GB864393A - Process for the production of lead tetraalkyls - Google Patents
Process for the production of lead tetraalkylsInfo
- Publication number
- GB864393A GB864393A GB5084/59A GB508459A GB864393A GB 864393 A GB864393 A GB 864393A GB 5084/59 A GB5084/59 A GB 5084/59A GB 508459 A GB508459 A GB 508459A GB 864393 A GB864393 A GB 864393A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- sodium
- compound
- potassium
- triethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011734 sodium Substances 0.000 abstract 17
- 239000004411 aluminium Substances 0.000 abstract 14
- 229910052782 aluminium Inorganic materials 0.000 abstract 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 9
- 229910052708 sodium Inorganic materials 0.000 abstract 9
- 150000001875 compounds Chemical class 0.000 abstract 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 abstract 4
- 229910052700 potassium Inorganic materials 0.000 abstract 4
- 239000011591 potassium Substances 0.000 abstract 4
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 3
- 239000005977 Ethylene Substances 0.000 abstract 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 3
- -1 alkyl radical Chemical class 0.000 abstract 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 abstract 2
- 229910000104 sodium hydride Inorganic materials 0.000 abstract 2
- 239000012312 sodium hydride Substances 0.000 abstract 2
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 abstract 1
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical compound CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 abstract 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910000102 alkali metal hydride Inorganic materials 0.000 abstract 1
- 150000008046 alkali metal hydrides Chemical class 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000006612 decyloxy group Chemical group 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 abstract 1
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 abstract 1
- 229940031826 phenolate Drugs 0.000 abstract 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/062—Al linked exclusively to C
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/90—Antimony compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/94—Bismuth compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/01—Products
- C25B3/13—Organo-metallic compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/02—Electrolytic production, recovery or refining of metals by electrolysis of melts of alkali or alkaline earth metals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Compounds of the general formula Me [Al(R1)3OR] wherein Me represents sodium or potassium, R1 represents a straight chain primary alkyl radical (especially C2-C4) and R represents a hydrocarbon radical (especially C2-C12 alkyl) are prepared by reacting: 1) a compound of formula MeAlR14 with an alcohol or phenol, 2) an aluminium trialkyl with a sodium or potassium alcoholate or phenolate, 3) an aluminium trialkyl and sodium or potassium with a compound of formula (R1)2AlOR formed by electrolysis, or 4) the addition product of an alkali metal hydride and a compound (R1)2AlOR (or a compound R2AlOR obtained by oxidising an aluminium trialkyl with 1/2 mol of oxygen) with ethylene or an olefin of type CnH2n+1-CH=CH2. In Examples 1) Na[Al(C2H5)3 OC4H9) is prepared from sodium aluminium tetra-ethyl and butyl alcohol; 2) Na[Al(C2H5)3 (OC2H5)] from sodium ethylate and aluminium triethyl; 3) K[Al(C4H9)3 OCH2CH(C2H5) C4H9] from aluminium tri-n-butyl, potassium and ethyl hexanol: Na[Al(C2H5)3 (OC6H5)] from anhydrous phenol and aluminium triethyl, and Na[Al(C2H5)3 (OC6H4CH3)] using m-cresol instead of phenol: 5) a complex from butoxy aluminium diethyl, aluminium triethyl and sodium; (6 Na[AlH(C2H5)3 (OC4H9)] from the addition of ethylene to Na[AlH(C2H5)2 (OC4H9)] which is obtained by adding sodium hydride to diethyl aluminium butoxide; 7) decyloxyaluminium diethyl is prepared from aluminium triethyl and n-decyl alcohol, mixed with sodium hydride and ethylene added to give Na[C2H)3 AlOC10H21], and using isohexylalcohol instead of n-decyl alcohol, the product is Na[(C2H5)3 AlOCH2CH(CH3)C3H7]:15) sodium hexyloxy aluminium tripropyl from sodium hexylate and aluminium tripropyl: and 16) sodium aluminium tetrabutyl is reacted with n-decanol-(1) to give sodium decyloxy aluminium tributyl. Specifications 814,609 and 848,364 are referred to.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ6509A DE1127900B (en) | 1958-02-13 | 1958-02-13 | Process for the preparation of alkyls of the metals of groups ób to ó§b of the periodic system, in particular lead tetraalkyls |
| DEZ6510A DE1153754B (en) | 1958-02-13 | 1958-02-14 | Process for the preparation of alkyls of the metals of ó . Subgroup and the ó¾. to ó§. Main group, in particular lead tetraalkylene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB864393A true GB864393A (en) | 1961-04-06 |
Family
ID=26003348
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5084/59A Expired GB864393A (en) | 1958-02-13 | 1959-02-13 | Process for the production of lead tetraalkyls |
| GB5332/59A Expired GB864394A (en) | 1958-02-13 | 1959-02-16 | Process for separating lead tetraalkyls from aluminium alkyls |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5332/59A Expired GB864394A (en) | 1958-02-13 | 1959-02-16 | Process for separating lead tetraalkyls from aluminium alkyls |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3254009A (en) |
| BE (2) | BE575595A (en) |
| DE (2) | DE1127900B (en) |
| FR (2) | FR1223643A (en) |
| GB (2) | GB864393A (en) |
| NL (4) | NL106593C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3234114A (en) * | 1961-06-30 | 1966-02-08 | Ziegler Karl | Process for the recovery of purified sodium |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL263352A (en) * | 1960-07-13 | |||
| US3392093A (en) * | 1964-06-23 | 1968-07-09 | Du Pont | Electrolytic process for producing tetraalkyl lead compounds |
| US3493592A (en) * | 1968-01-15 | 1970-02-03 | Ethyl Corp | Preparation of dialkyltins and dialkyltin oxides |
| DE10226360A1 (en) * | 2002-06-13 | 2003-12-24 | Crompton Gmbh | Process for the preparation of alkali tetraalkyl aluminates and their use |
| US6960677B1 (en) | 2003-10-28 | 2005-11-01 | Albemarle Corporation | Preparation of aluminates |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL101542C (en) * | 1954-11-26 | |||
| BE540052A (en) * | 1955-06-13 | |||
| US2944948A (en) * | 1956-02-06 | 1960-07-12 | Ethyl Corp | Method of purifying organometallic complexes and their use in the preparation of organolead compounds |
-
0
- NL NL236102D patent/NL236102A/xx unknown
- NL NL236048D patent/NL236048A/xx unknown
-
1958
- 1958-02-13 DE DEZ6509A patent/DE1127900B/en active Pending
- 1958-02-14 DE DEZ6510A patent/DE1153754B/en active Pending
-
1959
- 1959-02-10 FR FR786319A patent/FR1223643A/en not_active Expired
- 1959-02-11 BE BE575595D patent/BE575595A/fr unknown
- 1959-02-11 FR FR786423A patent/FR1218121A/en not_active Expired
- 1959-02-12 NL NL236048A patent/NL106593C/xx active
- 1959-02-12 BE BE575641D patent/BE575641A/xx unknown
- 1959-02-13 NL NL236102A patent/NL106595C/xx active
- 1959-02-13 GB GB5084/59A patent/GB864393A/en not_active Expired
- 1959-02-16 GB GB5332/59A patent/GB864394A/en not_active Expired
-
1963
- 1963-02-04 US US262285A patent/US3254009A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3234114A (en) * | 1961-06-30 | 1966-02-08 | Ziegler Karl | Process for the recovery of purified sodium |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1218121A (en) | 1960-05-09 |
| GB864394A (en) | 1961-04-06 |
| BE575595A (en) | 1959-08-11 |
| NL236102A (en) | 1900-01-01 |
| BE575641A (en) | 1959-08-12 |
| US3254009A (en) | 1966-05-31 |
| NL236048A (en) | 1900-01-01 |
| DE1153754B (en) | 1963-09-05 |
| NL106593C (en) | 1963-11-15 |
| FR1223643A (en) | 1960-06-17 |
| DE1127900B (en) | 1962-04-19 |
| NL106595C (en) | 1963-05-15 |
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