GB881624A - Compounds containing boron and silicon - Google Patents

Compounds containing boron and silicon

Info

Publication number
GB881624A
GB881624A GB28623/58A GB2862358A GB881624A GB 881624 A GB881624 A GB 881624A GB 28623/58 A GB28623/58 A GB 28623/58A GB 2862358 A GB2862358 A GB 2862358A GB 881624 A GB881624 A GB 881624A
Authority
GB
United Kingdom
Prior art keywords
phenyl
alkyl
siladiborinanes
trioxa
plasticizers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28623/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of GB881624A publication Critical patent/GB881624A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02Boron compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0834Compounds having one or more O-Si linkage
    • C07F7/0836Compounds with one or more Si-OH or Si-O-metal linkage
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/08Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds
    • C10M2227/081Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds with a metal carbon bond belonging to a ring, e.g. ferocene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/06Groups 3 or 13
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)

Abstract

Organo-silicon-boron compounds of the formula <FORM:0881624/III/1> where R is a carbocylic radical, are used as petroleum additives which are hydrolytically and thermally stable, e.g. as V.I. improvers, in lubricants and greases, as cetane improvers, ignition promoters, anti-knock agents, preventives of pre-ignition &c.ALSO:The invention comprises siladiborinanes of the formula <FORM:0881624/IV (a)/1> where R is a carbocyclic radical which may be substituted by radicals which do not react with boronic acid during the preparation. They are prepared by reacting a carbocyclylboronic acid RB(OH)2 with a dicarbocyclylsilane diol R2Si (OH)2, preferably in a molar ratio of at least 2:1. Each R can be the same or different; examples are phenyl, mono- and poly-alkyl phenyl, biphenyl, naphthyl, alkyl naphthyl, tetrahydronaphthyl, anthryl, alkyl anthryl, cycloalkyl, cycloalkenyl, and halo and alkoxy carbocyclic radicals. The examples describe the preparation of 2,2,4,6-tetraphenyl, tetra-(p-tolyl)-and tetra-(m-chlorophenyl)-1,3,5-trioxa-2-siladiborinanes, and 2-phenyl-2,4,6-tricyclohexyl-1,3,5-trioxa-2-siladiborinane. The compounds are useful, inter alia, as plasticizers for polyvinyl and polyvinylidene halides, e.g. chloride or bromide, with or without other plasticizers, e.g. trialkyl cyanurates, in amounts of from 2 to 65% by weight of the composition. Other uses: neutron absorbers, ingredients in flame-resistant compositions, active ingredient in insectisides, germicides, fungicides &c., in arc-extinguishing tubes, heat-exchange media, petroleum additives.
GB28623/58A 1957-09-16 1958-09-05 Compounds containing boron and silicon Expired GB881624A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US881624XA 1957-09-16 1957-09-16

Publications (1)

Publication Number Publication Date
GB881624A true GB881624A (en) 1961-11-08

Family

ID=22209711

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28623/58A Expired GB881624A (en) 1957-09-16 1958-09-05 Compounds containing boron and silicon

Country Status (1)

Country Link
GB (1) GB881624A (en)

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