GB924230A - Water-soluble dyes of the phthalocyanine-azo series - Google Patents

Water-soluble dyes of the phthalocyanine-azo series

Info

Publication number
GB924230A
GB924230A GB1503661A GB1503661A GB924230A GB 924230 A GB924230 A GB 924230A GB 1503661 A GB1503661 A GB 1503661A GB 1503661 A GB1503661 A GB 1503661A GB 924230 A GB924230 A GB 924230A
Authority
GB
United Kingdom
Prior art keywords
radical
amino
group
carbonamido
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1503661A
Inventor
Arnold Tartter
Dieter Ludsteck
Rudolf Schroedel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DEB57672A external-priority patent/DE1130097B/en
Priority claimed from DEB61744A external-priority patent/DE1208020B/en
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB924230A publication Critical patent/GB924230A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/443—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being alternatively specified

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

3-(4- Chlorbutyn- (2)-ylamino-sulphonyl)-benzoic acid chloride is obtained by refluxing with thionyl chloride the corresponding acid made by reacting benzene-1-carboxylic acid-3-sulphonyl chloride with excess of 1-amino-4-chlorbutyne hydrochloride.ALSO:The invention comprises water-soluble dyes of the formula: <FORM:0924230/IV(a)/1> where P is the radical of a phthalocyanine derivative, G is -SO2-, -CO- or a sulphonamidophenylene-aminotriazine linkage wherein the sulphon radical is attached to the phthalocyanine derivative radical, R1 is hydrogen or alkyl, A is alkylene or phenylene which may be substituted by sulphonic acid or carboxylic acid groups, E is the radical of an enol capable of coupling, B is the radical of an aromatic diazo component, D is -O-, -S-, amino or ureido, or diaminotriazine group attached via the amino groups, an aminophenylene carbonamido group attached to B via the carbonamido and to X via the amino group, a sulphonamidophenylene carbonamido group attached to B via the carbonamido and to X via the sulphonamido or an amino group attached to B via -SO2- or -CO-, X is <FORM:0924230/IV(a)/2> or <FORM:0924230/IV(a)/3> where Y is chlorine or bromine, R2 is hydrogen, chlorine or bromine and n is a whole number from 1 to 4, the dye molecule containing at least one water-solubilizing radical. The dyes are made by reacting a phthalocyanine derivative containing a sulphonic acid halide, carboxylic acid halide or halogentriazinylamino group with an amine of the formula: <FORM:0924230/IV(a)/4> or with an amine of the formula <FORM:0924230/IV(a)/5> and then coupling the product with the diazo compound of an amine H2N-B-D-X; or by reacting a derivative of the formula: <FORM:0924230/IV(a)/6> where Z is hydroxy, mercapto or a primary or secondary amino group, with a compound Y-M-X where M is a direct linkage, an aminotriazine radical attached directly to Y and via the amino group to X, an aminobenzoyl or a benzoylsulphonamido group attached via the amino or sulphonamido to X and via the carbonyl to Y. The enol group E may be derived from pyrazolones, acetoacetamides or benzoylacetamides. Examples are given. The dyes dye and print wool, silk, linear polyamides, leather and, in conjunction with treatment with an acidbinding agent, native or regenerated cellulose materials in green shades.
GB1503661A 1960-04-30 1961-04-26 Water-soluble dyes of the phthalocyanine-azo series Expired GB924230A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEB57672A DE1130097B (en) 1960-04-30 1960-04-30 Process for the production of water-soluble dyes of the phthalocyanine series
DEB61744A DE1208020B (en) 1961-03-18 1961-03-18 Process for the production of water-soluble dyes of the phthalocyanine series

Publications (1)

Publication Number Publication Date
GB924230A true GB924230A (en) 1963-04-24

Family

ID=25965638

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1503661A Expired GB924230A (en) 1960-04-30 1961-04-26 Water-soluble dyes of the phthalocyanine-azo series

Country Status (2)

Country Link
BE (1) BE603299A (en)
GB (1) GB924230A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0433764A1 (en) * 1989-12-15 1991-06-26 BASF Aktiengesellschaft Reactive dyestuffs with triazin- and chlorobutinyl anchor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0433764A1 (en) * 1989-12-15 1991-06-26 BASF Aktiengesellschaft Reactive dyestuffs with triazin- and chlorobutinyl anchor

Also Published As

Publication number Publication date
BE603299A (en) 1961-11-03

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