GB847343A - Improvements in the stabilisation of epoxidised fatty acid ester plasticisers - Google Patents

Improvements in the stabilisation of epoxidised fatty acid ester plasticisers

Info

Publication number
GB847343A
GB847343A GB40093/58A GB4009358A GB847343A GB 847343 A GB847343 A GB 847343A GB 40093/58 A GB40093/58 A GB 40093/58A GB 4009358 A GB4009358 A GB 4009358A GB 847343 A GB847343 A GB 847343A
Authority
GB
United Kingdom
Prior art keywords
ester
fatty acid
esters
aliphatic
epoxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB40093/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Corp
Original Assignee
FMC Corp
Food Machinery and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FMC Corp, Food Machinery and Chemical Corp filed Critical FMC Corp
Publication of GB847343A publication Critical patent/GB847343A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Compounds (AREA)

Abstract

Epoxy-containing fatty acid esters, prepared by epoxidation of an ester of an unsaturated fatty acid containing 12 to 22 carbon atoms with an aliphatic peracid formed in situ from hydrogen peroxide, an aliphatic acid and sulphuric acid, are stabilized by heating in the substantial absence of water and in the presence of a solid particulate hydroxide of sodium, potassium, calcium or barium. The treatment normally comprises mixing the ester with 1-5% by weight of the alkali and heating the mixture for 1/2 to 2 hours at a temperature of 30 DEG to 100 DEG C. The treatment is preferably carried out with agitation, and if desired in the presence of a liquid which is either a solvent or diluent for the ester but which is not a solvent for the alkali, e.g. aliphatic and cyclic hydrocarbons and water insoluble oxygenated and halogenated derivatives thereof. Typical unsaturated fatty acids useful in preparing the esters are myristoleic, palmitoleic, oleic, linoleic, elaeostearic, licanic, ricinoleic, erucic, parinaric, arachidonic and clupadonic acids. The epoxidation of the esters may be carried out as described in Specification 739,609. Examples describe the preparation of butyl epoxystearate, epoxy soybean oil and the hexyl ester of epoxidized tall oil fatty acids and the stabilization thereof.
GB40093/58A 1957-12-16 1958-12-12 Improvements in the stabilisation of epoxidised fatty acid ester plasticisers Expired GB847343A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US847343XA 1957-12-16 1957-12-16

Publications (1)

Publication Number Publication Date
GB847343A true GB847343A (en) 1960-09-07

Family

ID=22186885

Family Applications (1)

Application Number Title Priority Date Filing Date
GB40093/58A Expired GB847343A (en) 1957-12-16 1958-12-12 Improvements in the stabilisation of epoxidised fatty acid ester plasticisers

Country Status (1)

Country Link
GB (1) GB847343A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3150153A (en) * 1962-06-15 1964-09-22 Gen Mills Inc Stability of epoxidized oils by oxidation and naturalization

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3150153A (en) * 1962-06-15 1964-09-22 Gen Mills Inc Stability of epoxidized oils by oxidation and naturalization

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