GB882742A - Anhydrous germicidal compositions - Google Patents

Anhydrous germicidal compositions

Info

Publication number
GB882742A
GB882742A GB5757/60A GB575760A GB882742A GB 882742 A GB882742 A GB 882742A GB 5757/60 A GB5757/60 A GB 5757/60A GB 575760 A GB575760 A GB 575760A GB 882742 A GB882742 A GB 882742A
Authority
GB
United Kingdom
Prior art keywords
oxyethylene groups
averaging
per mol
groups per
ammonium bromide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5757/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chesebrough Ponds Inc
Original Assignee
Chesebrough Ponds Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chesebrough Ponds Inc filed Critical Chesebrough Ponds Inc
Publication of GB882742A publication Critical patent/GB882742A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cosmetics (AREA)

Abstract

An anhydrous liquid germicidal shampoo comprises at least 60% by weight of the composition of (a) a white mineral oil preferably of the type used for pharmaceutical preparations and preferably in an amount of 60 to 95% by weight, (b) a non-ionic emulsifier which is soluble in both the white oil and the water, preferably in an amount of about 1 to 10% by weight, and (c) a germicide which is soluble both in the white mineral oil and water, preferably in an amount of 0,5 to 1,5% by weight. There may also be incorporated a solubilizing agent for enhancing the solubility of the germicide in the white mineral oil, preferably in an amount of 1 to 10% by weight. Specified solubilizing agents are high molecular weight aliphatic alcohols and mixtures thereof, such, for example, as lauryl alcohol, cetyl alcohol and octyl dodecanol and high molecular weight glycols and mixtures thereof, such, for example, as ethylhexylene glycol. The germicide may be a quaternary ammonium compound, a chlorophenol or an alkylchlorophenol, a labile disulphide, an organic peroxide or a chloroamine. The emulsifier may be those formed by the reaction of acids such as myristic, stearic, palmitic, lauric and oleic with polyhydroxy compounds such as polyglycols, glycerol, polyglycerols, erythritol, pentaerythritol, the hexitans and hexitols, and with ethylene oxide to form partial esters of polyoxyethylene ethers and polyoxyethylene ethers of partial esters. Preferred among these are the polyoxyethylene ethers of hexitan partial esters of fatty acids having from 12 to 18 carbon atoms wherein the ratio of oxyethylene groups to fatty acids radicals is from 3 to 8, and partial esters of fatty acids having from 12 to 18 carbon atoms with polyoxyethylene ethers of hexitols wherein the ratio of oxyethylene groups to fatty acid radicals is from 3 to 8. Specified emulsifiers of this type are polyoxyethylene sorbitan monostearate averaging 4 oxyethylene groups per mol, polyoxyethylene sorbitan monooleate averaging 5 oxyethylene groups per mol, polyoxyethylene mannitan monolaurate averaging 3 oxyethylene groups per mol polyoxyethylene sorbitan tristerarate averaging 20 oxyethylene groups per mol, polyexyethylene sorbitan trioleate averaging 20 oxyethylene groups per mol, polyoxyethylene sorbitan monopalmitate averaging 16 oxyethylene groups per mol, hexaoleate of polyoxyethylene sorbitol averaging 30 oxyethylene groups per mol, mono-laurate of polyoxyethylene sorbitan averaging 3 oxyethylene groups per mol, mono-palmitate of polyoxyethylene sorbitan averaging 6 oxyethylene groups per mol. The emulsifier may also be a polyether alcohol of the general formula R-(O CnH2n)x-OH wherein R is an aryl, aralkyl or saturated aliphatic group having from 10 to 20 carbon atoms, n is 2 and x is an integer of 2 to 20. The preferred emulsifers of this type are alkylaryl polyether alcohols in which R is essentially nonyl phenyl, m is 2 and x averages about 4 1/2 . Specified germicides are alkyl ammonium halides such as cetyl trimethyl ammonium bromide, octadecyl dimethyl ethyl ammonium bromide, octadecenyl dimethyl ethyl ammonium bromide, and dioctadecyl dimethyl ammonium chloride, alkylaryl ammonium halides in which the aryl group may be phenyl, benzyl, xylyl such as the long-chain alkyl dimethyl benzyl ammonium chlorides in teneral, including octadecyl dimethyl benzyl ammonium bromide and lauryl dimethyl benzyl ammonium chloride, cetylbenzyldimethyl ammonium bromide, an alkylbenzyldimethyl ammonium bromide in which the alkyl group averages about 14 carbon atoms, dioctylbenzylmethyl ammonium bromide and trioctylmethyl ammonium bromide, p.chloro meta xylenol, hexachlorphene, 2,21methylene bis (3,4,6-trichlorophenol), and hydroxy chlorodiphenyl methane, dibenzoyl peroxide, dinonyl dibenzoyl peroxide, and tetramethyl thiuram disulphide.ALSO:An anhydrous liquid germicidal composition, cosmetic, hair preparation, or pharmaceutical preparation comprises at least 60% by weight of the composition of a white mineral oil preferably of the type used for pharmaceutical preparations preferably in an amount of 60 to 95% by weight, a non-ionic emulsifier which is soluble in both the white oil and the water and preferably in about 1 to 10% by weight, and a germicide which is soluble both in the white mineral oil and water and preferably in an amount of 0.5 to 1.5% by weight. There may also be incorporated a solubilizing agent for enhancing the solubility of the germicide in the white mineral oil preferably in an amount of 1 to 10% by weight. Specified solubilizing agents are high molecular weight aliphatic alcohols and mixtures thereof, such, for example, as lauryl alcohol, cetyl alcohol and octyl dodecanol and high molecular weight glycols and mixtures thereof such, for example, as ethylhexylene glycol. The germicide may be a quaternary ammonium compound, a chlorophenol or an alkylchlorophenol, a labile disulphide, an organic peroxide or a chloroamine. The emulsifier may be those formed by the reaction of acids such as myristic, stearic, palmitic, lauric and oleic with polyhydroxy compounds such as polyglycols, glycerol, polyglycerols, erythritol, pentaerythritol, the hexitans and hexitols and with ethylene oxide to form partial esters of polyoxyethylene ethers and polyoxyethylene ethers of partial esters. Preferred among these are the polyoxyethylene ethers of hexitan partial esters of fatty acids having from 12 to 18 carbon atoms wherein the ratio of oxyethylene groups to fatty acids radicals is from 3 to 8, and partial esters of fatty acids having from 12 to 18 carbon atoms with polyoxyethylene ethers of hexitols wherein the ratio of oxyethylene groups to fatty acid radicals is from 3 to 8. Specified emulsifiers of this type are polyoxyethylene sorbitan mono-stearate averaging 4 oxyethylene groups per mol., polyoxyethylene sorbitan mono-oleate averaging 5 oxyethylene groups per mol., polyoxyethylene mannitan monolaurate averaging 3 oxyethylene groups per mol., polyoxyethylene sorbitan tristearate averaging 20 oxyethylene groups per mol., polyoxyethylene sorbitan trioleate averaging 20 oxyethylene groups per mol., polyoxyethylene sorbitan monopalmitate averaging 16 oxyethylene groups per mol., hexaoleate of polyoxyethylene sorbitol averaging 30 oxyethylene groups per mol., mono-laurate of polyoxyethylene sorbitan averaging 3 oxyethylene groups per mol., mono-palmitate of polyoxyethylene sorbitan averaging 6 oxyethylene groups per mol. The emulsifier may also be a polyether alcohol of the general formula R-(OCnH2n)x-OH wherein R is an aryl, aralkyl or saturated aliphatic group having from 10 to 20 carbon atoms, n is 2 and x is an integer of 2 to 20. The preferred emulsifiers of this type are alkyl-aryl polyether alcohols in which R is essentially nonyl phenyl, m is 2 and x averages about 4 1/2 e.g. Triton (Registered Trade Mark) Specified germicides are alkyl ammonium halides such as cetyl trimethyl ammonium bromide, octadecyl dimethyl ethyl ammonium bromide, octadecenyl dimethyl ethyl ammonium bromide, and dioctadecyl dimethyl ammonium chloride, alkylaryl ammonium halides in which the aryl group may be phenyl, benzyl, xylyl such as the long-chain alkyl dimethyl benzyl ammonium chlorides in general, including octadecyl dimethyl benzyl ammonium bromide and lauryl dimethyl benzyl ammonium chloride, cetylbenzyldimethyl ammonium bromide, an alkylbenzyldimethyl ammonium bromide in which the alkyl group averages about 14 carbon atoms, dioctylbenzylmethyl ammonium bromide and trioctylmethyl ammonium bromide, p-chloro meta xylenol, hexachlorophene, 2,21 - methylene bis (3,4,6-trichlorophenol), and hydroxy chloro-diphenyl methane, dibenzoyl peroxide, dinonyl dibenzoyl peroxide, and tetramethyl thiuram disulphide.
GB5757/60A 1959-02-19 1960-02-18 Anhydrous germicidal compositions Expired GB882742A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US882742XA 1959-02-19 1959-02-19

Publications (1)

Publication Number Publication Date
GB882742A true GB882742A (en) 1961-11-22

Family

ID=22210417

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5757/60A Expired GB882742A (en) 1959-02-19 1960-02-18 Anhydrous germicidal compositions

Country Status (1)

Country Link
GB (1) GB882742A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008058720A1 (en) * 2006-11-17 2008-05-22 Beiersdorf Ag Cosmetic preparations containing guerbet alcohols
US8198326B2 (en) 2004-09-07 2012-06-12 3M Innovative Properties Company Phenolic antiseptic compositions and methods of use
US9028852B2 (en) 2004-09-07 2015-05-12 3M Innovative Properties Company Cationic antiseptic compositions and methods of use
WO2017075681A1 (en) * 2015-11-06 2017-05-11 Oxiteno S.A. Indústria E Comércio Liquid thickener composition for cosmetic formulations for skin and hair cleansing, and for surface and fabric cleaners, and use of the liquid thickener composition

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8198326B2 (en) 2004-09-07 2012-06-12 3M Innovative Properties Company Phenolic antiseptic compositions and methods of use
US9028852B2 (en) 2004-09-07 2015-05-12 3M Innovative Properties Company Cationic antiseptic compositions and methods of use
US10016501B2 (en) 2004-09-07 2018-07-10 3M Innovative Properties Company Cationic antiseptic compositions and methods of use
WO2008058720A1 (en) * 2006-11-17 2008-05-22 Beiersdorf Ag Cosmetic preparations containing guerbet alcohols
WO2017075681A1 (en) * 2015-11-06 2017-05-11 Oxiteno S.A. Indústria E Comércio Liquid thickener composition for cosmetic formulations for skin and hair cleansing, and for surface and fabric cleaners, and use of the liquid thickener composition

Similar Documents

Publication Publication Date Title
EP0451002B1 (en) Clear antiperspirant stick
US9326923B2 (en) Water-in-oil-type skin-whitening cosmetic
IT1141625B (en) NON-IONIC SURFACTANTS PROCEDURE FOR THEIR PREPARATION AND COMPOSITIONS CONTAINING THEM
SK11993A3 (en) External preparation containing cyclosporin
JPH05213715A (en) Stable water in oil type emulsion
US8911715B2 (en) L-menthyl-N-(2-hydroxyphenyl)carbamate
JPH0219342A (en) Production of nonionic surfactant, skin treatment and cosmetic preparation, and paint and wood preservatives
JPH0332534B2 (en)
GB882742A (en) Anhydrous germicidal compositions
US3668136A (en) Compatible anionic-catonic surfactant compositions
WO2016132270A1 (en) Stable ready to use cyclophosphamide liquid formulations
KR870001865A (en) Water-based acidic acid containing urethane
US8080581B2 (en) Cosmetics
KR20150120298A (en) Cleansing cosmetics
SE451666B (en) STABLE BENZOYL PEROXIDE COMPOSITION
ES2211841T3 (en) AGENTS FOR THE FIGHT AGAINST MICROORGANISMS THAT HAVE EFFECTIVE CONTENT OF POLYGLYCERINE ESTERS.
KR20180126036A (en) An aqueous emulsion comprising an amino-functional organopolysiloxane and a non-ionic emulsifier
GB1230413A (en)
CA1121729A (en) Citrate or lactate or tartrate of alkylene-ols in aqueous antiperspirant
US4474912A (en) Stable water-in-oil emulsions containing polyoxyalkylene block copolymers
AU2018230712B2 (en) Topical compositions containing synthetic esters of sinapinic acid and methods for treating keratin surfaces
GB1499271A (en) Stable emulsions of water in 1,1,2-trichloro-1,2,2-trifluoroethane
JPH08325126A (en) Composition for oral cavity
EP0307083B1 (en) Composition for external use containing an ethoxylated compound
JP2004051979A (en) Glyceryl ether for antiseptic for cooling lubricant