GB875920A - Improvements relating to compositions suitable for use in the manufacture of floor and wall coverings - Google Patents

Improvements relating to compositions suitable for use in the manufacture of floor and wall coverings

Info

Publication number
GB875920A
GB875920A GB1089357A GB1089357A GB875920A GB 875920 A GB875920 A GB 875920A GB 1089357 A GB1089357 A GB 1089357A GB 1089357 A GB1089357 A GB 1089357A GB 875920 A GB875920 A GB 875920A
Authority
GB
United Kingdom
Prior art keywords
resins
polyvinyl
chloride
oils
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1089357A
Inventor
Wilfred Henry Hogg
Peter Ford
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dunlop Rubber Co Ltd
Original Assignee
Dunlop Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE566279D priority Critical patent/BE566279A/xx
Priority to FR1194187D priority patent/FR1194187A/fr
Application filed by Dunlop Rubber Co Ltd filed Critical Dunlop Rubber Co Ltd
Priority to GB1089357A priority patent/GB875920A/en
Priority to GB1086957A priority patent/GB821368A/en
Priority to DED27793A priority patent/DE1092189B/en
Publication of GB875920A publication Critical patent/GB875920A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/36—Hydroxylated esters of higher fatty acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N1/00—Linoleum, e.g. linoxyn, polymerised or oxidised resin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Organic Insulating Materials (AREA)

Abstract

A composition suitable for use in the manufacture of floor and wall coverings comprises filler material together with a binder comprising (1) an oxidizable vegetable oil having in its molecule at least two hydrogen atoms replaceable by a metal and (2) a substantially non-crosslinked reaction product having in its molecule at least two isocyanate or isothiocyanate groups obtained from a diisocyanate or diisothiocyanate and a polyester, polyesteramide or polyglycol. The binder may also contain vinyl resins (e.g. polyvinyl chloride, copolymers of vinyl chloride and vinylidene chloride, copolymers of vinyl chloride and vinyl acetate, polyvinyl acetate, and polyvinyl formal, polyvinyl butyral and other vinyl acetals), resins derived from pentaerythritol, phenol-aldehyde resins (e.g. xylenol-formaldehyde novolak resins) and natural resins (e.g. wood resin and dammar and other copal resins). As plasticizers there may be added phosphate and phthalate esters (for polyvinyl chloride), glycollate and sulphonamide plasticizers (for polyvinyl acetals and nitrile rubbers (for phenolic resins). The oxidizable vegetable oils include unoxidized oils, e.g. raw linseed oil, and partially oxidized oils, e.g. blown or gelled linseed or castor oil. Tung oil, rape oil and dehydrated castor oil are also mentioned; animal oils may be used in addition to the vegetable oils. Oils which are unreactive or insufficiently reactive can be made isocyanate group-reactive by heating with glycerol, glycol or other polyhydroxy compound or with an amine or hydroxyamine. The prepolymer can be obtained from a simple diisocyanate or diisothiocyanate and a polyglycol and also trimethylolpropane and/or another aliphatic polyhydroxy compound. In examples the prepolymers are prepared from propylene glycol polymer in one case containing trimethylolpropane and toluylene diisocyanate, stabilized with phthalyl or benzoyl chloride, or from a mixture of equal parts of oleic acid trimer and polypropylene ether diol. Other components of the mixture are in Example (1) gelled linseed oil, vinyl chloride-vinylidene chloride copolymer, dioctyl phthalate, tri-xylyl phosphate, lead carbonate, asbestos fibres, whiting and pigments. Alternative ingredients in mentioned other examples are wood rosin, xylenol formaldehyde novolak resin, wood flour, pentaerythritol ester of rosin acid, cork flour, titanium dioxide, lead chromate. The mixtures are blended in a mixer or roller mill, sheeted and heated to give linoleum-like material.
GB1089357A 1957-04-03 1957-04-03 Improvements relating to compositions suitable for use in the manufacture of floor and wall coverings Expired GB875920A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BE566279D BE566279A (en) 1957-04-03
FR1194187D FR1194187A (en) 1957-04-03
GB1089357A GB875920A (en) 1957-04-03 1957-04-03 Improvements relating to compositions suitable for use in the manufacture of floor and wall coverings
GB1086957A GB821368A (en) 1957-04-03 1957-04-03 Improvements in or relating to the manufacture of polyurethanes
DED27793A DE1092189B (en) 1957-04-03 1958-04-03 Process for the production of preformed rubber-like floor coverings or wall coverings

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1089357A GB875920A (en) 1957-04-03 1957-04-03 Improvements relating to compositions suitable for use in the manufacture of floor and wall coverings

Publications (1)

Publication Number Publication Date
GB875920A true GB875920A (en) 1961-08-23

Family

ID=9976262

Family Applications (2)

Application Number Title Priority Date Filing Date
GB1089357A Expired GB875920A (en) 1957-04-03 1957-04-03 Improvements relating to compositions suitable for use in the manufacture of floor and wall coverings
GB1086957A Expired GB821368A (en) 1957-04-03 1957-04-03 Improvements in or relating to the manufacture of polyurethanes

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB1086957A Expired GB821368A (en) 1957-04-03 1957-04-03 Improvements in or relating to the manufacture of polyurethanes

Country Status (4)

Country Link
BE (1) BE566279A (en)
DE (1) DE1092189B (en)
FR (1) FR1194187A (en)
GB (2) GB875920A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010007319A2 (en) * 2008-07-18 2010-01-21 Gerflor Use of polyols derived from a renewable plant source for the manufacture of floor coverings

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3718102A1 (en) * 1987-05-29 1988-12-08 Teroson Gmbh LIQUID, SOLVENT-FREE, AIRLESS AND COMPRESSED AIR SPRAYABLE, HARDENABLE POLYURETHANE OIL SOFTENER COMPONENT COMPOSITION, METHOD FOR THE PRODUCTION AND USE THEREOF
DE3839334A1 (en) * 1988-11-22 1990-05-23 Bayer Ag PROCESS FOR PREPARING POLYURETHANE MASSES
DE68917123T2 (en) * 1989-02-28 1995-01-05 Mondo Spa Process for the production of linoleum.
KR101609720B1 (en) * 2008-08-06 2016-04-06 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 Films and articles made with thermoplastic block copolymers

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2282827A (en) * 1939-11-13 1942-05-12 Du Pont Resinous product and method of making
US2358475A (en) * 1940-11-08 1944-09-19 Du Pont Modified drying oil
DE964987C (en) * 1953-12-20 1957-05-29 Oelfabrik Dr Grandel & Co Deut Process for the production of elastic abrasive bodies

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010007319A2 (en) * 2008-07-18 2010-01-21 Gerflor Use of polyols derived from a renewable plant source for the manufacture of floor coverings
FR2933991A1 (en) * 2008-07-18 2010-01-22 Gerflor USE OF POLYOLS FROM RENEWABLE PLANT SOURCE FOR THE MANUFACTURE OF SOIL COATINGS
WO2010007319A3 (en) * 2008-07-18 2010-03-11 Gerflor Use of polyols derived from a renewable plant source for the manufacture of floor coverings

Also Published As

Publication number Publication date
GB821368A (en) 1959-10-07
FR1194187A (en) 1959-11-06
BE566279A (en)
DE1092189B (en) 1960-11-03

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