GB842728A - Process for dyeing with pigments and synthetic resin compositions suitable therefor - Google Patents

Process for dyeing with pigments and synthetic resin compositions suitable therefor

Info

Publication number
GB842728A
GB842728A GB34716/56A GB3471656A GB842728A GB 842728 A GB842728 A GB 842728A GB 34716/56 A GB34716/56 A GB 34716/56A GB 3471656 A GB3471656 A GB 3471656A GB 842728 A GB842728 A GB 842728A
Authority
GB
United Kingdom
Prior art keywords
cation
ammonium
active
water
methosulphate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB34716/56A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba AG filed Critical Ciba AG
Publication of GB842728A publication Critical patent/GB842728A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

An aqueous dispersion for use in dyeing with pigments contains (i) a pigment dispersed with a cation-active dispersing agent and (ii), as sole binding agent, (a) a cation active dispersion of one or more addition polymers which are free from anion-active water solubilizing groups, or (b) an aqueous dispersion, produced with a cation active dispersing agent, of a hardenable amino plastic resin insoluble in water but soluble in organic solvents. The addition polymers may themselves contain cation-active groups, or they may contain no cation-active groups but be dispersed in a cation-active dispersing agent. There may also be added to the dispersion (iii) a water-soluble hardenable amino plastic resin. Specified materials are:-(i) as pigments, carbon black, titanium dioxide, iron oxide, Cu phthalocyanine; as dispersing agents, octadecylamine acetate, (dodecyl)-di-ethyl-cyclohexyl-amine sulphate, oleylamido ethyl-diethyl-amino-acetate, cetyldimethyl benzylammonium chloride, cetyltrimethyl-ammonium bromide, p-(trimethyl ammonium)-benzoic acid cetyl ester methosulphate, cetyl pyridinium methosulphate, octadecyl trimethyl ammonium bromide, the quaternary compound from diethyl sulphate and triethenolamine tristearate, [b -(octadecenoylamido)-ethyl]-diethylmethyl ammonium-methosulphate, [g -(laurylamido-)propyl]-diethylmethyl-ammonium-methosulphate (and for diethyl methyl read, trimethyl), [g -(stearylamido)-propyl]-dimethyl-(b -oxyethyl)-ammonium phosphate; (ii) (a) addition polymers, co-polymers, terpolymers and a quaterpolymer are derived from butadiene, 2-chloro-butadiene, vinyl-acetate,-formate,-butyrate or -benzoate, vinyl alkyl ketones, vinyl isobutyl ether, styrene, isobutylene, methyl-ethyl-, n-or iso-butyl- or dodecyl acrylates, acrylonitrile, acrylamide, the nitriles or amides of methacrylic, a -chloro-acrylic or crotonic acids, the quaternary compound from acrylic acid-(3-diethylaminopropyl)-amide and chloroacetamide, the nitriles or amides of maleic or fumaric acids, vinylchloride or fluoride, vinylidenechloride, asym. dichloroethylene, or vinyl pyridines; (iii) (b) the water-insoluble amino plastics may be derived from formaldehyde and urea, thiourea, guanidine, acetylene-di-ureine, dicyandiamide, uron melamine, aceto-, benzo- or formoguanam ine, modified by butyl, amyl, hexyl, benzyl, lauryl, oleyl, abietyl or allyl alcohols, cyclohexanol, stearic acid and/or soya fatty acids; (iii) the water-soluble aminoplasts are prepared from the same amino-compounds but are either unmodified or modified with methanol or ethanol. Hardeners, e.g. NH4NO3, may be added. For processes of dyeing specified materials (see Group IV(c)). Specifications 777,488, 796,543 and 842,727 are referred to.ALSO:In a process for dyeing with pigments, an aqueous dyebath is used containing (i) a pigment dispersed with a cation-active dispersing agent and (ii), as sole binding agent, (a) a cationactive dispersion of one or more addition polymers which are free from anion-active water solubilizing groups, or (b) an aqueous dispersion, produced with a cation-active dispersing agent, of a hardenable aminoplastic resin insoluble in water but soluble in organic solvents; the material is then dried and, when a hardenable compound is used, hardening at an elevated temperature follows. The addition polymers may themselves contain cation-active groups, or they may contain no cation-active groups but be dispersed in a cation-active dispersing agent. There may also be added to the dispersion (iii) a water-soluble hardenable aminoplastic resin. Specified materials are: (i) as pigments, carbon black, titanium dioxide, iron oxide, copper phthalocyanine and organic vat or azo dyestuff pigments; as dispersing agents, octadecylamine acetate, (dodecyl)-diethyl-cydohexyl-amine sulphate, oleylamidoethyl-diethyl-amino-acetate, cetyl dimethyl benzylammonium chloride, cetyl-trimethyl-ammonium-bromide, p-(trimethyl ammonium)-benzoic acid cetyl ester methosulphate, cetyl pyridinium methosulphate, octadecyl trimethylammonium bromide, the quaternary compound from diethyl sulphate and triethanolamine tristearate, [b -octadecenoylamido)-ethyl] diethylmethyl ammonium-methosulphate, [g -(lauroylamido-) propyl]-diethyl methyl-ammonium-methosulphate (and for diethyl methyl read trimethyl), [g -(stearylamido)-propyl]-dimethyl-(b -oxyethyl) ammonium phosphate; (ii) (a) addition polymers, copolymers, terpolymers and a quaterpolymer are derived from butadiene, 2-chloro-butadiene, vinyl-acetate, -formate, -butyrate or -benzoate, vinyl alkyl ketones, vinyl isobutyl ether, styrene, isobutylene, methyl-, ethyl-,n- or iso-butyl- or dodecyl acrylates, acrylonitrile, acrylamide, the nitriles or amides of methacrylic, a -chloro-acrylic or crotonic acids, the quaternary compound from acrylic acid -(3-diethylamino propyl)-amide and chloracetamide, the nitriles or amides of maleic or fumaric acids, vinyl chloride or fluoride, vinylidene chloride, asym. dichloroethylene, or vinyl pyridines; (ii) (b) the water-insoluble aminoplastics may be derived from formaldehyde and urea, thiourea, guanidine, acetylene-di-ureine, dicyandiamide, uron, melamine, aceto-, benzo- or formo-guanamine, modified by butyl, amyl, hexyl, benzyl, lauryl, oleyl, abietyl, or allyl alcohols, cyclohexanol, stearic acid and/or soya fatty acids; (iii) the water-soluble aminoplasts are prepared from the same amino-compounds but are either unmodified or modified with methanol or ethanol. Hardeners, e.g. ammonium nitrate, may be added, in which case hardening takes place at 120-160 DEG C. for 2-10 minutes. The dyeing may be by the exhaust or the foulard process, and the fibrous materials which may be dyed include fabrics of natural or regenerated cellulose, e.g. cotton (poplin) or linen, acetate silk, wool or synthetic fibres, e.g. nylon, polyesters or polyacrylonitrile. Specifications 777,488, 796,543 and 842,727 are referred to.
GB34716/56A 1955-11-30 1956-11-13 Process for dyeing with pigments and synthetic resin compositions suitable therefor Expired GB842728A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH842728X 1955-11-30

Publications (1)

Publication Number Publication Date
GB842728A true GB842728A (en) 1960-07-27

Family

ID=4541446

Family Applications (1)

Application Number Title Priority Date Filing Date
GB34716/56A Expired GB842728A (en) 1955-11-30 1956-11-13 Process for dyeing with pigments and synthetic resin compositions suitable therefor

Country Status (1)

Country Link
GB (1) GB842728A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000055420A1 (en) * 1999-03-18 2000-09-21 Zydex Industries Method of pigment dyeing anionic materials
GB2504207A (en) * 2012-06-13 2014-01-22 Afton Chemical Corp Fuel additive for improved performance in fuel injected engines
US9340742B1 (en) 2015-05-05 2016-05-17 Afton Chemical Corporation Fuel additive for improved injector performance
US11390821B2 (en) 2019-01-31 2022-07-19 Afton Chemical Corporation Fuel additive mixture providing rapid injector clean-up in high pressure gasoline engines

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000055420A1 (en) * 1999-03-18 2000-09-21 Zydex Industries Method of pigment dyeing anionic materials
GB2504207A (en) * 2012-06-13 2014-01-22 Afton Chemical Corp Fuel additive for improved performance in fuel injected engines
US8894726B2 (en) 2012-06-13 2014-11-25 Afton Chemical Corporation Fuel additive for improved performance in fuel injected engines
GB2504207B (en) * 2012-06-13 2015-02-11 Afton Chemical Corp Fuel additive for improved performance in fuel injected engines
US9340742B1 (en) 2015-05-05 2016-05-17 Afton Chemical Corporation Fuel additive for improved injector performance
US11390821B2 (en) 2019-01-31 2022-07-19 Afton Chemical Corporation Fuel additive mixture providing rapid injector clean-up in high pressure gasoline engines

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