GB901166A - Improvements in methods of and apparatus for activating aluminium and producing organic derivatives therefrom - Google Patents
Improvements in methods of and apparatus for activating aluminium and producing organic derivatives therefromInfo
- Publication number
- GB901166A GB901166A GB38893/58A GB3889358A GB901166A GB 901166 A GB901166 A GB 901166A GB 38893/58 A GB38893/58 A GB 38893/58A GB 3889358 A GB3889358 A GB 3889358A GB 901166 A GB901166 A GB 901166A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- activated
- reaction
- inlet
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052782 aluminium Inorganic materials 0.000 title abstract 6
- 239000004411 aluminium Substances 0.000 title abstract 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract 4
- 230000003213 activating effect Effects 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 abstract 5
- 150000001398 aluminium Chemical class 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- -1 halogen hydrides Chemical class 0.000 abstract 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 230000004913 activation Effects 0.000 abstract 2
- 239000012190 activator Substances 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 239000011261 inert gas Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- RVHSTXJKKZWWDQ-UHFFFAOYSA-N 1,1,1,2-tetrabromoethane Chemical compound BrCC(Br)(Br)Br RVHSTXJKKZWWDQ-UHFFFAOYSA-N 0.000 abstract 1
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000005234 alkyl aluminium group Chemical group 0.000 abstract 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 239000001273 butane Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 238000007865 diluting Methods 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000012263 liquid product Substances 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 150000002899 organoaluminium compounds Chemical class 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/065—Aluminium compounds with C-aluminium linkage compounds with an Al-H linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/14—Treatment of metallic powder
- B22F1/145—Chemical treatment, e.g. passivation or decarburisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treating Waste Gases (AREA)
Abstract
Aluminium to be used in the preparation of organo-aluminium compounds is activated by reaction with one or more halogens, halogen hydrides or organic substances containing labile halogen atoms, and the resulting aluminium halide separated from the aluminium. Chlorine and hydrochloric acid are the preferred reagents and when using these the aluminium trichloride formed can be easily volatilized: tetrachlorethane and tetrabromethane may also be used. The rate of the activation reaction may be controlled by diluting the activator with an inert gas such as nitrogen, argon, propane or butane, or by lowering the pressure at which the reaction <FORM:0901166/IV (b)/1> is conducted. The activation and conversion of the activated aluminium into say, alkyl aluminium compounds may be conducted in the apparatus shown. Aluminium shot is stored in a hopper 1, the lower part 2 of which is cylindrical and surrounded by a furnace 5. The part 2 is provided with an inlet 6 for an inert gas, an inlet 7 for the introduction of the halogen activator and an outlet 8 for removal of aluminium halide and gases formed. The activated aluminium passes via an air lock 4 into the reaction tower 3. At the bottom of the tower is a perforated plate 11 on which the charge lies, liquid products 12 falling through the plate and being drawn off. The organic substance which is to react with the activated aluminium enters at 14 and is pumped via 16 to a sprinkler 18. An inlet 19 allows for the introduction of a gas such as hydrogen.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR752961 | 1957-12-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB901166A true GB901166A (en) | 1962-07-18 |
Family
ID=8705207
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB38893/58A Expired GB901166A (en) | 1957-12-03 | 1958-12-02 | Improvements in methods of and apparatus for activating aluminium and producing organic derivatives therefrom |
Country Status (2)
| Country | Link |
|---|---|
| ES (1) | ES245720A1 (en) |
| GB (1) | GB901166A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3764664A (en) * | 1970-06-19 | 1973-10-09 | Sumitomo Chemical Co | Process for the production of active anhydrous aluminum chloride |
-
1958
- 1958-12-02 GB GB38893/58A patent/GB901166A/en not_active Expired
- 1958-12-02 ES ES0245720A patent/ES245720A1/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3764664A (en) * | 1970-06-19 | 1973-10-09 | Sumitomo Chemical Co | Process for the production of active anhydrous aluminum chloride |
Also Published As
| Publication number | Publication date |
|---|---|
| ES245720A1 (en) | 1959-06-16 |
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