GB939878A - Heat-treated detergent compositions - Google Patents
Heat-treated detergent compositionsInfo
- Publication number
- GB939878A GB939878A GB38792/61A GB3879261A GB939878A GB 939878 A GB939878 A GB 939878A GB 38792/61 A GB38792/61 A GB 38792/61A GB 3879261 A GB3879261 A GB 3879261A GB 939878 A GB939878 A GB 939878A
- Authority
- GB
- United Kingdom
- Prior art keywords
- present
- alkyl
- mono
- composition
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 239000003599 detergent Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- -1 aryl sulphonate Chemical compound 0.000 abstract 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 2
- 239000001913 cellulose Substances 0.000 abstract 2
- 229920002678 cellulose Polymers 0.000 abstract 2
- 150000002191 fatty alcohols Chemical class 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000002002 slurry Substances 0.000 abstract 2
- 229920002554 vinyl polymer Chemical class 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000008096 xylene Substances 0.000 abstract 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229920013820 alkyl cellulose Polymers 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 abstract 1
- 229910021538 borax Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 125000004181 carboxyalkyl group Chemical group 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 239000007850 fluorescent dye Substances 0.000 abstract 1
- 239000004872 foam stabilizing agent Substances 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229940102253 isopropanolamine Drugs 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- NIXKBAZVOQAHGC-UHFFFAOYSA-N phenylmethanesulfonic acid Chemical class OS(=O)(=O)CC1=CC=CC=C1 NIXKBAZVOQAHGC-UHFFFAOYSA-N 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229920001451 polypropylene glycol Polymers 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 239000004328 sodium tetraborate Substances 0.000 abstract 1
- 235000010339 sodium tetraborate Nutrition 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000013042 solid detergent Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 125000003944 tolyl group Chemical group 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229960004418 trolamine Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A solid detergent composition comprises (a) a water soluble C8-15alkyl mono-nuclear aryl sulphonate, and (b) polyvinyl alcohol having a viscosity of 1,8-3 cps. (measured as a 4% aqueous solution at 20 DEG C.) containing 10-30% by weight of polyvinyl acetate. (a) generally comprises 5-50% of the composition and preferably contains 12-15 carbon atoms in the alkyl group while the mono-nuclear aryl group may be a toluene, xylene or phenol nucleus although benzene is preferred; the cation present may be ammonium, mono-, di- and tri-ethanolamine, or isopropanolamine, but sodium and potassium are preferred. A cellulosic compound, e.g. a carboxyalkyl cellulose, a cellulose sulphate, or an alkyl or hydroxyalkylcellulose, but most suitably sodium carboxymethylcellulose with a degree of substitution of 0,5-0,7, is preferably also included, in which case the total of cellulosic compound and polyvinyl compounds is 0,1-2% of the total solids and are present in a ratio of 20:1 to 1:20; in general however, both the cellulosic compounds (if present) and the polyvinyl compounds are present to the extent of 0,05-5%. 10-80% of such alkaline builder salts as the alkali metal pyro-, tripoly-, tetrapoly- and hexameta-phosphates, silicates (M2O:SiO2=1:1 to 1:4), borax and sodium carbonate are usually also present. Fatty acid mono- and di-ethanolamides and isopropanolamides, sodium sulphate, fatty alcohols, xylene or toluene sulphonates, alkyl sulphates and alkyl polyether sulphates, alkyl glyceryl ether sulphonates, alkylarylpolyglycol ether sulphates, ethylene oxide condensates with fatty alcohols, alkylphenols and polypropylene glycol, fluorescent dye, colour, corrosion inhibitors, bleaching agents, foam stabilizers or inhibitors, and detergency improvers may also be incorporated. The composition is suitably prepared by heat treating a slurry of the ingredients at 100 DEG -200 DEG F. for less than 3 hours, after which the mixture is spray-, roll-, or drum-dried at above 212 DEG F. to a moisture content (if spray dried) of 3-15%. If preferred, the slurry is made up with only so much water as is necessary to hydrate the hydratable salts present, when a dry solidified mass is obtained upon aging which may then be granulated. In general, the composition may be produced as beads, granules, flake, chips and powders.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66432A US3248331A (en) | 1960-11-01 | 1960-11-01 | Heat-treated detergent compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB939878A true GB939878A (en) | 1963-10-16 |
Family
ID=22069460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB38792/61A Expired GB939878A (en) | 1960-11-01 | 1961-10-30 | Heat-treated detergent compositions |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3248331A (en) |
| BE (1) | BE609041A (en) |
| CA (1) | CA688538A (en) |
| CH (1) | CH414906A (en) |
| DE (1) | DE1145735B (en) |
| DK (1) | DK106001C (en) |
| GB (1) | GB939878A (en) |
| MY (1) | MY6600097A (en) |
| NL (1) | NL270782A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3950276A (en) | 1971-09-01 | 1976-04-13 | Colgate-Palmolive Company | Sulfonate detergent compositions |
| US4006110A (en) | 1971-11-30 | 1977-02-01 | Colgate-Palmolive Company | Manufacture of free-flowing particulate heavy duty synthetic detergent composition |
| US4131558A (en) | 1975-02-14 | 1978-12-26 | The Procter & Gamble Company | Process for preparing an orthophosphate-silicate detergent product |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA797198A (en) * | 1965-05-24 | 1968-10-22 | J. Foster Donald | Heavy duty detergent compositions |
| WO2001007551A1 (en) * | 1999-07-26 | 2001-02-01 | Henkel Kommanditgesellschaft Auf Aktien | Use of polyvinyl alcohols as detergent additives capable of removing soiling |
| CN104459013A (en) * | 2014-11-27 | 2015-03-25 | 华南理工大学 | Method for testing degree of substitution of low-sodium sodium carboxymethylcellulose |
| CN104459014A (en) * | 2014-11-27 | 2015-03-25 | 华南理工大学 | Method for determining degree of substitution of sodium carboxymethylcellulose |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2755252A (en) * | 1956-07-17 | Partially-acetylated polyvinyl alco- | ||
| US2489955A (en) * | 1943-08-25 | 1949-11-29 | Colgate Palmolive Peet Co | Preparation of nondusting organic detergent compositions |
| US2798047A (en) * | 1953-02-11 | 1957-07-02 | Eastman Kodak Co | Detergent compositions for laundering textile fabrics, containing a copolymer of a lower nu-alkyl acrylamide and vinyl alcohol |
| US2897155A (en) * | 1955-07-27 | 1959-07-28 | Lever Brothers Ltd | Process for preparing a detergent composition containing anhydrous form 11 tripolyphosphate |
| US2877187A (en) * | 1955-08-10 | 1959-03-10 | Lever Brothers Ltd | Detergent containing beta, beta'-decylaminobisethanolpropionamide |
| US2870093A (en) * | 1956-01-09 | 1959-01-20 | Lever Brothers Ltd | Polyphosphate compositions containing coco-beta-alanine and 2-mercaptothiazoline |
-
0
- BE BE609041D patent/BE609041A/xx unknown
- CA CA688538A patent/CA688538A/en not_active Expired
- NL NL270782D patent/NL270782A/xx unknown
-
1960
- 1960-11-01 US US66432A patent/US3248331A/en not_active Expired - Lifetime
-
1961
- 1961-09-28 DE DEC25151A patent/DE1145735B/en active Pending
- 1961-10-04 CH CH1154561A patent/CH414906A/en unknown
- 1961-10-09 DK DK400161AA patent/DK106001C/en active
- 1961-10-30 GB GB38792/61A patent/GB939878A/en not_active Expired
-
1966
- 1966-12-31 MY MY196697A patent/MY6600097A/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3950276A (en) | 1971-09-01 | 1976-04-13 | Colgate-Palmolive Company | Sulfonate detergent compositions |
| US4006110A (en) | 1971-11-30 | 1977-02-01 | Colgate-Palmolive Company | Manufacture of free-flowing particulate heavy duty synthetic detergent composition |
| US4131558A (en) | 1975-02-14 | 1978-12-26 | The Procter & Gamble Company | Process for preparing an orthophosphate-silicate detergent product |
Also Published As
| Publication number | Publication date |
|---|---|
| DK106001C (en) | 1966-12-05 |
| NL270782A (en) | |
| BE609041A (en) | |
| CH414906A (en) | 1966-06-15 |
| CA688538A (en) | 1964-06-09 |
| DE1145735B (en) | 1963-03-21 |
| US3248331A (en) | 1966-04-26 |
| MY6600097A (en) | 1966-12-31 |
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