GB905051A - Alkylation transalkylation process - Google Patents
Alkylation transalkylation processInfo
- Publication number
- GB905051A GB905051A GB18049/60A GB1804960A GB905051A GB 905051 A GB905051 A GB 905051A GB 18049/60 A GB18049/60 A GB 18049/60A GB 1804960 A GB1804960 A GB 1804960A GB 905051 A GB905051 A GB 905051A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkylation
- boron trifluoride
- modified
- aromatic hydrocarbon
- transalkylation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
- C07C2/68—Catalytic processes with halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/12—Fluorides
- C07C2527/1213—Boron fluoride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Aromatic hydrocarbons are mono-alkylated by reactng an excess with an alkylating agent in the presence of boron trifluoride and a boron trifluoride-modified, solid, refractory inorganic oxide to effect alkylation, adding to the effluent a recycle stream of polyalkylated aromatic hydrocarbon and passing with boron trifluoride over a boron trifluoride modified inorganic oxide to effect transalkylation and recovering from the product unreacted aromatic hydrocarbon which is recycled to the alkylation, monoalkylated hydrocarbon product and polyalkyl hydrocarbon which is recycled to the transalkylation. The aromatic hydrocarbon may have one or more rings and may contain alkyl groups and the alkylation agent may be an olefin, polyolefin, cycloolefin, acetylene or an alkyl ester e.g. alkyl halide, sulphate or phosphate, and may be diluted with nonreactive components, e.g. in a refinery stream. The alkylation of benzene with ethylene is exemplified. The molar ratio of aromatic to alkylating agent may be 4-20:1 and boron trifluoride is added in amounts of 0.1 milligram to 0.8 gram per gram mol of alkylating agent. An inert diluent may be present. The inorganic oxide may be of aluminium, zirconium, silicon, magnesium, boron, phosphorus, mixtures of such oxides or diatomaceous earth or bauxite and may be premodified or modified in situ during the reaction. The alkylation may be effected at 50-250 DEG C., 1-100 atmospheres maintaining the aromatic hydrocarbon liquid, and a space velocity of 0.1-20 vol./vol./hr. The transalkylation is preferably effected under more severe conditions, e.g. at a higher p temperature in the range 100-300 DEG C., by adding further boron trifluoride or by using more modified oxide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US81557559A | 1959-05-25 | 1959-05-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB905051A true GB905051A (en) | 1962-09-05 |
Family
ID=25218205
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB18049/60A Expired GB905051A (en) | 1959-05-25 | 1960-05-23 | Alkylation transalkylation process |
Country Status (4)
Country | Link |
---|---|
CH (1) | CH410885A (en) |
DK (1) | DK103014C (en) |
ES (1) | ES258338A1 (en) |
GB (1) | GB905051A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1277231B (en) * | 1964-03-21 | 1968-09-12 | Universal Oil Prod Co | Process for the preparation of monoalkylated aromatic hydrocarbons |
-
1960
- 1960-05-23 GB GB18049/60A patent/GB905051A/en not_active Expired
- 1960-05-24 ES ES0258338A patent/ES258338A1/en not_active Expired
- 1960-05-24 DK DK203960AA patent/DK103014C/en active
- 1960-05-25 CH CH601560A patent/CH410885A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1277231B (en) * | 1964-03-21 | 1968-09-12 | Universal Oil Prod Co | Process for the preparation of monoalkylated aromatic hydrocarbons |
Also Published As
Publication number | Publication date |
---|---|
ES258338A1 (en) | 1960-11-16 |
CH410885A (en) | 1966-04-15 |
DK103014C (en) | 1965-11-08 |
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