GB874561A - Process for the production of vinyl chloride - Google Patents
Process for the production of vinyl chlorideInfo
- Publication number
- GB874561A GB874561A GB2593759A GB2593759A GB874561A GB 874561 A GB874561 A GB 874561A GB 2593759 A GB2593759 A GB 2593759A GB 2593759 A GB2593759 A GB 2593759A GB 874561 A GB874561 A GB 874561A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dichloroethane
- hydrochloride
- heating
- tertiary amine
- vinyl chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Vinyl chloride is prepared by heating 1 : 2-dichloroethane at above 150 DEG C. in the presence of the hydrochloride or quaternary ammonium chloride derived from a tertiary amine. The catalyst (when a hydrochloride) may be prepared in situ by heating the dichloroethane in the presence of the tertiary amine. Amines specified are triethanolamine, tri-butylamine, trioctylamine, tridodecylamine, quinoline, collidine and pyridine.ALSO:Hydrogen chloride is recovered by conventional means from the dehydrochlorination of 1:2-dichloroethane accomplished by heating the dichloroethane at above 150 DEG C. in the presence of the hydrochloride or quaternary ammonium chloride derived from a tertiary amine. Amines specified are triethanolamine, tributylamine, trioctylamine, tridodecylamine, quinoline, collidine and pyridine.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2593759A GB874561A (en) | 1959-07-29 | 1959-07-29 | Process for the production of vinyl chloride |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2593759A GB874561A (en) | 1959-07-29 | 1959-07-29 | Process for the production of vinyl chloride |
Publications (1)
Publication Number | Publication Date |
---|---|
GB874561A true GB874561A (en) | 1961-08-10 |
Family
ID=10235738
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2593759A Expired GB874561A (en) | 1959-07-29 | 1959-07-29 | Process for the production of vinyl chloride |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB874561A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3244755A (en) * | 1961-10-23 | 1966-04-05 | Monsanto Co | Purification of vinyl chloride |
-
1959
- 1959-07-29 GB GB2593759A patent/GB874561A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3244755A (en) * | 1961-10-23 | 1966-04-05 | Monsanto Co | Purification of vinyl chloride |
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