GB864433A - Thiophosphoric acid esters - Google Patents
Thiophosphoric acid estersInfo
- Publication number
- GB864433A GB864433A GB4006/59A GB400659A GB864433A GB 864433 A GB864433 A GB 864433A GB 4006/59 A GB4006/59 A GB 4006/59A GB 400659 A GB400659 A GB 400659A GB 864433 A GB864433 A GB 864433A
- Authority
- GB
- United Kingdom
- Prior art keywords
- thiophosphoric acid
- alkyl
- acid esters
- sulphoxide
- sulphur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003580 thiophosphoric acid esters Chemical class 0.000 title abstract 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- ATTZFSUZZUNHBP-UHFFFAOYSA-N Piperonyl sulfoxide Chemical compound CCCCCCCCS(=O)C(C)CC1=CC=C2OCOC2=C1 ATTZFSUZZUNHBP-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Chemical group 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- -1 phenyl alkyl sulphide Chemical compound 0.000 abstract 2
- 125000001174 sulfone group Chemical group 0.000 abstract 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003701 inert diluent Substances 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229920000151 polyglycol Polymers 0.000 abstract 1
- 239000010695 polyglycol Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1653—Esters of thiophosphoric acids with arylalkanols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises thiophosphoric acid esters of formula: <FORM:0864433/IV (b)/1> where R, R1 and R2 are C1-4 alkyl, X is oxygen or sulphur and n is 0, 1 or 2. They may be prepared by reacting a 4-(a -chloromethyl) phenyl alkyl sulphide, sulphoxide or sulphone with a salt, e.g. the ammonium salt, of a 0, 0-dialkyl thiol- or thionothiol-phosphoric acid. Elevated temperatures are preferred and an inert solvent may be used. The sulphoxide and sulphones may be obtained by oxidation of the corresponding sulphide either before or after reaction with the phosphorus compound. Specification 808,879 is referred to.ALSO:Insecticidal compositions comprise a thiophosphoric acid ester of formula <FORM:0864433/VI/1> where R, R1 and R2 are C1-4 alkyl, X is oxygen or sulphur and n is 0, 1 or 2, together with an inert diluent. A specified composition contains dimethyl formamide and an aromatic polyglycol ether. Specification 808,879 is referred to.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0024992 | 1958-02-06 | ||
| DEF20758A DE1035153B (en) | 1958-02-06 | 1958-02-06 | Process for the preparation of insecticidally active thiophosphoric acid esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB864433A true GB864433A (en) | 1961-04-06 |
Family
ID=25973980
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB21241/57A Expired GB808879A (en) | 1958-02-06 | 1957-07-04 | Thiophosphoric acid esters |
| GB4006/59A Expired GB864433A (en) | 1958-02-06 | 1959-02-04 | Thiophosphoric acid esters |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB21241/57A Expired GB808879A (en) | 1958-02-06 | 1957-07-04 | Thiophosphoric acid esters |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2938919A (en) |
| CH (2) | CH359146A (en) |
| DE (2) | DE1035153B (en) |
| FR (1) | FR1178349A (en) |
| GB (2) | GB808879A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL288076A (en) * | 1962-01-24 | |||
| NL302624A (en) * | 1963-01-04 | |||
| US3933947A (en) * | 1970-03-25 | 1976-01-20 | Bayer Aktiengesellschaft | O-ethyl-S-propyl-S-benzyl-phosphorodithiolates |
| JPS57183796A (en) * | 1981-04-06 | 1982-11-12 | Nippon Tokushu Noyaku Seizo Kk | Preparation of organophosphoric acid ester substituted with alkylsulfinyl group |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE830509C (en) * | 1950-05-24 | 1952-02-04 | Bayer Ag | Process for the preparation of neutral esters of thiophosphoric acid |
| DE885176C (en) * | 1951-10-02 | 1953-08-03 | Bayer Ag | Pest repellants |
| NL205249A (en) * | 1955-03-05 | |||
| DE949231C (en) * | 1955-05-03 | 1956-09-13 | Bayer Ag | Process for the preparation of chlorinated benzyl esters of thiol or thionothiol phosphoric acids |
| DE1018053B (en) * | 1955-10-29 | 1957-10-24 | Bayer Ag | Process for the preparation of S-chlorobenzyl esters of O, O-dialkyl-thiolphosphoric acid |
-
0
- DE DENDAT1074034D patent/DE1074034B/en active Pending
-
1957
- 1957-06-21 CH CH359146D patent/CH359146A/en unknown
- 1957-07-04 GB GB21241/57A patent/GB808879A/en not_active Expired
- 1957-07-10 FR FR1178349D patent/FR1178349A/en not_active Expired
-
1958
- 1958-02-06 DE DEF20758A patent/DE1035153B/en active Pending
-
1959
- 1959-01-23 CH CH6868459A patent/CH367832A/en unknown
- 1959-01-27 US US789259A patent/US2938919A/en not_active Expired - Lifetime
- 1959-02-04 GB GB4006/59A patent/GB864433A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1035153B (en) | 1958-07-31 |
| DE1074034B (en) | 1960-01-28 |
| US2938919A (en) | 1960-05-31 |
| CH367832A (en) | 1963-03-15 |
| GB808879A (en) | 1959-02-11 |
| FR1178349A (en) | 1959-05-06 |
| CH359146A (en) | 1961-12-31 |
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