GB855741A - Improvements in or relating to polyacrylamide derivatives - Google Patents

Improvements in or relating to polyacrylamide derivatives

Info

Publication number
GB855741A
GB855741A GB2790758A GB2790758A GB855741A GB 855741 A GB855741 A GB 855741A GB 2790758 A GB2790758 A GB 2790758A GB 2790758 A GB2790758 A GB 2790758A GB 855741 A GB855741 A GB 855741A
Authority
GB
United Kingdom
Prior art keywords
lithium
acrylamide
hydride
sodium
sodium hydride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2790758A
Inventor
Alan Trevor Radcliffe
Peter Raymond Thomas
Geoffrey James Tyler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British Nylon Spinners Ltd
Original Assignee
British Nylon Spinners Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Nylon Spinners Ltd filed Critical British Nylon Spinners Ltd
Priority to GB2790758A priority Critical patent/GB855741A/en
Priority to GB3327460A priority patent/GB914780A/en
Publication of GB855741A publication Critical patent/GB855741A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Crystalline polymers of acrylamide derivatives wherein the acrylamide molecule bears on the nitrogen atom two monovalent hydrocarbon radical substituents which contain a total of at least 5 carbon atoms and are saturated except for aromatic unsaturation, or said nitrogen atom forms part of a saturated heterocyclic ring which may contain a second heteroatom, namely oxygen or nitrogen bearing an alkyl group, and is optionally substituted by alkyl, may be prepared by polymerization in an inert liquid hydrocarbon in the presence of a catalyst which is an organometallic compound, hydride or complex hydride containing a metal of Group I or II of the Mendeleeff Periodic Table, an alkali metal amide or a complex formed by the addition reaction of an alkali metal with an aromatic organic compound. The liquid hydrocarbon may be toluene, hexane or petroleum ether. Lists of suitable acrylamides and catalysts are given and examples describe the polymerization of N-methyl-Nphenyl acrylamide with (1) lithium ethyl, (2) lithium diethylamide, (3) sodium hydride, (4) lithium amide, (14) sodium boron triphenyl and (15) lithium benzophenone; N : N-diisobutyl acrylamide with (5) sodium hydride; N : N-di-nbutyl acrylamide with (6) sodium hydride and (16) sodium hydride and lithium aluminium hydride; N-acrylylmorpholine with (7) lithium borohydride; N-acrylylpiperidine with (8) lithium ethyl, (9) lithium aluminium ethyl triisobutyl, (11) sodium naphthalene, (12) lithium stilbene and (13) lithium azobenzene; and N : Ndicyclohexylacrylamide with (10) lithium naphthalene. The products may be formed into films, filaments or other shaped articles. U.S.A. Specification 2,494,583 is referred to.
GB2790758A 1958-08-30 1958-08-30 Improvements in or relating to polyacrylamide derivatives Expired GB855741A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB2790758A GB855741A (en) 1958-08-30 1958-08-30 Improvements in or relating to polyacrylamide derivatives
GB3327460A GB914780A (en) 1958-08-30 1960-09-28 Improvements in or relating to polyacrylamide derivatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2790758A GB855741A (en) 1958-08-30 1958-08-30 Improvements in or relating to polyacrylamide derivatives

Publications (1)

Publication Number Publication Date
GB855741A true GB855741A (en) 1960-12-07

Family

ID=10267222

Family Applications (2)

Application Number Title Priority Date Filing Date
GB2790758A Expired GB855741A (en) 1958-08-30 1958-08-30 Improvements in or relating to polyacrylamide derivatives
GB3327460A Expired GB914780A (en) 1958-08-30 1960-09-28 Improvements in or relating to polyacrylamide derivatives

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB3327460A Expired GB914780A (en) 1958-08-30 1960-09-28 Improvements in or relating to polyacrylamide derivatives

Country Status (1)

Country Link
GB (2) GB855741A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5717049A (en) * 1996-03-25 1998-02-10 Pharmacia Iovision, Inc. High refractive index hydrogels prepared from polymers and copolymers of N-benzyl-N-methylacrylamide

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL89371A (en) * 1988-02-24 1993-07-08 Us Commerce Polyacrylamide gels, their preparation and their use for detection and separation of proteins
US4945006A (en) * 1989-01-17 1990-07-31 Minnesota Mining And Manufacturing Company Low odor adhesive compositions and bonding method employing same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5717049A (en) * 1996-03-25 1998-02-10 Pharmacia Iovision, Inc. High refractive index hydrogels prepared from polymers and copolymers of N-benzyl-N-methylacrylamide

Also Published As

Publication number Publication date
GB914780A (en) 1963-01-02

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