GB938325A - Treatment of organic thermoplastic film - Google Patents
Treatment of organic thermoplastic filmInfo
- Publication number
- GB938325A GB938325A GB2544062A GB2544062A GB938325A GB 938325 A GB938325 A GB 938325A GB 2544062 A GB2544062 A GB 2544062A GB 2544062 A GB2544062 A GB 2544062A GB 938325 A GB938325 A GB 938325A
- Authority
- GB
- United Kingdom
- Prior art keywords
- film
- interpolymers
- fluoride
- tetrafluoroethylene
- tubes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/10—Surface shaping of articles, e.g. embossing; Apparatus therefor by electric discharge treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/10—Surface shaping of articles, e.g. embossing; Apparatus therefor by electric discharge treatment
- B29C59/12—Surface shaping of articles, e.g. embossing; Apparatus therefor by electric discharge treatment in an environment other than air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/12—Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
Abstract
An organic thermoplastic polymeric film is passed on to an electrically grounded moving surface, an electrostatic charge sufficient to cause the film to adhere firmly to the moving surface is deposited on the upper surface of the film and the film, on the moving surface, is then subjected to a treatment with a high frequency electrical spark discharge to improve its adhereability while maintaining firm adhesion during the treatment. The treatment to improve adhereability may comprise passing the film through spaced positive and negative electrodes while continuously applying to the positive electrode an alternating current of 0,5-2,5 radio frequency amperes at a voltage of 10,000-100,000 volts especially 10,000-30,000 volts and p at a frequency of 100,000-1,000,000 cycles per sec. especially 300,000-500,000 cycles/sec. in an atmosphere effective to create an electrical discharge between the electrodes. An electrostatic charge of at least 0,23 microcoulombs per square inch may be deposited in a continuous and uniform manner on the upper surface of the film at least adjacent to each edge of the film. The film may be made of polytetrafluoroethylene of a copolymer of 50-95% <PICT:0938325/IV(a)/1> by weight tetrafluoroethylene and 50-5% hexafluoropropylene, of polyvinyl chloride, polypropylene, polyethylene or polyethylene terephthalate, which are preferred, or may be made of polyvinyl fluoride, polyvinylidene fluoride, vinyl fluoride/vinylidene fluoride interpolymers, polychlorotrifluoroethylene, tetrafluoroethylene/hexafluoropropylene interpolymers in general, vinyl fluoride/tetrafluoroethylene interpolymers, vinylidene fluoride/tetrafluoroethylene interpolymers, vinylidene fluoride/hexafluoropropylene interpolymers, vinyl chloride/vinyl acetate interpolymers, vinyl chloride/vinylidene chloride interpolymers, polyoxymethylene, polyacrylonitrile and polyamides. In apparatus as shown, film 11 enters chamber 12 through opening 13, passes around the electrically grounded rotatable roll 14, and leaves the chamber at 19. The film is electrostatically charged by one or more electrodes 15, which may be wire electrodes of 0,001-0,125 inch diameter, charged from a D.C. power source to 15-30 kilovolts, so as to provide sufficient charge on the upper surface of the film to force it into intimate contact with the driven roll 14. The roll may be replaced by a belt or chain. Its surface may be metallic, or it may be coated with a thin layer of polyethylene, polytetrafluoroethylene, or silica, glass, or aluminium oxide. The film then passes under one or more hollow tubes 16, 17 disposed parallel to the longitudinal axis of the roll and spaced 0,008-0,25 inch therefrom. The tubes are each connected to a power source supplying an alternating, or pulsating direct current of 0,5-2,5 radio frequency amperes at 10,000-100,000 volts and at a frequency of 100,000-1,000,000 cycles/sec. An atmosphere of nitrogen or other gas in which the electrical discharge takes place is fed to the hollow interior of the tubes through ducts 18 and issues from the tubes at narrow slots running lengthwise of each tube and facing the film. Other gaseous atmospheres specified include nitrogen and glycidyl methacrylate vapour, nitrogen and carbon tetrachloride vapour, and chlorine. Specification 829,600 and U.S.A. Specification 2,833,686 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12150461A | 1961-07-03 | 1961-07-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB938325A true GB938325A (en) | 1963-10-02 |
Family
ID=22397132
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2544062A Expired GB938325A (en) | 1961-07-03 | 1962-07-03 | Treatment of organic thermoplastic film |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE619638A (en) |
DE (1) | DE1504661C3 (en) |
GB (1) | GB938325A (en) |
LU (1) | LU41955A1 (en) |
NL (1) | NL280451A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0160889A2 (en) * | 1984-05-04 | 1985-11-13 | Hoechst Aktiengesellschaft | Method and apparatus for surface-treating sheet-material webs |
US4929319A (en) * | 1987-02-20 | 1990-05-29 | Hoechst Aktiengesellschaft | Process and device for surface pre-treatment of plastic by means of an electrical corona discharge |
US4940521A (en) * | 1988-08-16 | 1990-07-10 | Hoechst Aktiengesellschaft | Process and apparatus for pretreating the surface of a single-layer or multilayer molded material by means of an electrical corona discharge |
EP0814917A1 (en) * | 1994-02-23 | 1998-01-07 | Pilot Industries, Inc. | Fluoropolymer composite tube and method of preparation |
DE10224516A1 (en) * | 2002-05-31 | 2003-12-11 | Etifix Etiketten Gmbh | Label roll on a core element comprises a carrier strip which on its side free from labels is provided with areas with a higher coefficient of friction than the rest of the strip material |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3991365C2 (en) * | 1988-11-17 | 2001-07-19 | Gunze Kk | Process for improving the inside surface of an airtight heat-shrinkable multilayer plastic film |
-
0
- NL NL280451D patent/NL280451A/xx unknown
- BE BE619638D patent/BE619638A/xx unknown
-
1962
- 1962-06-27 LU LU41955D patent/LU41955A1/xx unknown
- 1962-07-02 DE DE19621504661 patent/DE1504661C3/en not_active Expired
- 1962-07-03 GB GB2544062A patent/GB938325A/en not_active Expired
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0160889A2 (en) * | 1984-05-04 | 1985-11-13 | Hoechst Aktiengesellschaft | Method and apparatus for surface-treating sheet-material webs |
EP0160889A3 (en) * | 1984-05-04 | 1986-02-12 | Hoechst Aktiengesellschaft | Method and apparatus for surface-treating sheet-material webs |
US4615906A (en) * | 1984-05-04 | 1986-10-07 | Hoechst Aktiengesellschaft | Method and device for surface treatment of film webs |
US4929319A (en) * | 1987-02-20 | 1990-05-29 | Hoechst Aktiengesellschaft | Process and device for surface pre-treatment of plastic by means of an electrical corona discharge |
US4940521A (en) * | 1988-08-16 | 1990-07-10 | Hoechst Aktiengesellschaft | Process and apparatus for pretreating the surface of a single-layer or multilayer molded material by means of an electrical corona discharge |
EP0814917A1 (en) * | 1994-02-23 | 1998-01-07 | Pilot Industries, Inc. | Fluoropolymer composite tube and method of preparation |
EP0814917A4 (en) * | 1994-02-23 | 1999-06-23 | Pilot Ind Inc | Fluoropolymer composite tube and method of preparation |
DE10224516A1 (en) * | 2002-05-31 | 2003-12-11 | Etifix Etiketten Gmbh | Label roll on a core element comprises a carrier strip which on its side free from labels is provided with areas with a higher coefficient of friction than the rest of the strip material |
Also Published As
Publication number | Publication date |
---|---|
NL280451A (en) | |
LU41955A1 (en) | 1962-12-27 |
BE619638A (en) | |
DE1504661B2 (en) | 1974-09-26 |
DE1504661C3 (en) | 1975-05-15 |
DE1504661A1 (en) | 1970-02-05 |
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