GB841190A - Process for producing and recovering aromatic hydrocarbons - Google Patents

Process for producing and recovering aromatic hydrocarbons

Info

Publication number
GB841190A
GB841190A GB183159A GB183159A GB841190A GB 841190 A GB841190 A GB 841190A GB 183159 A GB183159 A GB 183159A GB 183159 A GB183159 A GB 183159A GB 841190 A GB841190 A GB 841190A
Authority
GB
United Kingdom
Prior art keywords
alumina
silica
cut
solvent
gasoline
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB183159A
Inventor
Richard Marston Deanesly
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Priority to GB183159A priority Critical patent/GB841190A/en
Publication of GB841190A publication Critical patent/GB841190A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Aromatic hydrocarbons are obtained by reforming a gasoline employing the hydrogen formed to hydrorefine a coke oven light oil derived from coal and containing non-hydrocarbon impurities, combining the refined oil and the reformate and solvent extracting to obtain an aromatic fraction. The reforming may be effected with a platinum or palladium catalyst supported on alumina with or without halogen, silica-alumina or silica magnesia at 425-600 DEG C. and 3-70 atmospheres with a hydrogen to hydrocarbon mol. ratio between 1 and 15:1. The gasoline may be a full boiling range straight-run gasoline or have an initial boiling point between 65-120 DEG C. and a final boiling point of 145-190 DEG C. The volume ratio of gasoline to coke oven light oil is generally 0.25 to 0.4:1. The hydrofining may be effected with a mixture of the oxides or sulphides of cobalt and molybdenum supported on alumina, silicaalumina, silica-magnesia or magnesia-alumina or composites of nickel and tungsten sulphides supported on alumina or silica-alumina, at 315-425 DEG C. and 3-100 atmospheres. Either or both of the liquid products from the two stages may be fractionated to separate materials boiling below and/or above the desired hydrocarbon, e.g. a benzene cut, a toluene cut, a xylene cut, a benzene-toluene cut or a toluenexylene cut may be separated. The solvent extraction may be effected with a glycol, e.g. ethylene, diethylene, propylene, dipropylene, butylene or dibutylene glycol or mixtures thereof, together with, if desired, 2-25% (by weight of the total solvent) of water. Alcohols, phenols, ethers, nitriles or esters can also be used. A temperature of atmospheric to 250 DEG C. can be used at 2-25 atmospheres to maintain the liquid phase using 2-20 volumes of solvent per volume of hydrocarbon. The raffinate may be recycled to the reforming operation. Aromatic hydrocarbons are stripped from the solvent and fractionated to separate individual hydrocarbons if desired and may be purified by contact with clay or other adsorbent at up to 250 DEG C.ALSO:Aromatic hydrocarbons are obtained by reforming a gasoline employing the hydrogen formed to hydrorefine a coke-oven light oil derived from coal and containing non-hydrocarbon impurities, combining the refined oil and the reformate and solvent extracting to obtain an aromatic fraction. The reforming may be effected with a platinum or palladium catalyst supported on alumina with or without halogen, silica-alumina or silica-magnesia at 425-600 DEG C. and 3-70 atmospheres with a hydrogen to hydrocarbon mol. ratio between 1 and 15 : 1. The gasoline may be a full boiling range straight-run gasoline or have an initial boiling point between 65-120 DEG C. and a final boiling point of 145-190 DEG C. The volume ratio of gasoline to coke-oven light oil is generally 0.25 to 0.4 : 1. The hydrofining may be effected with a mixture of the oxides or sulphides of cobalt and molybdenum supported on alumina, silica-alumina, silica-magnesia or magnesia-alumina or composites of nickel and tungsten sulphides supported on alumina or silica-alumina, at 315-425 DEG C. and 3-100 atmospheres. Either or both of the liquid products from the two stages may be fractionated to separate materials boiling below and/or above the desired hydrocarbon, e.g. a benzene cut, a toluene cut, a xylene cut, a benzene-toluene cut or a toluene-xylene cut may be separated. The solvent extraction may be effected with a glycol, e.g. ethylene, diethylene, propylene, dipropylene, butylene or dibutylene glycol or mixtures thereof, together with, if desired, 2-25% (by weight of the total solvent) of water. Alcohols, phenols, ethers, nitriles or esters can also be used. A temperature of atmospheric to 250 DEG C. can be used at 2-25 atmospheres to maintain the liquid phase using 2-20 volumes of solvent per volume of hydrocarbon. The raffinate may be recycled to the reforming operation. Aromatic hydrocarbons are stripped from the solvent and fractionated to separate individual hydrocarbons if desired, and may be purified by contact with clay or other adsorbent at up to 250 DEG C.
GB183159A 1959-01-19 1959-01-19 Process for producing and recovering aromatic hydrocarbons Expired GB841190A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB183159A GB841190A (en) 1959-01-19 1959-01-19 Process for producing and recovering aromatic hydrocarbons

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB183159A GB841190A (en) 1959-01-19 1959-01-19 Process for producing and recovering aromatic hydrocarbons

Publications (1)

Publication Number Publication Date
GB841190A true GB841190A (en) 1960-07-13

Family

ID=9728764

Family Applications (1)

Application Number Title Priority Date Filing Date
GB183159A Expired GB841190A (en) 1959-01-19 1959-01-19 Process for producing and recovering aromatic hydrocarbons

Country Status (1)

Country Link
GB (1) GB841190A (en)

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