GB835719A - Process for the optical brightening of artificial fibres - Google Patents

Process for the optical brightening of artificial fibres

Info

Publication number
GB835719A
GB835719A GB38605/56A GB3860556A GB835719A GB 835719 A GB835719 A GB 835719A GB 38605/56 A GB38605/56 A GB 38605/56A GB 3860556 A GB3860556 A GB 3860556A GB 835719 A GB835719 A GB 835719A
Authority
GB
United Kingdom
Prior art keywords
derivatives
dibiguanide
formaldehyde
acid
artificial
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB38605/56A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba AG filed Critical Ciba AG
Publication of GB835719A publication Critical patent/GB835719A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60Optical bleaching or brightening

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Artificial fibres are impregnated with an aqueous preparation containing (1) an optical brightening agent having no brightening effect upon the fibre when applied by exhaustion of a dilute bath at elevated temperature, and (2) an artificial resin; they are then dried. The preparations may be applied at room or slightly elevated temperature by spraying or by treatment on the foulard. Fibres treated may be of cellulose triacetate, polyamides, polyurethanes, polyacrylonitrile or polyesters, e.g. of terephthalic acid and glycol, or of mixtures or copolymers of polycondensation or polymerization products, or mixtures of such artificial fibres or of artificial and natural fibres of animal or vegetable origin, e.g. in mixed yarns or mixed fabrics, may be treated. The preparations may contain dispersing or emulsifying agents. The optical brightening agent and resin may be selected so that one is basic and the other acidic. The many optical brightening agents specified include bisazole, dibenzazole, and azole compounds and derivatives; coumarin derivatives; stilbene derivatives which may not contain triazine rings; bisstyryl-benzene derivatives; benzidine sulphone derivatives; 1 : 2 : 3-triazole derivatives; pyrazoline derivatives; oxacyanine derivatives; oxdiazoles; imidazolones; dehydrocollidine derivatives and naphthalene-1 : 8-dicarboxylic acid imides. The many artificial resins specified include polyvinyl acetate; copolymers from isobutyl acrylate, acrylonitrile and acrylic acid; from n-butyl acrylate, vinyl acetate and acrylic acid; from the compound <FORM:0835719/IV(c)/1> and vinyl acetate or from these two components and n-butyl acrylate; condensation products of formaldehyde and urea, melamine, dicyandiamide, the reaction product of ethylene diamine dihydrochloride and dicyandiamide, acetoguanamine, acetoguanidine, biguanide, dicyandiamidine, ethylene dibiguanide, 1 : 3-propylene dibiguanide, 1 : 6-hexamethylene dibiguanide, 1 : 4 - cyclohexylene dibiguanide, melam, melem, ammeline, ammelide, 2-chloro-4 : 6 - diamino - 1 : 3 : 5 - triazine, benzoguanamine, acetoguanamine, formoguanamine, guanyl melamines, a mixture of methylol-melamine-methyl ethers or acetylene di-urea; and a condensation product (obtained step-wise) of stearic acid methylolamide, triethanolamine and methylol melamine methyl ether reacted with glacial acetic acid. The basic formaldehyde condensates may be used as salts with hydrochloric, sulphuric, formic, acetic, propionic or glycollic acid. Also included are copolymers of unsaturated acids containing hydrazide or hydrazide derivative groups with other unsaturated compounds and condensates of ethers of low M.W. aliphatic alcohols, e.g. methanol, with methylol-melamines.ALSO:Artificial textile fibres are treated with an aqueous composition which contains an optical brightening agent having no brightening effect upon the fibre when applied by exhaustion of a dilute bath at elevated temperature, and an artificial resin. Emulsifying or dispersing agents may be added. The optical brightening agents specified include bisazole, dibenzazole and azole compounds and derivatives; coumarin derivatives, stilbene derivatives which may or may not contain triazine rings; bis-styryl-benzene derivatives; benzidine sulphone derivatives; 1:2:3 triazole derivatives; pyrazoline derivatives; oxacyanine derivatives; oxdiazoles; imidazolones; dehydrocollidine derivatives and naphthalene-1:8-dicarboxylic acid imides. The resins specified include polyvinyl acetate; copolymers from isobutyl acrylate, acrylonitrile and acrylic acid; n-butyl acrylate, vinyl acetate and acrylic acid; the quaternary compound H2C = CHCONH(CH2)3N(CH2CONH) (C2H5)2(Cl) and vinyl acetate or these two components and n-butyl acrylate and copolymers of unsaturated acids containing hydrazide or hydrazide derivative groups with other unsaturated compounds. Also specified are condensation products of up to 4 mols. of formaldehyde with one mol. of urea, dicyandiamide, dicyandiamidine, guanidine, acetoguanidine, biguanide, ethylene biguanide, 1:3 - propylene dibiguanide, 1:6-hexamethylene dibiguanide, 1:4 cyclohexylene dibiguanide and their alkyl or hydroxyalkyl derivatives, organic nitrogen compounds produced by heating dicyandiamide with hydrochlorides or sulphates of aliphatic or cycloaliphatic amines containing at least 2 primary or secondary amino groups or chlorides of polyalkylene polyamines or of such polyamines as are obtained by reacting ethylene dihalides or glycerol dichlorohydrins with ammonia or alkanolamines, the condensates being obtained by reacting the components either alone or in the presence of a solvent or in the presence of caustic soda at 90 DEG to 95 DEG C. or in the presence of sulphuric or hydrochloric acid and acetic or formic acid under pressure at 80 DEG to 100 DEG C. A condensation resin specified is obtained by reacting 2 mols. of a non-cyclic compound containing at least once the group <FORM:0835719/IV (a)/1> in a first stage with 0.5 to 4 mols. of formaldehyde and 1 mol. of a salt of an aliphatic amine containing at least 2 primary or secondary amino groups, at above 100 DEG C., e.g. by reacting the organic nitrogen compounds at 150 DEG to 260 DEG C. and then condensing the product with paraformaldehyde at 170 DEG to 180 DEG C., or in the presence of a solvent at 110 DEG to 130 DEG C., and in a second stage condensing with 1 to 8 mols. of formaldehyde. Also specified are condensates of formaldehyde with melamine, melam, melem, ammeline, ammelide, 2-chloro-4:6-diamino-1:3:5 triazine, benzoguanamine, acetoguanamine formoguanamine, methylol melamine methylether, stearic acid methylolamide, tertiary amines containing a reactive hydrogen atom attached to an O or S atom, e.g. triethanolamine, guanylmelamines and mixtures thereof and substituted guanyl melamines. The condensates may be used as salts with hydrochloric, sulphuric, formic, acetic, propionic or glycollic acids. Other resins specified include reaction products of condensates of formaldehyde and aminotriazines or "urea compounds" which contain at least one methylol group etherified with a low molecular alcohol, nitriles or amides of unsaturated polymerizable acids and compounds with at least one active hydrogen atom which are capable of becoming attached to double bonds of the unsaturated compound. Examples are given.
GB38605/56A 1955-12-20 1956-12-18 Process for the optical brightening of artificial fibres Expired GB835719A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH835719X 1955-12-20

Publications (1)

Publication Number Publication Date
GB835719A true GB835719A (en) 1960-05-25

Family

ID=4540690

Family Applications (1)

Application Number Title Priority Date Filing Date
GB38605/56A Expired GB835719A (en) 1955-12-20 1956-12-18 Process for the optical brightening of artificial fibres

Country Status (1)

Country Link
GB (1) GB835719A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3184459A (en) * 1965-05-18 Chs chj
USRE30227E (en) 1973-11-29 1980-03-11 Ciba-Geigy Corporation Agent for brightening and removing greyness from textiles
GB2210374A (en) * 1987-09-24 1989-06-07 Acushnet Co Improvements in clear coats
US5018742A (en) * 1987-09-24 1991-05-28 Acushnet Company Golf ball clear coating with optical brighteners
US5160536A (en) * 1991-04-18 1992-11-03 Acushnet Company Printing ink for golf balls
CN111757684A (en) * 2018-02-15 2020-10-09 花王株式会社 Human hair fiber treating agent

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3184459A (en) * 1965-05-18 Chs chj
USRE30227E (en) 1973-11-29 1980-03-11 Ciba-Geigy Corporation Agent for brightening and removing greyness from textiles
GB2210374A (en) * 1987-09-24 1989-06-07 Acushnet Co Improvements in clear coats
US4865326A (en) * 1987-09-24 1989-09-12 Acushnet Company Optical brightners in golf ball clear coatings
US5018742A (en) * 1987-09-24 1991-05-28 Acushnet Company Golf ball clear coating with optical brighteners
GB2210374B (en) * 1987-09-24 1991-12-18 Acushnet Co Improvements in clear coats
US5160536A (en) * 1991-04-18 1992-11-03 Acushnet Company Printing ink for golf balls
CN111757684A (en) * 2018-02-15 2020-10-09 花王株式会社 Human hair fiber treating agent

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