GB841190A - Process for producing and recovering aromatic hydrocarbons - Google Patents
Process for producing and recovering aromatic hydrocarbonsInfo
- Publication number
- GB841190A GB841190A GB183159A GB183159A GB841190A GB 841190 A GB841190 A GB 841190A GB 183159 A GB183159 A GB 183159A GB 183159 A GB183159 A GB 183159A GB 841190 A GB841190 A GB 841190A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alumina
- silica
- cut
- solvent
- gasoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Aromatic hydrocarbons are obtained by reforming a gasoline employing the hydrogen formed to hydrorefine a coke oven light oil derived from coal and containing non-hydrocarbon impurities, combining the refined oil and the reformate and solvent extracting to obtain an aromatic fraction. The reforming may be effected with a platinum or palladium catalyst supported on alumina with or without halogen, silica-alumina or silica magnesia at 425-600 DEG C. and 3-70 atmospheres with a hydrogen to hydrocarbon mol. ratio between 1 and 15:1. The gasoline may be a full boiling range straight-run gasoline or have an initial boiling point between 65-120 DEG C. and a final boiling point of 145-190 DEG C. The volume ratio of gasoline to coke oven light oil is generally 0.25 to 0.4:1. The hydrofining may be effected with a mixture of the oxides or sulphides of cobalt and molybdenum supported on alumina, silicaalumina, silica-magnesia or magnesia-alumina or composites of nickel and tungsten sulphides supported on alumina or silica-alumina, at 315-425 DEG C. and 3-100 atmospheres. Either or both of the liquid products from the two stages may be fractionated to separate materials boiling below and/or above the desired hydrocarbon, e.g. a benzene cut, a toluene cut, a xylene cut, a benzene-toluene cut or a toluenexylene cut may be separated. The solvent extraction may be effected with a glycol, e.g. ethylene, diethylene, propylene, dipropylene, butylene or dibutylene glycol or mixtures thereof, together with, if desired, 2-25% (by weight of the total solvent) of water. Alcohols, phenols, ethers, nitriles or esters can also be used. A temperature of atmospheric to 250 DEG C. can be used at 2-25 atmospheres to maintain the liquid phase using 2-20 volumes of solvent per volume of hydrocarbon. The raffinate may be recycled to the reforming operation. Aromatic hydrocarbons are stripped from the solvent and fractionated to separate individual hydrocarbons if desired and may be purified by contact with clay or other adsorbent at up to 250 DEG C.ALSO:Aromatic hydrocarbons are obtained by reforming a gasoline employing the hydrogen formed to hydrorefine a coke-oven light oil derived from coal and containing non-hydrocarbon impurities, combining the refined oil and the reformate and solvent extracting to obtain an aromatic fraction. The reforming may be effected with a platinum or palladium catalyst supported on alumina with or without halogen, silica-alumina or silica-magnesia at 425-600 DEG C. and 3-70 atmospheres with a hydrogen to hydrocarbon mol. ratio between 1 and 15 : 1. The gasoline may be a full boiling range straight-run gasoline or have an initial boiling point between 65-120 DEG C. and a final boiling point of 145-190 DEG C. The volume ratio of gasoline to coke-oven light oil is generally 0.25 to 0.4 : 1. The hydrofining may be effected with a mixture of the oxides or sulphides of cobalt and molybdenum supported on alumina, silica-alumina, silica-magnesia or magnesia-alumina or composites of nickel and tungsten sulphides supported on alumina or silica-alumina, at 315-425 DEG C. and 3-100 atmospheres. Either or both of the liquid products from the two stages may be fractionated to separate materials boiling below and/or above the desired hydrocarbon, e.g. a benzene cut, a toluene cut, a xylene cut, a benzene-toluene cut or a toluene-xylene cut may be separated. The solvent extraction may be effected with a glycol, e.g. ethylene, diethylene, propylene, dipropylene, butylene or dibutylene glycol or mixtures thereof, together with, if desired, 2-25% (by weight of the total solvent) of water. Alcohols, phenols, ethers, nitriles or esters can also be used. A temperature of atmospheric to 250 DEG C. can be used at 2-25 atmospheres to maintain the liquid phase using 2-20 volumes of solvent per volume of hydrocarbon. The raffinate may be recycled to the reforming operation. Aromatic hydrocarbons are stripped from the solvent and fractionated to separate individual hydrocarbons if desired, and may be purified by contact with clay or other adsorbent at up to 250 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB183159A GB841190A (en) | 1959-01-19 | 1959-01-19 | Process for producing and recovering aromatic hydrocarbons |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB183159A GB841190A (en) | 1959-01-19 | 1959-01-19 | Process for producing and recovering aromatic hydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
GB841190A true GB841190A (en) | 1960-07-13 |
Family
ID=9728764
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB183159A Expired GB841190A (en) | 1959-01-19 | 1959-01-19 | Process for producing and recovering aromatic hydrocarbons |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB841190A (en) |
-
1959
- 1959-01-19 GB GB183159A patent/GB841190A/en not_active Expired
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3617495A (en) | Process for production of olefins and acetylene | |
US3835037A (en) | Purification of aromatic hydrocarbons | |
GB1301019A (en) | A process for the hydrogenation of pyrolysis gasoline | |
GB1080586A (en) | Process for producing high purity benzene | |
US3985644A (en) | Use of water/methanol mixtures as solvents for aromatics extraction | |
GB889789A (en) | Improvements in or relating to the recovery of naphthalene from petroleum fractions | |
GB841190A (en) | Process for producing and recovering aromatic hydrocarbons | |
US3556987A (en) | Process for the production of acetylene,ethylene and aromatics | |
US3317622A (en) | Polycyclic aromatics for hydrodealkylation | |
GB830806A (en) | Process for the production í¡í¡ octane gasolines | |
US2223133A (en) | Treatment of petroleum products | |
US3271297A (en) | Recycle of monoolefines to a hydrocarbon pyrolysis process | |
EP0153112A1 (en) | Electrical insulating oil | |
US2345877A (en) | Manufacture of liquid hydrocarbons | |
GB825353A (en) | A process for improving straight-run gasoline | |
EP0164229B1 (en) | Straight chain paraffin producing material | |
GB836104A (en) | Fuel composition | |
US2234207A (en) | Process of making heavy fuel oil | |
US3649517A (en) | Resins prepared from aromatic hydrocarbons | |
GB1116107A (en) | Process for producing aromatic hydrocarbons | |
US2983666A (en) | Hydrorefining of low-temperature tar fractions | |
US3317623A (en) | Polycyclic aromatics by two-stage hydrodealkylation | |
US3484367A (en) | Process for the hydrogenation of benzene | |
GB698332A (en) | Improvements in or relating to the refining and catalytic cracking of hydrocarbons | |
GB585497A (en) | Improved process for the production of aviation gasoline |