GB948447A - Process for the production of polyolefins and catalyst therefor - Google Patents

Process for the production of polyolefins and catalyst therefor

Info

Publication number
GB948447A
GB948447A GB1542260A GB1542260A GB948447A GB 948447 A GB948447 A GB 948447A GB 1542260 A GB1542260 A GB 1542260A GB 1542260 A GB1542260 A GB 1542260A GB 948447 A GB948447 A GB 948447A
Authority
GB
United Kingdom
Prior art keywords
aluminium
group
compound
halide
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1542260A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ruhrchemie AG
Original Assignee
Ruhrchemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ruhrchemie AG filed Critical Ruhrchemie AG
Publication of GB948447A publication Critical patent/GB948447A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00—Engines characterised by air compression and subsequent fuel addition
    • F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A compound of a metal of sub-groups A of Group 4-6 of the Periodic System is prepared by reducing a metal compound with an alkyl aluminium halide in an inert liquid medium at -100 DEG to 0 DEG C. Thus, TiCl3 is made from TiCl4 with diethyl aluminium chloride, bromide or fluoride or with aluminium sesquichloride; and TiBr3 from TiBr4 with diethyl aluminium chloride. Preferred liquid media are propylene trimer and diesel oil (b.p. 120-190 DEG C.).ALSO:Crystalline polymers of olefins of the general formula CH2=CHR wherein R is H, or aliphatic hydrocarbon group (up to C8) or an aromatic group, are produced by effecting the polymerization in presence of an aluminium alkyl halide and a lower valency Group 4A-6A metal compound (the latter being a precipitate obtained from a higher valency compound by reduction with an alkyl aluminium halide in an inert liquid medium at -100 to 0 DEG C. and which is thoroughly washed before use). The preparation of polypropylene is exemplified.
GB1542260A 1959-05-02 1960-05-02 Process for the production of polyolefins and catalyst therefor Expired GB948447A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DER0025463 1959-05-02

Publications (1)

Publication Number Publication Date
GB948447A true GB948447A (en) 1964-02-05

Family

ID=7401924

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1542260A Expired GB948447A (en) 1959-05-02 1960-05-02 Process for the production of polyolefins and catalyst therefor

Country Status (4)

Country Link
BE (1) BE590316A (en)
DE (1) DE1420733B2 (en)
GB (1) GB948447A (en)
NL (1) NL251081A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3979372A (en) 1974-01-03 1976-09-07 Shell Oil Company Preparation of titanium trichloride polymerization catalyst component

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5130593A (en) * 1974-09-09 1976-03-15 Mitsubishi Chem Ind KOTAISANENKACHITANSHOKUBAI NO SEIZOHO

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3979372A (en) 1974-01-03 1976-09-07 Shell Oil Company Preparation of titanium trichloride polymerization catalyst component

Also Published As

Publication number Publication date
DE1420733B2 (en) 1969-11-27
DE1420733A1 (en) 1969-03-27
BE590316A (en)
NL251081A (en)

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