GB913909A - Amine-alkylene oxide-monocarboxylic acid condensation products - Google Patents
Amine-alkylene oxide-monocarboxylic acid condensation productsInfo
- Publication number
- GB913909A GB913909A GB7363/60A GB736360A GB913909A GB 913909 A GB913909 A GB 913909A GB 7363/60 A GB7363/60 A GB 7363/60A GB 736360 A GB736360 A GB 736360A GB 913909 A GB913909 A GB 913909A
- Authority
- GB
- United Kingdom
- Prior art keywords
- moles
- organic acid
- polyamine
- phpa
- elevated temperatures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007859 condensation product Substances 0.000 title abstract 4
- 229920000768 polyamine Polymers 0.000 abstract 15
- -1 polyhexamethylene Polymers 0.000 abstract 12
- 150000007524 organic acids Chemical class 0.000 abstract 11
- 125000002947 alkylene group Chemical group 0.000 abstract 8
- 239000000203 mixture Substances 0.000 abstract 7
- 239000000047 product Substances 0.000 abstract 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 6
- 238000006243 chemical reaction Methods 0.000 abstract 4
- 230000008030 elimination Effects 0.000 abstract 4
- 238000003379 elimination reaction Methods 0.000 abstract 4
- 230000003993 interaction Effects 0.000 abstract 3
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 239000010426 asphalt Substances 0.000 abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 2
- 238000005553 drilling Methods 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 239000003129 oil well Substances 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000007983 Tris buffer Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- MRNZSTMRDWRNNR-UHFFFAOYSA-N bis(hexamethylene)triamine Chemical compound NCCCCCCNCCCCCCN MRNZSTMRDWRNNR-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000010687 lubricating oil Substances 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- 239000000025 natural resin Substances 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- 238000007127 saponification reaction Methods 0.000 abstract 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/16—Amines or polyamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/82—Oil-based compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/03—Specific additives for general use in well-drilling compositions
- C09K8/035—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/32—Non-aqueous well-drilling compositions, e.g. oil-based
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/044—Polyamides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/045—Polyureas; Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A composition suitable for dewatering sands encountered in oil-well drilling is obtained by adding to mineral oil condensation products obtained by the interaction of a polyhexamethylene polyamine with an alkylene oxide and a monocarboxylic organic acid (see Group IV(b)).ALSO:The invention comprises condensation products obtained by the interaction of a polyhexamethylene polyamine (PHPA) as hereinafter defined with an alkylene oxide (AO) and a monocarboxylic organic acid as hereinafter defined, said products having the formula:-(1) PHPA.nAO.mAc or (2) PHPA.nAc.mAO, in which n and m are integers such that n + m is equal to or less than b, b representing the number of hydrogen atoms attached to the nitrogen atoms of the molecule of polyhexamethylene polyamine, and Ac represents the acyl radicals derived from the monocarboxylic organic acid with loss of water, and wherein formula (1) represents the mixture of products obtained by the addition of n moles of alkylene oxide to one mole of polyhexamethylene polyamine at elevated temperatures followed by reaction with m moles of the monocarboxylic organic acid at elevated temperatures with elimination of m moles of water, and formula (2) represents the mixture of products obtained by the reaction of n moles of a monocarboxylic organic acid with one mole of the polyhexamethylene polyamine at elevated temperatures with elimination of n moles of water followed by the addition of m moles of alkylene oxide at elevated temperatures. The polyhexamethylene polyamine (PHPA) is defined as NH2[(CH2)6NH]a(CH2)6NH2, where a is from 1 to 6, and is exemplified by bis(hexamethylene)triamine and tris(hexamethylene)tetramine. The polyhexamethylene polyamine may also be used in admixture with other polyamines, provided that these are present in minor amount. The monocarboxylic organic acid is defined as any saturated or unsaturated carboxylic acid of the aliphatic or cycloaliphatic series, and is exemplified by stearic, oleic, linoleic and abietic acids, or by mixtures thereof as obtained by the saponification of natural resins or rosins. Suitable alkylene oxides are ethylene oxide and propylene oxide, or mixtures thereof. The products may be added to bitumen or to lubricating oils, the latter then being used for dewatering sands encountered in oil-well drilling.ALSO:Bitumen intended for coating roadstone is admixed with condensation products obtained by the interaction of a polyhexamethylene polyamine (PHPA) as hereinafter defined with an alkylene oxide (AO) and a monocarboxylic organic acid as hereinafter defined, said products having the formula:- (1) PHPA n AO m Ac or (2) PHPA. n Ac. m AO in which n and m are integers such that n + m is equal to or less than b, b representing the number of hydrogen atoms attached to the nitrogen atoms of the molecule of polyhexamethylene polyamine, and Ac represents the acyl radicals derived from the monocarboxylic organic acid with loss of water, and wherein formula (1) represents the mixture of products obtained by the addition of n moles of alkylene oxide to one mole of polyhexamethylene polyamine at elevated temperatures followed by reaction with m moles of the monocarboxylic organic acid at elevated temperatures with elimination of m moles of water, and formula (2) represents the mixture of products obtained by the reaction of n moles of a monocarboxylic organic acid with one mole of the polyhexamethylene polyamine at elevated temperatures with elimination of n moles of water followed by the addition of m moles of alkylene oxide at elevated temperatures. The polyhexamethylene polyamine (PHPA) is defined as NH2 [(CH2)6 NH] a (CH2)6 NH2 where a is from 1 to 6, and this polyamine may also be used in admixture with minor amounts of other polyamines. The monocarboxylic organic acid is defined as any saturated or unsaturated carboxylic acid of the aliphatic or cycloaliphatic series.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL261877D NL261877A (en) | 1960-03-02 | ||
| GB7363/60A GB913909A (en) | 1960-03-02 | 1960-03-02 | Amine-alkylene oxide-monocarboxylic acid condensation products |
| FR854389A FR1287627A (en) | 1960-03-02 | 1961-03-02 | Condensation products of a polyhexamethylene polyamine, an alkylene oxide and a monocarboxylic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB7363/60A GB913909A (en) | 1960-03-02 | 1960-03-02 | Amine-alkylene oxide-monocarboxylic acid condensation products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB913909A true GB913909A (en) | 1962-12-28 |
Family
ID=9831688
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7363/60A Expired GB913909A (en) | 1960-03-02 | 1960-03-02 | Amine-alkylene oxide-monocarboxylic acid condensation products |
Country Status (2)
| Country | Link |
|---|---|
| GB (1) | GB913909A (en) |
| NL (1) | NL261877A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0077632A1 (en) * | 1981-10-21 | 1983-04-27 | Morton Thiokol, Inc. | Compositions comprising a bituminous material and an epoxylated amine asphalt anti-stripping agent, aggregate coated therewith and substrates coated with said aggregate |
| WO2003015523A3 (en) * | 2001-08-08 | 2003-10-02 | Schlumberger Ca Ltd | Methods for dewatering shaly subterranean formations |
-
0
- NL NL261877D patent/NL261877A/xx unknown
-
1960
- 1960-03-02 GB GB7363/60A patent/GB913909A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0077632A1 (en) * | 1981-10-21 | 1983-04-27 | Morton Thiokol, Inc. | Compositions comprising a bituminous material and an epoxylated amine asphalt anti-stripping agent, aggregate coated therewith and substrates coated with said aggregate |
| WO2003015523A3 (en) * | 2001-08-08 | 2003-10-02 | Schlumberger Ca Ltd | Methods for dewatering shaly subterranean formations |
Also Published As
| Publication number | Publication date |
|---|---|
| NL261877A (en) |
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