GB1352347A - Stabilized film-forming polyolefin composition - Google Patents

Stabilized film-forming polyolefin composition

Info

Publication number
GB1352347A
GB1352347A GB2072371A GB2072371A GB1352347A GB 1352347 A GB1352347 A GB 1352347A GB 2072371 A GB2072371 A GB 2072371A GB 2072371 A GB2072371 A GB 2072371A GB 1352347 A GB1352347 A GB 1352347A
Authority
GB
United Kingdom
Prior art keywords
per cent
preferred proportion
volatilize
decompose
polyolefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2072371A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB1352347A publication Critical patent/GB1352347A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/132—Phenols containing keto groups, e.g. benzophenones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

1352347 Polyolefin compositions and paperlike films thereof UNION CARBIDE CORP 19 April 1971 [30 Jan 1970] 20723/71 Heading C3P Polyolefin compositions comprise components A, B, C and D below optionally with one or more of components E, F and G. (A) A polyolefin, e.g. high density polyethylene and/or polypropylene; preferred proportion: 45-85 wt. per cent of the composition; (B) A U.V. stabilizer comprising at least one organic compound capable of forming a sixmembered chelate ring through hydrogen bonding, and which is a solid or liquid which does not decompose or volatilize below 200‹ C., e.g. of formula wherein the various A's and B's, which may be the same or different are H or substituents (e.g. OH, Cl, But, n-octoxy); a is 1-9; and b is 1-8; preferred proportion: 0À2-2À0 wt. per cent; (C) An antistatic agent comprising at least one alkoxylated amine or amide which contains at least one saturated or unsaturated C 7 -C 22 hydrocarbon group optionally bearing one or more substituents (e.g. OH), and which does not volatilize or decompose below 200‹ C., e.g. N,N - bis - (2 - hydroxyethyl)- or N,N- bis - 3 - hydroxypropyl) - C 8 -C 22 alkylamines or -C 8 -C 22 fatty acid amides; and N-(3- dodecyloxy - 2 - hydroxypropyl) - ethanolamine; preferred proportion: 0À1-2À0 wt. per cent; (D) A thermal stabilizer comprising at least one sterically hindered phenol which does not volatilize or decompose below 200‹ C., e.g. octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate or tetrakis-[3-(3,5-di-tert-butyl-4- hydroxyphenyl) propionyloxymethyl] methane; preferred proportion: 0À02-1À0 wt. per cent; (E) A filler preferably having an average particle diameter of 0À1-15 microns, e.g. CaO, ZnO, MgCO 3 , CaSO 4 , MgSO 4 , PbSO 4 , TiO 2 , MgO, CaCO 3 , various silicas, silicates, silica-alumina or asbestos; preferred proportion: 5-45 wt. per cent; (F) A polymeric accommodation resin, e.g. a low density vinyl addition polymer or copolymer e.g. polyethylene or ethylene/vinyl acetate copolymer (many others are listed); preferred proportion 3-15 wt. per cent; (G) Unspecified flame retardants and colorants. The compositions may be formed into sheets or into paper-like films of 0À25-20 mils thickness which may be surface-treated by electrostatic discharge, flame treatment or oxidative chemical treatment.
GB2072371A 1970-01-30 1971-04-19 Stabilized film-forming polyolefin composition Expired GB1352347A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US721370A 1970-01-30 1970-01-30

Publications (1)

Publication Number Publication Date
GB1352347A true GB1352347A (en) 1974-05-08

Family

ID=21724866

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2072371A Expired GB1352347A (en) 1970-01-30 1971-04-19 Stabilized film-forming polyolefin composition

Country Status (2)

Country Link
FR (1) FR2077182A5 (en)
GB (1) GB1352347A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2156837A (en) * 1984-03-29 1985-10-16 British Telecomm Optical fibre transmission lines
WO2004009690A2 (en) * 2002-07-18 2004-01-29 Exxonmobil Chemical Patents Inc. Ultraviolet radiation stabilized polyolefins
WO2004024810A2 (en) * 2002-09-11 2004-03-25 Ciba, Specialty Chemicals Holding Inc. Stabillization of organic materials

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4049751A (en) * 1976-04-26 1977-09-20 Dart Industries Inc. Extraction resistant polyolefin stabilizers

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2156837A (en) * 1984-03-29 1985-10-16 British Telecomm Optical fibre transmission lines
WO2004009690A2 (en) * 2002-07-18 2004-01-29 Exxonmobil Chemical Patents Inc. Ultraviolet radiation stabilized polyolefins
WO2004009690A3 (en) * 2002-07-18 2004-08-12 Exxonmobil Chem Patents Inc Ultraviolet radiation stabilized polyolefins
US7259198B2 (en) 2002-07-18 2007-08-21 Exxonmobil Chemical Patents Inc. Ultraviolet radiation stabilized polyolefins
WO2004024810A2 (en) * 2002-09-11 2004-03-25 Ciba, Specialty Chemicals Holding Inc. Stabillization of organic materials
WO2004024810A3 (en) * 2002-09-11 2004-08-12 Ciba Sc Holding Ag Stabillization of organic materials
US7375149B2 (en) 2002-09-11 2008-05-20 Ciba Specialty Chemicals Corp. Stabilization of organic materials

Also Published As

Publication number Publication date
DE2103935A1 (en) 1971-08-05
DE2103935B2 (en) 1977-06-08
FR2077182A5 (en) 1971-10-15

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Legal Events

Date Code Title Description
PS Patent sealed
PLE Entries relating assignments, transmissions, licences in the register of patents
PCNP Patent ceased through non-payment of renewal fee