GB876469A - Rigid polyurethane foam - Google Patents

Rigid polyurethane foam

Info

Publication number
GB876469A
GB876469A GB28170/59A GB2817059A GB876469A GB 876469 A GB876469 A GB 876469A GB 28170/59 A GB28170/59 A GB 28170/59A GB 2817059 A GB2817059 A GB 2817059A GB 876469 A GB876469 A GB 876469A
Authority
GB
United Kingdom
Prior art keywords
hexitol
organic compounds
water
polyurethane foam
rigid polyurethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28170/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zeneca Inc
Original Assignee
Atlas Chemical Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlas Chemical Industries Inc filed Critical Atlas Chemical Industries Inc
Publication of GB876469A publication Critical patent/GB876469A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives
    • C08G2170/60—Compositions for foaming; Foamed or intumescent adhesives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

A rigid polyurethane foam is produced by reacting an arylene di-isocyanate with a polyoxypropylene ether obtained by condensing 0,25-50 parts of propylene oxide with 1 part of a hexitol or a hexitol-water mixture containing up to 15% water. Specified hexitols are sorbitol, mannitol, dulcitol and iditol, and their mixtures may also be used. A list of suitable isocyanates is given, and optional ingredients are catalysts, e.g. tertiary amines and organo-tin derivatives; surfactants, e.g. silicones; and flame retardants, e.g. halogeno-organic compounds, antimony trichloride or phosphoro-organic compounds such as an aryl alkyl phosphonate.ALSO:A rigid polyurethane foam is produced by reacting an arylene diisocyanate with a polyoxypropylene ether obtained by condensing 0,25 to 50 parts of propylene oxide with 1 part of a hexitol or a hexitol-water mixture containing up to 15% water. Specified hexitols are sorbitol, mannitol, dulcitol and iditol, and their mixtures may also be used. A list of suitable isocyanates is given, and optional ingredients are catalysts e.g. tertiary amines and organo-tin derivatives; surfactants e.g. silicones; and flame retardants e.g. halogens-organic compounds, antimony trichloride or phosphors-organic compounds such as an aryl alkyl phosphonate. Cellularity may derive from a thermally unstable or a low boiling point component, or by adding water where a molar excess of di-isocyanate is used.
GB28170/59A 1958-08-28 1959-08-18 Rigid polyurethane foam Expired GB876469A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US876469XA 1958-08-28 1958-08-28

Publications (1)

Publication Number Publication Date
GB876469A true GB876469A (en) 1961-09-06

Family

ID=22206408

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28170/59A Expired GB876469A (en) 1958-08-28 1959-08-18 Rigid polyurethane foam

Country Status (3)

Country Link
BE (1) BE582076A (en)
FR (1) FR1238950A (en)
GB (1) GB876469A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3214392A (en) * 1961-08-21 1965-10-26 Hooker Chemical Corp Foamable resinous polyurethane compositions
US3218272A (en) * 1962-09-05 1965-11-16 Fmc Corp Flame-retardant polyurethane foams
DE1239469B (en) * 1963-12-31 1967-04-27 Hercules Inc Process for the production of polyurethane foams
US3644236A (en) * 1968-02-21 1972-02-22 Bp Chem Int Ltd Lead filled polyurethane foams
WO2007096317A1 (en) * 2006-02-27 2007-08-30 Basf Se Process of forming a polyol

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3214392A (en) * 1961-08-21 1965-10-26 Hooker Chemical Corp Foamable resinous polyurethane compositions
US3218272A (en) * 1962-09-05 1965-11-16 Fmc Corp Flame-retardant polyurethane foams
DE1239469B (en) * 1963-12-31 1967-04-27 Hercules Inc Process for the production of polyurethane foams
US3356622A (en) * 1963-12-31 1967-12-05 Hercules Inc Polyurethane foam produced from hydroxyalkylated substantially petroleum hydrocarbon-insoluble pine wood resin
US3644236A (en) * 1968-02-21 1972-02-22 Bp Chem Int Ltd Lead filled polyurethane foams
WO2007096317A1 (en) * 2006-02-27 2007-08-30 Basf Se Process of forming a polyol
KR101376421B1 (en) * 2006-02-27 2014-03-27 바스프 에스이 Process of forming a polyol

Also Published As

Publication number Publication date
BE582076A (en)
FR1238950A (en) 1960-08-19

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