GB942776A - Hydroxy alkoxy alkyl phosphites - Google Patents
Hydroxy alkoxy alkyl phosphitesInfo
- Publication number
- GB942776A GB942776A GB12910/62A GB1291062A GB942776A GB 942776 A GB942776 A GB 942776A GB 12910/62 A GB12910/62 A GB 12910/62A GB 1291062 A GB1291062 A GB 1291062A GB 942776 A GB942776 A GB 942776A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polypropylene glycol
- phosphites
- tris
- phosphite
- mole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 title abstract 8
- 125000005113 hydroxyalkoxy group Chemical group 0.000 title 1
- 229920001451 polypropylene glycol Polymers 0.000 abstract 10
- 239000007983 Tris buffer Substances 0.000 abstract 6
- 239000012530 fluid Substances 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 4
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 4
- QABUQFYJORNZBW-UHFFFAOYSA-N 2-(2-hydroxypropoxy)propan-1-ol;phosphorous acid Chemical compound OP(O)O.CC(O)COC(C)CO QABUQFYJORNZBW-UHFFFAOYSA-N 0.000 abstract 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 125000004104 aryloxy group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000003827 glycol group Chemical group 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000000314 lubricant Substances 0.000 abstract 2
- 239000003879 lubricant additive Substances 0.000 abstract 2
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 abstract 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- 229920000728 polyester Polymers 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- 239000004593 Epoxy Substances 0.000 abstract 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 239000004926 polymethyl methacrylate Substances 0.000 abstract 1
- 150000007519 polyprotic acids Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M3/00—Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/1411—Esters of phosphorous acids with hydroxyalkyl compounds with further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5075—Polyethers having heteroatoms other than oxygen having phosphorus
- C08G18/5081—Polyethers having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
- C08G18/5087—Phosphite compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4071—Curing agents not provided for by the groups C08G59/42 - C08G59/66 phosphorus containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
- C08G63/6924—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus derived from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/335—Polymers modified by chemical after-treatment with organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Polypropylene glycol phosphites are prepared by heating at least one mole of a polypropylene glycol with one mole of a triaryl or trialkyl phosphite. An alkaline catalyst or a diaryl or dialkyl phosphite catalyst may be used. The invention also comprises tris polypropylene glycol phosphites and compounds of formula R1R2R3P where R1 is a polypropylene glycol residue having predominantly the structure HOCH(CH3)CH2 (OCH2CH(CH3))xO where X is an integer of at least one and R2 and R3 are selected from R1, alkoxy and aryloxy. The higher tris polypropylene glycol phosphites can be obtained by reacting tris dipropyleneglycol phosphite with propylene oxide. The phosphites may be incorporated into or added as stabilizers or plasticizers to various resin systems (see Division C3) and may be used as lubricants or lubricant additives, heat transfer fluids, hydraulic fluids or pump fluids.ALSO:Polypropylene glycol phosphites are prepared by heating at least one mole of a polypropylene glycol with one mole of a triaryl or trialkyl phosphite. An alkaline catalyst or a diaryl or dialkyl phosphite catalyst may be used. The invention also comprises tris polypropylene glycol phosphites and compounds of formula R1 R2 R3 P where R1 is a polypropylene glycol residue having predominantly the structure HOCH(CH3)CH2 (OCH2CH(CH3))xO where X is an integer and R2 and R3 are selected from R1, alkoxy and aryloxy. The higher tris poly-propylene glycol phosphites can be obtained by reacting tris dipropylene glycol phosphite with propylene oxide. The polypropylene glycol phosphites may be incorporated by reaction into urethane systems or into epoxy systems, in which case they may be reacted as such or as an ester of a polybasic acid, or may be used to form polyesters. They may also be used as stabilisers or plasticisers for polyether polyurethanes, polyesters or polymethylmethacrylate or as lubricants or lubricant additives, heat transfer fluids, hydraulic fluids or pump fluids.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US109842A US3009939A (en) | 1960-09-15 | 1961-05-15 | Hydroxy propoxy propyl phosphites |
Publications (1)
Publication Number | Publication Date |
---|---|
GB942776A true GB942776A (en) | 1963-11-27 |
Family
ID=22329859
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12910/62A Expired GB942776A (en) | 1961-05-15 | 1962-04-04 | Hydroxy alkoxy alkyl phosphites |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1233841B (en) |
GB (1) | GB942776A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2352823A2 (en) * | 1976-05-28 | 1977-12-23 | Hoechst Ag | ORGANIC PHOSPHITES THAT CAN BE USED TO STABILIZE POLYMERIC MATERIALS |
WO2005097810A1 (en) * | 2004-03-26 | 2005-10-20 | E.I. Dupont De Nemours And Company | Alkoxylated phosphite ester and process therefor |
EP2133383A1 (en) * | 2002-10-25 | 2009-12-16 | Hoeganaes Corporation | Method for preparing a solid lubricant composition |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1075584B (en) * | 1960-02-18 | Hooker Chemical Corporation, Niagara Falls, N. Y. (V. St. A.) | Process for the preparation of tertiary aliphatic esters of phosphorous acid |
-
1962
- 1962-04-04 GB GB12910/62A patent/GB942776A/en not_active Expired
- 1962-04-27 DE DEP29266A patent/DE1233841B/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2352823A2 (en) * | 1976-05-28 | 1977-12-23 | Hoechst Ag | ORGANIC PHOSPHITES THAT CAN BE USED TO STABILIZE POLYMERIC MATERIALS |
EP2133383A1 (en) * | 2002-10-25 | 2009-12-16 | Hoeganaes Corporation | Method for preparing a solid lubricant composition |
WO2005097810A1 (en) * | 2004-03-26 | 2005-10-20 | E.I. Dupont De Nemours And Company | Alkoxylated phosphite ester and process therefor |
US7138356B2 (en) | 2004-03-26 | 2006-11-21 | E. I. Du Pont De Nemours And Company | Alkoxylated phosphite ester and process therefor |
Also Published As
Publication number | Publication date |
---|---|
DE1233841B (en) | 1967-02-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2909559A (en) | Polymeric phosphate esters and their production | |
US3711411A (en) | Low water-sensitive hydraulic fluids containing borate esters and monoethanolamine | |
US3139450A (en) | Alkaneetherpolyol phosphonate esters | |
US3467733A (en) | Cyclic esters of phosphorus and a process for the preparation thereof | |
GB1098936A (en) | Heterocyclic compounds | |
GB1056360A (en) | Phosphorus containing polyurethane compositions | |
US3763287A (en) | Phosphorus containing derivatives of omega-(3,5-dialkyl-4-hydroxyphenyl)alkanols | |
GB944726A (en) | The production of tertiary phosphites including new cyclic phosphites | |
US2629731A (en) | Esters of phosphonoformic acids and polyhydric alcohols | |
US3714302A (en) | Preparation of neoalkyl phenyl phosphite | |
US3009939A (en) | Hydroxy propoxy propyl phosphites | |
GB1118559A (en) | Neo carboxylate tetrol diphosphites and polymers thereof | |
GB1430660A (en) | Cyclic phosphorus esters having flame retardant properties | |
GB942776A (en) | Hydroxy alkoxy alkyl phosphites | |
US3061625A (en) | Phosphates and thiophosphates | |
GB1105965A (en) | Lubricating compositions | |
GB1083324A (en) | Improvements in or relating to hydraulic fluids | |
US3254142A (en) | Phosphorous acid esters | |
US2250049A (en) | Mixed triaryl thiophosphates | |
GB1080938A (en) | Method of preparing phosphorylated polyols,and their application | |
US3437721A (en) | Phosphato-phosphorus compounds and process for preparing same | |
US3264324A (en) | Phosphonites | |
GB1102733A (en) | Halogen-rich phosphites, phosphates, thiophosphates and phosphonates | |
GB1347278A (en) | Polyalkylene glycol vinyl phosphates | |
GB988936A (en) | Process for the production of ethers of hydroxymethyl polymethyl siloxanes |