GB914420A - Heat-sensitive recording material and process for the preparation thereof - Google Patents
Heat-sensitive recording material and process for the preparation thereofInfo
- Publication number
- GB914420A GB914420A GB536560A GB536560A GB914420A GB 914420 A GB914420 A GB 914420A GB 536560 A GB536560 A GB 536560A GB 536560 A GB536560 A GB 536560A GB 914420 A GB914420 A GB 914420A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solvent
- organic
- substantially anhydrous
- solvents
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
- C08J3/091—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/36—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
A process for preparing a heat-sensitive material adapted to receive an impression from a heat source, comprises the steps of preparing a solution of an organic thermoplastic polymer material, capable of forming a film, in a substantially anhydrous organic solvent for said organic material, adding to said solution a substantially anhydrous organic liquid which is a non-solvent precipitating liquid for the organic material and which has a boiling point which is at least 40 DEG C. higher than that of said substantially anhydrous organic solvent, the said non-solvent being added in such an amount that the pH of the resultant solution is lower than the pH of the isoelectric point of the solution of said organic thermoplastic polymer material in said organic solvent, but such that an incipient precipitation of at least a fraction of the solid phase takes place, spreading the resultant solution over a flat surface and evaporating all the liquid phases of the system until a continuous film is formed on said flat surface. The flat surface may be backing paper. The substantially anhydrous solvent is preferably a non-azeotropic mixture of substantially anhydrous organic solvents for the material, and the substantially anhydrous organic liquid is preferably a non-azeotropic mixture of substantially anhydrous organic liquid non-solvents for the material, the low-boiling component of the non-azeotropic mixture of non-solvent liquids having a higher boiling point than that of the high boiling component of the non-azeotropic mixture of substantially anhydrous organic solvents. Polymers specified are polyvinyl chloride and afterchlorinated polyvinyl chloride, natural and synthetic rubbers and chlorinated rubbers, e.g. polymerized chlorinated derivatives of isoprene and butadiene, polymers and copolymers of styrene, and polycarbonates. The films may be self-supporting or have a flexible backing. Besides paper other specified backing materials are flexible sheets of polyvinyl chloride, regenerated cellulose, polyethylene terephthalate, and polypropylene terephthalate. The solvents and non-solvents will vary according to the polymer but in the general examples of such materials given examples of solvents are dichloromethane, trichloromethane, trichloroethylene, 1,1,2-trichloroethane, tetrachloromethane, tetrachloroethylene, propylene oxide, ethyl formate, tetrahydrofurane, and tetrahydropyrane. General examples of non-solvent liquids are methanol, ethanol, propanol, butanols, amylalcohols, hexyl alcohols, octylalcohols, benzyl alcohol, cyclohexanol, furfural alcohol, tetrahydrofurfuryl alcohol, dipropylene glycol, polyglycol, 2-ethoxy ethanol and its methyl, butyl, dibutyl, and diethyl derivatives. Examples of plasticizers which may be included are dimethyl-, diethyl-, dibutyl-, diamyl- and dihexyl-phthalates, butyl-cyclohexyl phthalate, butyl-benzyl phthalate, tricresyl phosphate, alkyl-aryl phosphates, cresyl-diphenyl phosphate, diethylene glycol benzoate and dipropylene glycol dibenzoate. A secondary plasticizer, such as a chlorinated wax, may also be present. When stabilizers are used they should have melting points between 40 DEG C. and 140 DEG C. and have a multiple action as stabilizer, sequestrant, and lubricant. Examples given are metallic soaps, e.g. stearates of aluminium, calcium, magnesium, zinc, tin, lead, lithium and bismuth and ricinoleates of calcium, barium, cadmium and zinc. Small amounts, e.g. 1% of a phosphite or epoxy resin may be used in conjunction therewith. Several examples are provided illustrating the preparation of heat-sensitive films from the various materials mentioned above. The examples also illustrate the failure to obtain satisfactory heat-sensitive films if the requirements as to pH and gradient of boiling points of solvent and non-solvent are not complied with. In Example 5 the polymer is a mixture of polyvinyl chloride and polycarbonate; in Example 7 the polymer is a vinyl chloridevinylidine chloride copolymer, the solvent is ethyl formate and the stabilizer phenyl salicilate. The heat-sensitivity of the recording material produced according to the invention is due to its structure. The material comprises a plurality of translucent micellar particles of a thermoplastic polymeric organic material obtained by evaporating the solvent from a solution of the thermoplastic polymeric organic material, admixed to a second plurality of opaque particles of the thermoplastic polymeric organic material obtained by adding to the solution an organic liquid non-solvent for the material, the particles of the first and second plurality being close to one another substantially without discontinuity between adjacent particles of the same plurality and between adjacent particles of different pluralities, so as to form a continuous opaque film capable of changing its optical behaviour by the application of thermo energy. The material produced in Example 4 from a polycarbonate is tested with a recorder of the electro-cardiograph type. Specification 705,417 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT1960859 | 1959-11-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB914420A true GB914420A (en) | 1963-01-02 |
Family
ID=11159491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB536560A Expired GB914420A (en) | 1959-11-25 | 1960-02-15 | Heat-sensitive recording material and process for the preparation thereof |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1209127B (en) |
GB (1) | GB914420A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
HUP1100410A2 (en) * | 2011-08-01 | 2013-03-28 | Bela Bognar | Process and installation for preparation of solid combustible made of waste water suludge |
-
1960
- 1960-02-15 GB GB536560A patent/GB914420A/en not_active Expired
- 1960-02-16 DE DEE18913A patent/DE1209127B/en active Pending
Also Published As
Publication number | Publication date |
---|---|
DE1209127B (en) | 1966-01-20 |
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