxylamine, preferably in the presence of a water-miscible organic solvent which does not react with the aryl isocyanate. In examples the aryl group is phenyl and phenyl substituted as follows: 2-methyl, 3-methyl, 4-methyl, 2-methoxy, 4-methoxy, 3-chloro, 4-chloro, 2, 5-dichloro and 4-bromo. Suitable isocyanate starting materials are listed. The final products are herbicides. Specification 852,422 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8475761A | 1961-01-25 | 1961-01-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB951423A true GB951423A (en) | 1964-03-04 |
Family
ID=22187024
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB43760/61A Expired GB951423A (en) | 1961-01-25 | 1961-12-06 | Preparation of 1-alkyl-1-alkoxy-3-aryl ureas |
Country Status (4)
Country | Link |
---|---|
CH (1) | CH401949A (en) |
DE (1) | DE1196639B (en) |
FR (1) | FR1320068A (en) |
GB (1) | GB951423A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0001225A1 (en) * | 1977-09-01 | 1979-04-04 | BASF Aktiengesellschaft | Phenylurea derivatives, herbicides containing these compounds, and use of these herbicides |
-
1961
- 1961-12-06 GB GB43760/61A patent/GB951423A/en not_active Expired
- 1961-12-29 DE DEA39128A patent/DE1196639B/en active Pending
-
1962
- 1962-01-04 FR FR883901A patent/FR1320068A/en not_active Expired
- 1962-01-16 CH CH48962A patent/CH401949A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0001225A1 (en) * | 1977-09-01 | 1979-04-04 | BASF Aktiengesellschaft | Phenylurea derivatives, herbicides containing these compounds, and use of these herbicides |
Also Published As
Publication number | Publication date |
---|---|
CH401949A (en) | 1965-11-15 |
DE1196639B (en) | 1965-07-15 |
FR1320068A (en) | 1963-03-08 |
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