GB824897A - New copolymers of vinyl chloride - Google Patents
New copolymers of vinyl chlorideInfo
- Publication number
- GB824897A GB824897A GB3816/58A GB381658A GB824897A GB 824897 A GB824897 A GB 824897A GB 3816/58 A GB3816/58 A GB 3816/58A GB 381658 A GB381658 A GB 381658A GB 824897 A GB824897 A GB 824897A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- tin
- vinyl chloride
- organo
- tin compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
New copolymers have vinyl chloride as the major component and, as a minor component (e.g. 0.1-5%), an organo-tin compound having a vinyl group attached directly to the tin atom. Another organo-vinyl component, e.g. vinyl acetate, may be present in a smaller proportion than the vinyl chloride. The organo-tin compound may contain besides the vinyl group hydrocarbon radicals other than vinyl, e.g. ethyl or butyl, and/or acyloxy radicals directly attached to the tin atom. The products are stable to light and heat, even with a low proportion of the tin compound. Copolymerization is preferably effected in emulsion in water containing a suitable dispersing agent, e.g. partly saponified polyvinyl acetate, and a catalyst, e.g. lauryl peroxide. Plasticization of a copolymer of monovinyl diethyl tin laurate with vinyl chloride, followed by hot calendering, gives substantially colourless sheets. Fractional precipitation of the copolymer followed by an estimation of the tin content of the various fractions shows uniform copolymerization.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1079837X | 1957-02-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB824897A true GB824897A (en) | 1959-12-09 |
Family
ID=9609350
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3816/58A Expired GB824897A (en) | 1957-02-12 | 1958-02-05 | New copolymers of vinyl chloride |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE564652A (en) |
DE (1) | DE1079837B (en) |
FR (1) | FR1166281A (en) |
GB (1) | GB824897A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE596011A (en) * | 1959-10-16 | 1900-01-01 |
-
0
- BE BE564652D patent/BE564652A/xx unknown
-
1957
- 1957-02-12 FR FR1166281D patent/FR1166281A/en not_active Expired
-
1958
- 1958-01-17 DE DES56621A patent/DE1079837B/en active Pending
- 1958-02-05 GB GB3816/58A patent/GB824897A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
BE564652A (en) | |
DE1079837B (en) | 1960-04-14 |
FR1166281A (en) | 1958-11-04 |
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