GB820486A - Rubbery polymer-antioxidant compositions - Google Patents

Rubbery polymer-antioxidant compositions

Info

Publication number
GB820486A
GB820486A GB25982/55A GB2598255A GB820486A GB 820486 A GB820486 A GB 820486A GB 25982/55 A GB25982/55 A GB 25982/55A GB 2598255 A GB2598255 A GB 2598255A GB 820486 A GB820486 A GB 820486A
Authority
GB
United Kingdom
Prior art keywords
radical
tertiary butyl
alphaphenylethyl
phenols
tertiary
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB25982/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Goodyear Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co
Publication of GB820486A publication Critical patent/GB820486A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Rubbery polymers contain 0.5 to 5.0% by weight of a phenolic antioxidant of formula: <FORM:0820486/IV (a)/1> in which each R is a tertiary butyl, alphaphenylethyl or alpha-tolylethyl radical, there being at least one tertiary butyl radical and at least one aralkyl radical present and there being at least one tertiary butyl radical ortho to the hydroxyl group (see Group IV (b)). The rubbery polymers are natural rubber, polychloroprene, copolymers of isobutylene with butadiene or isoprene, copolymers of butadiene with styrene or acrylonitrile.ALSO:Tri-substituted phenols of formula <FORM:0820486/IV (a)/1> in which each R is a tertiary butyl radical or an alphaphenylethyl or alphatolylethyl radical, there being at least one tertiary butyl radical and at least one aralkyl radical present and there being at least one tertiary butyl radical ortho to the hydroxyl group, are used as anti-oxidants in rubber compositions (see Group IV (a)). The preparation of di-tertiary-butyl-alphaphenylethyl-phenols and ditertiary-butylalphatolyethyl-phenols is specified.
GB25982/55A 1955-03-02 1955-09-12 Rubbery polymer-antioxidant compositions Expired GB820486A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US820486XA 1955-03-02 1955-03-02

Publications (1)

Publication Number Publication Date
GB820486A true GB820486A (en) 1959-09-23

Family

ID=22168710

Family Applications (1)

Application Number Title Priority Date Filing Date
GB25982/55A Expired GB820486A (en) 1955-03-02 1955-09-12 Rubbery polymer-antioxidant compositions

Country Status (3)

Country Link
BE (1) BE545693A (en)
GB (1) GB820486A (en)
LU (1) LU33823A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3989665A (en) * 1975-01-20 1976-11-02 The Goodyear Tire & Rubber Company Butylated, α-methyl styrenated phenolic antioxidants for polymers

Also Published As

Publication number Publication date
BE545693A (en)
LU33823A1 (en)

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