GB839480A - Relating to coating compositions - Google Patents
Relating to coating compositionsInfo
- Publication number
- GB839480A GB839480A GB1186757A GB1186757A GB839480A GB 839480 A GB839480 A GB 839480A GB 1186757 A GB1186757 A GB 1186757A GB 1186757 A GB1186757 A GB 1186757A GB 839480 A GB839480 A GB 839480A
- Authority
- GB
- United Kingdom
- Prior art keywords
- butyl
- peroxide
- methacrylate
- methyl
- toluene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Coating compositions (see Group IV (a)) comprising a liquid carrier and as the predominant resinous component an interpolymer of 50 to 90% by weight of methyl methacrylate and 10 to 50% by weight of another alkyl ester of an ethylenically unsaturated carboxylic acid, said interpolymer having a viscosity of 25 to 320 centistokes when measured at 25 DEG C. as a solution of 25% solids in toluene, may be coated on wood, plastic and metal, e.g. car body panels. The metal may be unprimed, primed and coated with highly pigmented surfacers and undercoats, or with a single primer-surfacer composition comprising nitrocellulose, polyvinyl acetal, alkyd resins or shellac, the base coats being baked before applying top coats according to the invention. Examples describe the application by spraying of (vii) a composition comprising a methyl methacrylate-ethyl acetate copolymer, butyl benzyl phthalate, titanium dioxide, toluene and monoethyl ether of ethylene glycol acetate to primed steel panels; (viii) compositions comprising a methyl methacrylate-ethyl acrylate copolymer, titanium dioxide, polyethylene, butyl benzyl phthalate, toluene and monoethyl ether of ethylene glycol acetate to metal panels which had been "Bonderised" (Registered Trade Mark), primed, coated with a highly pigmented surfacer and a filler prepared from nitrocellulose, a soya oil modified alkyd resin and chlorinated biphenyl; and (ix) compositions comprising a methyl methacrylate-n-butyl methacrylate copolymer, titanium dioxide, phthalocyanine blue, carbon black, butyl benzyl phthalate, toluene and the monoethyl ether of ethylene glycol acetate to primed steel panels.ALSO:Coating compositions comprise a liquid carrier and as the predominant resinous component an interpolymer of 50 to 90% by weight of methyl methacrylate and 10 to 50% by weight of another alkyl ester of an ethylenically unsaturated carboxylic acid, said interpolymer having a viscosity of 25 to 320 centistokes when measured at 25 DEG C. as a solution of 25% solids in toluene. Specified alkyl esters are ethyl acrylate, propyl acrylate, butyl acrylate, octyl acrylate, ethyl methacrylate, n-butyl methacrylate, hexyl methacrylate, octyl methacrylate, lauryl methacrylate, mixed octyl and decyl methacrylates, dimethyl itaconate, diethyl itaconate and dibutyl itaconate. Minor amounts of additional comonomers, e.g. N-t.-butyl acrylamide and methacrylic acid (Example VI), may also be used. The interpolymers may be prepared by polymerization in solution, emulsion or suspension, e.g. in the presence of protective colloids such as polyvinyl alcohol, sodium polyacrylate, polyacrylamide, bentonite, starch or magnesium silicate, in the presence of catalysts, e.g. acetyl peroxide, benzoyl peroxide, lauroyl peroxide, acetyl benzoyl peroxide, hydroxyheptyl peroxide, 2,4-dichlorobenzoyl peroxide, dicumyl peroxide, di-t-butyl peroxide, p-chlorobenzoyl peroxide, cyclohexyl hydroperoxide, cumene hydroperoxide, t-butyl hydroperoxide, methyl cyclohexyl hydroperoxide, methyl ethyl ketone peroxide, cyclohexanone peroxide, methyl amyl ketone peroxide, peracetic acid, t-butyl peracetate, t-butyl permaleic acid, di-t-butyl perphthalate, t-perphthalic acid, potassium persulphate, ammonium persulphate, a ,a -azo-diisobutyronitrile and p-methoxy phenyl diazo-thio-(2-naphthyl) ether, buffers, e.g. mono- and disodium phospahtes, and chain transfer agents, e.g. dodecyl mercaptan, tertiary dodecyl mercaptan, octyl mercaptan, hexyl mercaptan, carbon tetrachloride, allyl acetate, allyl carbamate, isopropyl benzene, butyl chloride, acetic acid and dioxane. The polymers may be dissolved in solvents, e.g. toluene, xylene, acetone, methyl ethyl ketone, methyl amyl ketone, monoethyl ether of glycol acetate, ethyl acetate, isopropyl acetate, amyl acetate, heptane, octane, methyl alcohol, isopropyl alcohol, amyl alcohol and diacetone alcohol, together with plasticizers, e.g. butyl benzyl phthalate, tricresyl phosphate, dioctyl phthalate, dicyclohexyl phthalate, di-3,5,5-trimethyl hexyl phthalate, butyl cyclohexyl phthalate, epoxidized oils and castor oil acetoacetate, pigments, e.g. carbon black, titanium dioxide, phthalocyanine greens and blues, metal oxides and sulphides and metal, e.g. aluminium, flake pigments, fillers and extenders, e.g. talc, kieselguhr, clays, silicates and diatomaceous earth, silicones, nitrocellulose, polyvinyl acetal resins and polyethylene. The composition may be coated on bare or primed metal, e.g. car bodies, wood and plastics.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US58447456A | 1956-05-14 | 1956-05-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB839480A true GB839480A (en) | 1960-06-29 |
Family
ID=24337460
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1186757A Expired GB839480A (en) | 1956-05-14 | 1957-04-11 | Relating to coating compositions |
GB1698462A Expired GB991802A (en) | 1956-05-14 | 1962-05-03 | Coating compositions |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1698462A Expired GB991802A (en) | 1956-05-14 | 1962-05-03 | Coating compositions |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE557326A (en) |
CH (1) | CH368570A (en) |
FR (1) | FR1175483A (en) |
GB (2) | GB839480A (en) |
NL (2) | NL97015C (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3198654A (en) * | 1961-12-21 | 1965-08-03 | Pittsburgh Plate Glass Co | Coating system |
GB2155943A (en) * | 1984-03-20 | 1985-10-02 | Erba Farmitalia | Composition for mounting microscope slide specimens |
EP1500689A1 (en) * | 2003-07-24 | 2005-01-26 | Celanese Emulsions GmbH | Coating composition and method for its preparation |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1396128A (en) * | 1971-07-16 | 1975-06-04 | Monier Research Dev Pty Ltd | Acrylic polymers and acrylic coatings |
CA2021957A1 (en) * | 1989-09-11 | 1991-03-12 | Hans G. Feichtmeier | Abrasion resistant ionomeric film |
CN108948888A (en) * | 2018-08-19 | 2018-12-07 | 柳州市家富连装饰有限公司 | A kind of indoor decoration water paint and preparation method thereof |
-
0
- NL NL216873D patent/NL216873A/xx unknown
- BE BE557326D patent/BE557326A/xx unknown
- NL NL97015D patent/NL97015C/xx active
-
1957
- 1957-04-11 GB GB1186757A patent/GB839480A/en not_active Expired
- 1957-05-07 FR FR1175483D patent/FR1175483A/en not_active Expired
- 1957-05-09 CH CH4589357A patent/CH368570A/en unknown
-
1962
- 1962-05-03 GB GB1698462A patent/GB991802A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3198654A (en) * | 1961-12-21 | 1965-08-03 | Pittsburgh Plate Glass Co | Coating system |
GB2155943A (en) * | 1984-03-20 | 1985-10-02 | Erba Farmitalia | Composition for mounting microscope slide specimens |
EP1500689A1 (en) * | 2003-07-24 | 2005-01-26 | Celanese Emulsions GmbH | Coating composition and method for its preparation |
Also Published As
Publication number | Publication date |
---|---|
CH368570A (en) | 1963-04-15 |
BE557326A (en) | |
NL97015C (en) | |
GB991802A (en) | 1965-05-12 |
FR1175483A (en) | 1959-03-26 |
NL216873A (en) |
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