GB871538A - Process for the exchange of hydrocarbon groups between aluminium and boron hydrocarbon compounds - Google Patents
Process for the exchange of hydrocarbon groups between aluminium and boron hydrocarbon compoundsInfo
- Publication number
- GB871538A GB871538A GB2108/59A GB210859A GB871538A GB 871538 A GB871538 A GB 871538A GB 2108/59 A GB2108/59 A GB 2108/59A GB 210859 A GB210859 A GB 210859A GB 871538 A GB871538 A GB 871538A
- Authority
- GB
- United Kingdom
- Prior art keywords
- boron
- hydrocarbon
- aluminium
- reacted
- radicals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052796 boron Inorganic materials 0.000 title abstract 16
- -1 boron hydrocarbon compounds Chemical class 0.000 title abstract 15
- 239000004411 aluminium Substances 0.000 title abstract 12
- 229910052782 aluminium Inorganic materials 0.000 title abstract 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract 4
- 150000002430 hydrocarbons Chemical group 0.000 title abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 14
- 239000004215 Carbon black (E152) Substances 0.000 abstract 12
- 239000000203 mixture Substances 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001399 aluminium compounds Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical group CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/027—Organoboranes and organoborohydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/062—Al linked exclusively to C
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
An exchange of hydrocarbon groups between aluminium hydrocarbon compounds and boron hydrocarbon compounds is effected by reacting together two such compounds in which the hydrocarbon radicals are different. Thus a boron hydrocarbon the hydrocarbon radicals of which are of higher molecular weight than those of the boron hydrocarbon to be produced may be reacted with an aluminium hydrocarbon, the radicals of which are the same as those in the desired boron hydrocarbon, and the reaction mixture distilled to recover the boron hydrocarbon which is the most volatile component of the mixture. Boron hydrocarbons the radicals of which are of lower molecular weight than those of the desired boron hydrocarbon may be reacted in the cold with an excess of an aluminium hydrocarbon, the radicals of which are the same as those in the desired boron hydrocarbon and the mixture hydrolysed to decompose the aluminium compound and recover the desired boron hydrocarbon, for example with water or dilute sulphuric acid in the cold. Straight chain olefines may be reacted with diborane to form a boron trialkyl which is then reacted with an aluminium hydrocarbon to form the corresponding aluminium trialkyl. Lower boron alkyls formed as secondary products may be reconverted to diborane by hydrogenation. An aluminium triphenyl is obtained by reacting boron triphenyl, or the reaction product of sodium borotetraphenyl with diethyl aluminium chloride, with aluminium triethyl, distilling off boron triethyl and extracting the aluminium triphenyl, e.g. with hot xylene, in the absence of air. Boron alkyls may be built up by reaction with ethylene to form higher boron alkyls in the presence of catayltic quantities of aluminium alkyls as described in Specification 858,446, and the boron alkyls so formed may be then reacted with the aluminium hydrocarbons to form the corresponding higher aluminium trialkyls.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE871538X | 1958-01-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB871538A true GB871538A (en) | 1961-06-28 |
Family
ID=6814283
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2108/59A Expired GB871538A (en) | 1958-01-22 | 1959-01-20 | Process for the exchange of hydrocarbon groups between aluminium and boron hydrocarbon compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB871538A (en) |
-
1959
- 1959-01-20 GB GB2108/59A patent/GB871538A/en not_active Expired
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