GB938729A - Improvements in and relating to electrically non-conducting films - Google Patents
Improvements in and relating to electrically non-conducting filmsInfo
- Publication number
- GB938729A GB938729A GB37018/60A GB3701860A GB938729A GB 938729 A GB938729 A GB 938729A GB 37018/60 A GB37018/60 A GB 37018/60A GB 3701860 A GB3701860 A GB 3701860A GB 938729 A GB938729 A GB 938729A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- copolymers
- coating
- active agent
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/044—Forming conductive coatings; Forming coatings having anti-static properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/052—Forming heat-sealable coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0075—Antistatics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/285—Phosphines; Phosphine oxides; Phosphine sulfides; Phosphinic or phosphinous acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/405—Acylated polyalkylene polyamines
Landscapes
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Packages (AREA)
- Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
- Wrappers (AREA)
Abstract
Foods, particularly greasy foods, may be wrapped or packaged in an electrically non-conducting film which has an organic thermoplastic heat-seal coating, the coating having incorporated therein a cationic surface-active agent in an amount sufficient to confer anti-static properties sufficient to lower the electrostatic propensity to no more than 5 kilovolts/foot with a charge decay half time of no more than 5 seconds. By "electrically non-conducting film" is meant a film which accumulates electrostatic charges on its surface and includes film, which may be biaxially oriented and heat set, of cellulose ester, polyethylene terephthalate and similar polyester, vinylidene chloride copolymer, crystallizable polymers and copolymers of a -olefines, including ethylene, having preferably between 2 and 6 carbon atoms in the molecule and particularly propylene which is at least 75% insoluble in boiling n-heptane, e.g. isotactic polypropylene. The film may be chemically surface-treated to improve the adhesion of the heat seal coating before the latter is applied, e.g. by corona discharge, ozone, ionizing radiation in the presence of oxygen, or chemically oxidizing agents, e.g. halogens, potassium permanganate and chromic acid. The coating may be of copolymers of vinylidene chloride with, for example, acrylonitrile, methyl or ethyl acrylates, vinyl chloride, acrylic and methacrylic acids; vinyl acetate copolymers which may conveniently contain other monomers, e.g. itaconic and citraconic acids; gelatine, polyvinyl alcohol, acetate or acetal, e.g. butyral; copolymers of butadiene with acrylonitrile, ethyl or methyl acrylates, vinylidene chloride, vinyl chloride, acrylic or methacrylic acids, or vinyl acetate; copolymers of methyl methacrylate and methacrylic acid; copolyesters of terephthalic acid and another dicarboxylic acid, e.g. an aliphatic dicarboxylic acid, with alkylene glycols particularly ethylene glycol; and N-alkoxy methyl polyamides. The cationic surface-active agent may be an amine or phosphonium salt such as a quaternary ammonium or phosphonium salt, the quaternary residue being attached to at least one long chain of carbon atoms which may have other atoms besides carbon atoms, e.g. oxygen or nitrogen atoms, in the chain or substituted on to it, and may contain at least eight carbon atoms. The long chain of carbon atoms may be an alkyl group derived from a fatty acid or alcohol, the condensate of formaldehyde or of an alkylene oxide or glycol, e.g. ethylene or propylene oxide, or a polymeric residue to which one or more quaternary ammonium or phosphonium residues are attached. The cationic surface-active agent may be the salt of a strong acid, a betaine having a chain as above attached to the betaine nucleus, polymers of acrylic acid derivatives in which the monomer has the formula CH2=C(R)CO.NH.(CH2)N+R113X-or CH2=C(R).CO.O.(CH2)nN+R113X-and compounds of formula <FORM:0938729/VI/1> and particularly compounds having the formula R1-N+R113X-; <FORM:0938729/VI/2> R1CO.N+H(CH2)nN+R113X-; or R1.CO.O(CH2)n.N+R113X-; where R is hydrogen or methyl, R1 is a long chain of carbon atoms as above, preferably C10 to C24 normal-alkyl or alkenyl, or an ethylene oxide condensate having 5 to 40 ethylene oxide residues in the chain, R11 is an alkyd or alkenyl residue which may be substituted with hydroxyl or aryl groups, or a long chain of carbon atoms as in the case of R1, n is from 1 to 10, preferably 3, and X- is an anion. N-stearoyl (g ) amino propyl dimethyl b -hydroxy ethyl ammonium salt is particularly effective. The coating may be applied from an aqueous dispersion and the cationic surface-active agent may be an emulsifying agent for the dispersion. The coating may contain an additive in addition to and other than a cationic surface-active agent, e.g. anti-oxidants, dyes, pigments, lubricants, anti-blocking agents, ultra-violet light stabilizers and slip agents such as starch, talc, zinc oxide, calcium and magnesium carbonates, diatomaceous earth, silica, kaolin, titanium dioxide, triferric tetroxide, and other inorganic oxides, carbonates, silicates, aluminates and aluminosilicates, finely dispersed polypropylene and polyvinyl chloride (particle size 0.1 to 20 microns), unsaturated and saturated fatty acid amides, such as palmitamide, stearamide, distearamide and alkylene distearamides such as methylene and ethylene distearamide; hydroxylated fatty acid amides such as hydroxystearamide, hydrogenated castor oil, ester-type waxes, ether waxes and other hard waxes. The food may be heated in the package and stored. Specification 715,914 is referred to.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL270594D NL270594A (en) | 1960-10-27 | ||
BE609692D BE609692A (en) | 1960-10-27 | ||
GB37018/60A GB938729A (en) | 1960-10-27 | 1960-10-27 | Improvements in and relating to electrically non-conducting films |
FR877280A FR1308810A (en) | 1960-10-27 | 1961-10-27 | Process for the preparation of electrically non-conductive films exhibiting anti-static properties |
CH1244361A CH477968A (en) | 1960-10-27 | 1961-10-27 | Electrically non-conductive foil and its manufacture |
ES0271558A ES271558A1 (en) | 1960-10-27 | 1961-10-27 | Improvements in and relating to electrically non-conducting films |
DE1961J0020745 DE1285744C2 (en) | 1960-10-27 | 1961-10-27 | Antistatic plastic film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB37018/60A GB938729A (en) | 1960-10-27 | 1960-10-27 | Improvements in and relating to electrically non-conducting films |
Publications (1)
Publication Number | Publication Date |
---|---|
GB938729A true GB938729A (en) | 1963-10-02 |
Family
ID=10393064
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB37018/60A Expired GB938729A (en) | 1960-10-27 | 1960-10-27 | Improvements in and relating to electrically non-conducting films |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE609692A (en) |
CH (1) | CH477968A (en) |
DE (1) | DE1285744C2 (en) |
ES (1) | ES271558A1 (en) |
FR (1) | FR1308810A (en) |
GB (1) | GB938729A (en) |
NL (1) | NL270594A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3499791A (en) * | 1965-06-10 | 1970-03-10 | Du Pont | Quaternary ammonium salt containing polyolefin covered electrical conductor |
JPS5250232B1 (en) * | 1975-07-04 | 1977-12-22 | ||
EP0085474A2 (en) * | 1982-01-30 | 1983-08-10 | Marston Palmer Ltd. | Lined fabric reinforced flexible container for potable liquids |
EP0202532A2 (en) * | 1985-05-17 | 1986-11-26 | Hoechst Aktiengesellschaft | Unsealable, bioriented multilayered polypropylene film, method of making it and its use |
EP0324494A1 (en) * | 1988-01-14 | 1989-07-19 | W.R. Grace & Co.-Conn. | Permanent antistatic acid copolymer/quaternary amine mixtures and permanent antistatic polymeric films made therefrom |
EP0397185A1 (en) * | 1989-05-12 | 1990-11-14 | W.R. Grace & Co.-Conn. | Permanently antistatic polymeric rigid containers |
EP0398353A1 (en) * | 1989-05-19 | 1990-11-22 | W.R. Grace & Co.-Conn. | Semi-rigid heat-sealable laminates with permanent antistatic characteristics |
US4999252A (en) * | 1988-01-14 | 1991-03-12 | W. R. Grace & Co.-Conn. | Permanent antistatic acid copolymer/quaternary amine mixtures films |
US5153075A (en) * | 1988-01-14 | 1992-10-06 | W. R. Grace & Co.-Conn. | Permanent antistatic acid copolymer/quaternary amine polymeric films |
US5171641A (en) * | 1988-01-14 | 1992-12-15 | W. R. Grace & Co.-Conn. | Permanent antistatic acid copolymer/quaternary amine polymeric films |
-
0
- NL NL270594D patent/NL270594A/xx unknown
- BE BE609692D patent/BE609692A/xx unknown
-
1960
- 1960-10-27 GB GB37018/60A patent/GB938729A/en not_active Expired
-
1961
- 1961-10-27 ES ES0271558A patent/ES271558A1/en not_active Expired
- 1961-10-27 DE DE1961J0020745 patent/DE1285744C2/en not_active Expired
- 1961-10-27 FR FR877280A patent/FR1308810A/en not_active Expired
- 1961-10-27 CH CH1244361A patent/CH477968A/en not_active IP Right Cessation
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3499791A (en) * | 1965-06-10 | 1970-03-10 | Du Pont | Quaternary ammonium salt containing polyolefin covered electrical conductor |
JPS5250232B1 (en) * | 1975-07-04 | 1977-12-22 | ||
EP0085474A2 (en) * | 1982-01-30 | 1983-08-10 | Marston Palmer Ltd. | Lined fabric reinforced flexible container for potable liquids |
EP0085474A3 (en) * | 1982-01-30 | 1984-07-18 | Marston Palmer Ltd. | Lined fabric reinforced flexible container for potable liquids |
EP0202532A2 (en) * | 1985-05-17 | 1986-11-26 | Hoechst Aktiengesellschaft | Unsealable, bioriented multilayered polypropylene film, method of making it and its use |
EP0202532A3 (en) * | 1985-05-17 | 1988-06-08 | Hoechst Aktiengesellschaft | Unsealable, bioriented multilayered polypropylene film, method of making it and its use |
EP0324494A1 (en) * | 1988-01-14 | 1989-07-19 | W.R. Grace & Co.-Conn. | Permanent antistatic acid copolymer/quaternary amine mixtures and permanent antistatic polymeric films made therefrom |
US4999252A (en) * | 1988-01-14 | 1991-03-12 | W. R. Grace & Co.-Conn. | Permanent antistatic acid copolymer/quaternary amine mixtures films |
US5153075A (en) * | 1988-01-14 | 1992-10-06 | W. R. Grace & Co.-Conn. | Permanent antistatic acid copolymer/quaternary amine polymeric films |
US5171641A (en) * | 1988-01-14 | 1992-12-15 | W. R. Grace & Co.-Conn. | Permanent antistatic acid copolymer/quaternary amine polymeric films |
EP0397185A1 (en) * | 1989-05-12 | 1990-11-14 | W.R. Grace & Co.-Conn. | Permanently antistatic polymeric rigid containers |
EP0398353A1 (en) * | 1989-05-19 | 1990-11-22 | W.R. Grace & Co.-Conn. | Semi-rigid heat-sealable laminates with permanent antistatic characteristics |
US5064699A (en) * | 1989-05-19 | 1991-11-12 | W. R. Grace & Co.-Conn. | Semi-rigid heat-sealable laminates with permanent antistatic characteristics |
Also Published As
Publication number | Publication date |
---|---|
NL270594A (en) | 1900-01-01 |
FR1308810A (en) | 1962-11-09 |
DE1285744C2 (en) | 1969-08-21 |
DE1285744B (en) | 1968-12-19 |
ES271558A1 (en) | 1962-03-01 |
CH477968A (en) | 1969-09-15 |
BE609692A (en) | 1900-01-01 |
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