GB871085A - A process for the production of n-trialkyl borazanes - Google Patents
A process for the production of n-trialkyl borazanesInfo
- Publication number
- GB871085A GB871085A GB3620/58A GB362058A GB871085A GB 871085 A GB871085 A GB 871085A GB 3620/58 A GB3620/58 A GB 3620/58A GB 362058 A GB362058 A GB 362058A GB 871085 A GB871085 A GB 871085A
- Authority
- GB
- United Kingdom
- Prior art keywords
- trialkylamine
- boron
- trialkyl
- borazane
- hydrides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 3
- 125000005270 trialkylamine group Chemical group 0.000 abstract 6
- 229910015900 BF3 Inorganic materials 0.000 abstract 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 5
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 4
- JBANFLSTOJPTFW-UHFFFAOYSA-N azane;boron Chemical compound [B].N JBANFLSTOJPTFW-UHFFFAOYSA-N 0.000 abstract 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- -1 boron halides Chemical class 0.000 abstract 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- SIAPCJWMELPYOE-UHFFFAOYSA-N lithium hydride Chemical compound [LiH] SIAPCJWMELPYOE-UHFFFAOYSA-N 0.000 abstract 1
- 229910000103 lithium hydride Inorganic materials 0.000 abstract 1
- 229910001512 metal fluoride Inorganic materials 0.000 abstract 1
- 229910052987 metal hydride Inorganic materials 0.000 abstract 1
- 150000004681 metal hydrides Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 235000013024 sodium fluoride Nutrition 0.000 abstract 1
- 239000011775 sodium fluoride Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
Abstract
N-trialkyl borazanes are produced by reacting trialkylamine compounds of boron halides (i.e. N-trialkyl B-trihalogenoborazanes), including compounds of trialkylamines which contain cycloalkyl radicals attached to the nitrogen, at room temperature or elevated temperature with alkali metal or alkaline earth metal hydrides, borohydrides or complexes of the metal hydrides with boric acid esters. A solvent may be used, such as a hydrocarbon or ether or the N-trialkyl borazane which is being produced. A ball mill is a suitable reaction vessel. A trialkylamine-boron trichloride compound may be used with a wide range of hydrides. The trialkylamine-boron trifluoride compounds react readily with lithium hydride or alkaline earth metal hydrides but with sodium or potassium hydrides or borohydrides a sodium or potassium borofluoride is formed in addition to the borazane and trialkylamine, which borofluoride is decomposed, by heating, into boron fluoride and sodium fluoride and the resulting boron fluoride is reacted with the trialkylamine to form the trialkylamine-boron fluoride compound which can be used again. A trialkylamine-boron fluoride compound reacts with a borohydride of an alkali metal or alkaline earth metal in the presence of an excess of trialkylamine to give a borazane and a metal fluoride and some of the borazone is reacted with an alkali or alkaline earth metal hydride to form the borohydride and trialkylamine which can be used again. In one method of operation, the trialkylamine-boron fluoride compound is mixed with a trialkyl borazane as a solvent and calcium hydride is added in finely powdered form, preferably in suspension in an inert solvent. This process may be operated continuously. Specification 855,881 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE871085X | 1957-02-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB871085A true GB871085A (en) | 1961-06-21 |
Family
ID=6810913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3620/58A Expired GB871085A (en) | 1957-02-05 | 1958-02-04 | A process for the production of n-trialkyl borazanes |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB871085A (en) |
-
1958
- 1958-02-04 GB GB3620/58A patent/GB871085A/en not_active Expired
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