GB874776A - A process for the production of cyclopropane derivatives and resultant decompositionproducts - Google Patents
A process for the production of cyclopropane derivatives and resultant decompositionproductsInfo
- Publication number
- GB874776A GB874776A GB1476860A GB1476860A GB874776A GB 874776 A GB874776 A GB 874776A GB 1476860 A GB1476860 A GB 1476860A GB 1476860 A GB1476860 A GB 1476860A GB 874776 A GB874776 A GB 874776A
- Authority
- GB
- United Kingdom
- Prior art keywords
- halogen
- dichloro
- give
- salt
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 125000001559 cyclopropyl group Chemical class [H]C1([H])C([H])([H])C1([H])* 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical class 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
- 125000001033 ether group Chemical group 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 238000006317 isomerization reaction Methods 0.000 abstract 2
- 230000002269 spontaneous effect Effects 0.000 abstract 2
- XLBKTCKKJAGMQS-UHFFFAOYSA-N 1,1-dichloro-2-(chloromethyl)cyclopropane Chemical compound ClCC1CC1(Cl)Cl XLBKTCKKJAGMQS-UHFFFAOYSA-N 0.000 abstract 1
- GAAAGAHNGGKSQH-UHFFFAOYSA-N 1,1-dichloro-2-ethenylcyclopropane Chemical compound ClC1(Cl)CC1C=C GAAAGAHNGGKSQH-UHFFFAOYSA-N 0.000 abstract 1
- MENJBAPSEVYSIK-UHFFFAOYSA-N 2,2-dichloro-2-phenylacetic acid Chemical compound OC(=O)C(Cl)(Cl)C1=CC=CC=C1 MENJBAPSEVYSIK-UHFFFAOYSA-N 0.000 abstract 1
- KYNPSGINDDYHAL-UHFFFAOYSA-N 6,6-dichlorobicyclo[3.1.0]hex-2-ene Chemical compound ClC1(C2CC=CC12)Cl KYNPSGINDDYHAL-UHFFFAOYSA-N 0.000 abstract 1
- MBPSCGRETWPLSI-UHFFFAOYSA-N 7,7-dichlorobicyclo[4.1.0]heptane Chemical compound C1CCCC2C(Cl)(Cl)C21 MBPSCGRETWPLSI-UHFFFAOYSA-N 0.000 abstract 1
- LKESAMUKDSQRSS-UHFFFAOYSA-N 8,8-dichlorobicyclo[5.1.0]octa-3,5-diene Chemical compound C1C=CC=CC2C(Cl)(Cl)C21 LKESAMUKDSQRSS-UHFFFAOYSA-N 0.000 abstract 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 125000002015 acyclic group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- CHVJITGCYZJHLR-UHFFFAOYSA-N cyclohepta-1,3,5-triene Chemical compound C1C=CC=CC=C1 CHVJITGCYZJHLR-UHFFFAOYSA-N 0.000 abstract 1
- 150000001942 cyclopropanes Chemical class 0.000 abstract 1
- 230000000911 decarboxylating effect Effects 0.000 abstract 1
- 238000007033 dehydrochlorination reaction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical compound O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL238707 | 1959-04-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB874776A true GB874776A (en) | 1961-08-10 |
Family
ID=19751697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1476860A Expired GB874776A (en) | 1959-04-29 | 1960-04-27 | A process for the production of cyclopropane derivatives and resultant decompositionproducts |
Country Status (4)
| Country | Link |
|---|---|
| CH (1) | CH395968A (enrdf_load_html_response) |
| DE (1) | DE1121046B (enrdf_load_html_response) |
| GB (1) | GB874776A (enrdf_load_html_response) |
| NL (1) | NL99476C (enrdf_load_html_response) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3274270A (en) * | 1963-10-01 | 1966-09-20 | Monsauto Res Corp | Pyrolysis of sodium tribromoacetate |
-
0
- NL NL99476D patent/NL99476C/xx active
-
1960
- 1960-04-27 DE DES68252A patent/DE1121046B/de active Pending
- 1960-04-27 CH CH476360A patent/CH395968A/de unknown
- 1960-04-27 GB GB1476860A patent/GB874776A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CH395968A (de) | 1965-07-31 |
| NL99476C (enrdf_load_html_response) | |
| DE1121046B (de) | 1962-01-04 |
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