GB824897A - New copolymers of vinyl chloride - Google Patents

New copolymers of vinyl chloride

Info

Publication number
GB824897A
GB824897A GB3816/58A GB381658A GB824897A GB 824897 A GB824897 A GB 824897A GB 3816/58 A GB3816/58 A GB 3816/58A GB 381658 A GB381658 A GB 381658A GB 824897 A GB824897 A GB 824897A
Authority
GB
United Kingdom
Prior art keywords
vinyl
tin
vinyl chloride
organo
tin compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3816/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc SA
Original Assignee
Rhone Poulenc SA
Societe des Usines Chimiques Rhone Poulenc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc SA, Societe des Usines Chimiques Rhone Poulenc SA filed Critical Rhone Poulenc SA
Publication of GB824897A publication Critical patent/GB824897A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02Monomers containing chlorine
    • C08F214/04Monomers containing two carbon atoms
    • C08F214/06Vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/56Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • C08K5/57Organo-tin compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

New copolymers have vinyl chloride as the major component and, as a minor component (e.g. 0.1-5%), an organo-tin compound having a vinyl group attached directly to the tin atom. Another organo-vinyl component, e.g. vinyl acetate, may be present in a smaller proportion than the vinyl chloride. The organo-tin compound may contain besides the vinyl group hydrocarbon radicals other than vinyl, e.g. ethyl or butyl, and/or acyloxy radicals directly attached to the tin atom. The products are stable to light and heat, even with a low proportion of the tin compound. Copolymerization is preferably effected in emulsion in water containing a suitable dispersing agent, e.g. partly saponified polyvinyl acetate, and a catalyst, e.g. lauryl peroxide. Plasticization of a copolymer of monovinyl diethyl tin laurate with vinyl chloride, followed by hot calendering, gives substantially colourless sheets. Fractional precipitation of the copolymer followed by an estimation of the tin content of the various fractions shows uniform copolymerization.
GB3816/58A 1957-02-12 1958-02-05 New copolymers of vinyl chloride Expired GB824897A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1079837X 1957-02-12

Publications (1)

Publication Number Publication Date
GB824897A true GB824897A (en) 1959-12-09

Family

ID=9609350

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3816/58A Expired GB824897A (en) 1957-02-12 1958-02-05 New copolymers of vinyl chloride

Country Status (4)

Country Link
BE (1) BE564652A (en)
DE (1) DE1079837B (en)
FR (1) FR1166281A (en)
GB (1) GB824897A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE596011A (en) * 1959-10-16 1900-01-01

Also Published As

Publication number Publication date
BE564652A (en)
DE1079837B (en) 1960-04-14
FR1166281A (en) 1958-11-04

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