GB899558A - Improvements in or relating to chemical processes - Google Patents
Improvements in or relating to chemical processesInfo
- Publication number
- GB899558A GB899558A GB22186/59A GB2218659A GB899558A GB 899558 A GB899558 A GB 899558A GB 22186/59 A GB22186/59 A GB 22186/59A GB 2218659 A GB2218659 A GB 2218659A GB 899558 A GB899558 A GB 899558A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium borohydride
- liquid
- major component
- dichloroborane
- linear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000001311 chemical methods and process Methods 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 7
- 229920000570 polyether Polymers 0.000 abstract 7
- 229910000033 sodium borohydride Inorganic materials 0.000 abstract 7
- 239000012279 sodium borohydride Substances 0.000 abstract 7
- 239000007788 liquid Substances 0.000 abstract 6
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 4
- 238000006243 chemical reaction Methods 0.000 abstract 4
- 239000000376 reactant Substances 0.000 abstract 3
- 239000012429 reaction media Substances 0.000 abstract 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 2
- GNWFRVXIAJTNAO-UHFFFAOYSA-N ClBCl.CN(C)C Chemical compound ClBCl.CN(C)C GNWFRVXIAJTNAO-UHFFFAOYSA-N 0.000 abstract 2
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 abstract 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 abstract 2
- 150000001983 dialkylethers Chemical class 0.000 abstract 2
- LHCGBIFHSCCRRG-UHFFFAOYSA-N dichloroborane Chemical compound ClBCl LHCGBIFHSCCRRG-UHFFFAOYSA-N 0.000 abstract 2
- 150000008282 halocarbons Chemical class 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920001223 polyethylene glycol Polymers 0.000 abstract 2
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical class OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 abstract 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract 2
- 229910015900 BF3 Inorganic materials 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical class B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
- C01B6/10—Monoborane; Diborane; Addition complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
Abstract
A process for carrying out reactions in which sodium borohydride is a reactant comprises using as a reaction medium a liquid, a minor proportion of which comprises one or more linear polyethers and a major component of which is a liquid in which sodium borohydride is substantially insoluble. The linear polyether may be derived from diethylene, triethylene and tetraethylene glycols or di-, tri- and tetra-1:2-propylene glycols, dialkyl ethers of diethylene glycol, e.g. the dimethyl ether, being preferred. Preferably the linear polyether constitutes 1-20% by weight of the major component. The major component may be more volatile than the linear polyether component and may have a boiling point below 120 DEG C. Specified major components are dimethyl ether, diethyl ether, tetrahydrofuran and tetrahydropyran and mixtures thereof, dioxan, hydrocarbons and halogenated hydrocarbons. If desired the reactants may be brought together in the liquid which is the major component and thereafter the linear polyether may be added thereto. In examples the use of sodium borohydride is described for the preparation of (1) diborane, (2) dichloroborane and (3) trimethylamine dichloroborane. Specification 873,267 is referred to.ALSO:A process for carrying out reactions in which sodium borohydride is a reactant comprises using as a reaction medium a liquid, a minor proportion of which comprises one or more linear polyethers and a major component of which is a liquid in which sodium borohydride is substantially insoluble. The linear polyether may be derived from diethylene, triethylene and tetraethylene glycols or di-, tri- and tetra-1 : 2-propylene glycols, dialkyl ethers of diethylene glycol, e.g. the dimethyl ether, being preferred. The major component of the liquid reaction medium may be a mono-ether, e.g. dimethyl or diethyl ether, tetrahydrofuran and tetrahydropyran, and mixtures thereof or dioxan or a hydrocarbon, such as a saturated aliphatic or aromatic hydrocarbon, or a petroleum fraction, or a halogenated hydrocarbon. Specified reactions involving sodium borohydride are (1) with boron trifluoride to produce diborane, (ii) with the appropriate quantity of boron trichloride to give etherates of partially chlorinated boranes and (iii) those reactions involving esters, aldehydes, ketones and ethylenic compounds. Examples describe the use of sodium borohydride to produce dichloroborane etherate which is reacted with trimethylamine to give trimethylamine dichloroborane. Specification 873,267 is referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB22186/59A GB899558A (en) | 1959-06-29 | 1959-06-29 | Improvements in or relating to chemical processes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB22186/59A GB899558A (en) | 1959-06-29 | 1959-06-29 | Improvements in or relating to chemical processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB899558A true GB899558A (en) | 1962-06-27 |
Family
ID=10175341
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB22186/59A Expired GB899558A (en) | 1959-06-29 | 1959-06-29 | Improvements in or relating to chemical processes |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB899558A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4153672A (en) * | 1978-07-21 | 1979-05-08 | Union Carbide Corporation | Synthesis of tetradecahydroundecaborate (-1) from borohydride ion |
-
1959
- 1959-06-29 GB GB22186/59A patent/GB899558A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4153672A (en) * | 1978-07-21 | 1979-05-08 | Union Carbide Corporation | Synthesis of tetradecahydroundecaborate (-1) from borohydride ion |
| EP0007599A1 (en) * | 1978-07-21 | 1980-02-06 | Union Carbide Corporation | Synthesis of tetradecahydroundecaborate(-1) from borohydride ion |
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