GB834962A - Processes and compositions for imparting water-repellency - Google Patents
Processes and compositions for imparting water-repellencyInfo
- Publication number
- GB834962A GB834962A GB1035058A GB1035058A GB834962A GB 834962 A GB834962 A GB 834962A GB 1035058 A GB1035058 A GB 1035058A GB 1035058 A GB1035058 A GB 1035058A GB 834962 A GB834962 A GB 834962A
- Authority
- GB
- United Kingdom
- Prior art keywords
- specified
- water
- acrylic
- compositions
- acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 229910052725 zinc Inorganic materials 0.000 abstract 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- 239000000839 emulsion Substances 0.000 abstract 4
- 239000000049 pigment Substances 0.000 abstract 4
- 239000011148 porous material Substances 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- 239000005871 repellent Substances 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- -1 tiles Substances 0.000 abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 2
- 229910000906 Bronze Inorganic materials 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 2
- 235000021355 Stearic acid Nutrition 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 239000010425 asbestos Substances 0.000 abstract 2
- 239000011449 brick Substances 0.000 abstract 2
- 239000010974 bronze Substances 0.000 abstract 2
- 230000001413 cellular effect Effects 0.000 abstract 2
- 239000004568 cement Substances 0.000 abstract 2
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 abstract 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052571 earthenware Inorganic materials 0.000 abstract 2
- 239000003995 emulsifying agent Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052745 lead Inorganic materials 0.000 abstract 2
- 239000010985 leather Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 150000002825 nitriles Chemical class 0.000 abstract 2
- 239000000123 paper Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 229920001296 polysiloxane Polymers 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 238000009877 rendering Methods 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229910052895 riebeckite Inorganic materials 0.000 abstract 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 2
- 229920003002 synthetic resin Polymers 0.000 abstract 2
- 239000000057 synthetic resin Substances 0.000 abstract 2
- 239000004753 textile Substances 0.000 abstract 2
- 229920005992 thermoplastic resin Polymers 0.000 abstract 2
- 239000002562 thickening agent Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- BCVZNCWCAQBFPQ-UHFFFAOYSA-N 1,4-diethoxy-1,4-dioxobutane-2-sulfonic acid;sodium Chemical compound [Na].CCOC(=O)CC(S(O)(=O)=O)C(=O)OCC BCVZNCWCAQBFPQ-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- KXHPPCXNWTUNSB-UHFFFAOYSA-M benzyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1=CC=CC=C1 KXHPPCXNWTUNSB-UHFFFAOYSA-M 0.000 abstract 1
- 230000001680 brushing effect Effects 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 239000011111 cardboard Substances 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical class 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 1
- UPHWVVKYDQHTCF-UHFFFAOYSA-N octadecylazanium;acetate Chemical compound CC(O)=O.CCCCCCCCCCCCCCCCCCN UPHWVVKYDQHTCF-UHFFFAOYSA-N 0.000 abstract 1
- 235000021313 oleic acid Nutrition 0.000 abstract 1
- 150000002889 oleic acids Chemical class 0.000 abstract 1
- 230000002940 repellent Effects 0.000 abstract 1
- 239000008117 stearic acid Substances 0.000 abstract 1
- 239000003784 tall oil Substances 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- 239000002966 varnish Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/62—Coating or impregnation with organic materials
- C04B41/64—Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/495—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
- C04B41/4961—Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Paper (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Materials such as metals, textiles, leather, paper, bricks, tiles, asbestos and cellular cements, terra-cotta and earthenware articles, and tarred felt, are rendered water-repellent by applying, e.g. by brushing, a composition comprising an aqueous emulsion of an organopolysiloxane, a pigment and a thermoplastic resin, e.g. a polymer or copolymer of vinyl chloride or acetate, acrylic or methacrylic acid or an ester or nitrile thereof, styrene, butadiene, isoprene, chloroprene, isobutene, ethylene or propylene (see Group IV (a)). Pigments specified are oxides of Fe, Cr and Ti; chromates of Pb and Zn; sulphates of Ba and Ca; and powdered Al, Zn and bronze. The emulsion may also contain siloxane solvents, thickeners and emulsifying agents. Very porous materials are preferably pre-treated with an acrylic or other synthetic resin or varnish so that the majority of the pores become blocked. The compositions air-dry rapidly after application. Examples are given. Specification 806,226 is referred to.ALSO:A composition for rendering materials water-repellent (see Group VIII) comprises an aqueous emulsion of an organopolysiloxane, a pigment and a thermoplastic synthetic resin. The siloxanes specified may be liquids or resins containing alkyl, alkenyl, aryl or aralkyl radicals and may contain Si-bonded H atoms. Thermoplastic resins specified are the polymers and copolymers of vinyl chloride and acetate, acrylic and methacrylic acids and esters and nitriles thereof, styrene, butadiene, isoprene, chloroprene, isobutene, ethylene and propylene. The resins are preferably made by emulsion polymerization. Pigments specified are oxides of Fe, Cr and Ti; chromates of Pb and Zn; sulphides of Zn and Cd; sulphates of Ba and Ca; and powdered Al, Zn and bronze. The emulsions may contain solvents, e.g. toluene, xylene, white spirit and solvent naphtha, as well as water and emulsifying agents, e.g. stearic and oleic acids, sodium diethyl sulphosuccinate, the double titanate of triethanolamine and stearic acid, the condensate of tall oil with 10 mol. equivalents of ethylene oxide for each acid group present, a polyethyleneglycolalkylphenylether, octadecylamine acetate, morpholine, benzyltrimethylammonium chloride and cetyltrimethylammonium bromide. A thickener, e.g. carboxymethylcellulose, may also be present. The compositions when applied to the material to be treated dry rapidly in the air. Examples are given. Uses.-For rendering water repellent non-porous materials, e.g. metals, and porous materials, e.g. textiles, leather, paper, cardboard, bricks, tiles, asbestos and cellular cements, terra-cotta and earthenware articles and tarred felt. Specification 806,226 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE556493T | 1957-04-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB834962A true GB834962A (en) | 1960-05-18 |
Family
ID=3894441
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1035058A Expired GB834962A (en) | 1957-04-08 | 1958-04-01 | Processes and compositions for imparting water-repellency |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE556493A (en) |
| DE (2) | DE1235790B (en) |
| FR (1) | FR1205338A (en) |
| GB (1) | GB834962A (en) |
| NL (2) | NL102193C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4716188A (en) * | 1985-06-11 | 1987-12-29 | Oskar Mariusson | Water-repellent and vapor-permeable paint |
| EP0909747A1 (en) * | 1997-10-17 | 1999-04-21 | Erlus Baustoffwerke Ag | A method of applying self-cleaning surfaces |
| US7083828B2 (en) * | 2003-04-24 | 2006-08-01 | Goldschmidt Gmbh | Process for producing detachable dirt- and water-repellent surface coatings |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1805227C3 (en) * | 1968-10-25 | 1982-05-06 | Ruberoidwerke Ag, 2000 Hamburg | Process for the subsequent cladding of shell walls made of concrete, masonry or plastered walls with a predominantly panel-shaped covering made of plastic-soaked fabric or the like made of glass fibers |
| SE404358C (en) * | 1976-12-02 | 1984-10-15 | Dynamit Nobel Ag | PROCEDURE FOR HYDROPHOBOUS TREATMENT OF BUILDING MATERIAL, IN PARTICULAR POROSA SADANA |
| DE19529092A1 (en) * | 1995-08-08 | 1997-02-13 | Bayer Ag | New mixtures, a process for their preparation and their use for coatings |
| DE10104970A1 (en) * | 2001-02-03 | 2002-08-14 | Erwin Schmid | Agent for application to solids contains a viscous silicone preparation, useful for surface treatment of metal and wood, and textile and electrical component impregnation |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE543887A (en) * | 1955-12-23 |
-
0
- NL NL226287D patent/NL226287A/xx unknown
-
1957
- 1957-04-08 BE BE556493D patent/BE556493A/xx unknown
-
1958
- 1958-03-27 NL NL226287A patent/NL102193C/xx active
- 1958-04-01 GB GB1035058A patent/GB834962A/en not_active Expired
- 1958-04-04 FR FR1205338D patent/FR1205338A/en not_active Expired
- 1958-04-05 DE DE1958U0005262 patent/DE1235790B/en active Pending
- 1958-04-05 DE DE1958U0005262 patent/DE1246516B/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4716188A (en) * | 1985-06-11 | 1987-12-29 | Oskar Mariusson | Water-repellent and vapor-permeable paint |
| EP0909747A1 (en) * | 1997-10-17 | 1999-04-21 | Erlus Baustoffwerke Ag | A method of applying self-cleaning surfaces |
| DE19746053B4 (en) * | 1997-10-17 | 2006-11-16 | Erlus Aktiengesellschaft | Process for producing a self-cleaning property of surfaces, in particular roofing tiles, and ceramic bodies with a self-cleaning surface |
| US7083828B2 (en) * | 2003-04-24 | 2006-08-01 | Goldschmidt Gmbh | Process for producing detachable dirt- and water-repellent surface coatings |
Also Published As
| Publication number | Publication date |
|---|---|
| BE556493A (en) | 1957-04-30 |
| DE1235790B (en) | 1967-03-02 |
| FR1205338A (en) | 1960-02-02 |
| NL226287A (en) | |
| NL102193C (en) | 1962-08-15 |
| DE1246516B (en) | 1967-08-03 |
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