GB816609A - Improvements relating to the recovery of vanadium from slag - Google Patents
Improvements relating to the recovery of vanadium from slagInfo
- Publication number
- GB816609A GB816609A GB1340056A GB1340056A GB816609A GB 816609 A GB816609 A GB 816609A GB 1340056 A GB1340056 A GB 1340056A GB 1340056 A GB1340056 A GB 1340056A GB 816609 A GB816609 A GB 816609A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chlorides
- chloride
- iron
- ferric
- vanadium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002893 slag Substances 0.000 title abstract 5
- 229910052720 vanadium Inorganic materials 0.000 title abstract 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium(0) Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title abstract 3
- 238000011084 recovery Methods 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 7
- 238000001035 drying Methods 0.000 abstract 5
- 239000007789 gas Substances 0.000 abstract 5
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 5
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 5
- 229910052742 iron Inorganic materials 0.000 abstract 5
- 238000001704 evaporation Methods 0.000 abstract 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N Iron(III) oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 3
- 238000004821 distillation Methods 0.000 abstract 3
- 229910000460 iron oxide Inorganic materials 0.000 abstract 3
- NMCUIPGRVMDVDB-UHFFFAOYSA-L Iron(II) chloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 abstract 2
- RBTARNINKXHZNM-UHFFFAOYSA-K Iron(III) chloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 2
- 238000007792 addition Methods 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical class [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract 2
- 235000011148 calcium chloride Nutrition 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 2
- 150000001805 chlorine compounds Chemical class 0.000 abstract 2
- 238000002425 crystallisation Methods 0.000 abstract 2
- 230000005712 crystallization Effects 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 238000006460 hydrolysis reaction Methods 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 239000011572 manganese Substances 0.000 abstract 2
- 235000002867 manganese chloride Nutrition 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 238000005201 scrubbing Methods 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- RCJVRSBWZCNNQT-UHFFFAOYSA-N Dichlorine monoxide Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J Titanium tetrachloride Chemical class Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
- JBIQAPKSNFTACH-UHFFFAOYSA-K Vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 abstract 1
- HQYCOEXWFMFWLR-UHFFFAOYSA-K Vanadium(III) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 abstract 1
- RPESBQCJGHJMTK-UHFFFAOYSA-I [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] Chemical class [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 235000012255 calcium oxide Nutrition 0.000 abstract 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium;oxygen(2-) Chemical class [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000567 combustion gas Substances 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 1
- 229960002089 ferrous chloride Drugs 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000005755 formation reaction Methods 0.000 abstract 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000012452 mother liquor Substances 0.000 abstract 1
- 230000001590 oxidative Effects 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/04—Working-up slag
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/22—Obtaining vanadium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
Vanadium is recovered from slag produced in the manufacture of iron and steel by dissolving the slag in aqueous hydrochloric acid, evaporating the resultant chloride solution to dryness and distilling the dried residue in the presence of hydrogen chloride gas at up to 400 DEG C. The slag may be fed with hot 30 per cent HCl to a rotary kiln maintained at 95 DEG C. to form the chloride solution. Scrap iron or shot may, if desired, be present to prevent formation of ferric chloride rather than ferrous chloride. This solution which may contain silica in suspension and chlorides of iron, manganese, vanadium, aluminium, titanium, calcium and magnesium, may then be filtered, and evaporated in one or more steps, e.g. by partial evaporation in a steam-heated evaporator followed by spraying into hot combustion gases or a bed of hot fluidized solids, or by partial evaporation by submerged combustion followed by crystallization, filtration, the return of the mother liquor to the crystallization tank and drying of the crystals, e.g. in a steam-heated rotary drier. Drying may be carried out in the presence of hydrogen chloride gas as in Specification 734,081, to avoid hydrolysis, especially of iron chlorides. Aluminium and titanium chlorides are easily hydrolysed to oxide during the drying. The dried residue may then be crushed and fluidized in a stream of preheated hydrogen chloride to distil off the ferric and vanadium chlorides (the latter may be distilled as vanadyl chloride). The mixed gases may be separated as described in Specification 737,889. In one case, the chlorides were condensed, and after acid scrubbing of the gases leaving the condenser to recover remaining vanadium chloride, the condensate and scrubbing liquor were evaporated and roasted to recover vandium pentoxide. The residual ferrous, manganous and calcium chlorides may be hydrolysed as a fluidized bed in steam in two stages, the first at 350-400 DEG C. to yield ferric oxide, the second at 500-550 DEG C. with the addition of siliceous material, if desired, to yield manganese and calcium oxides, the manganese and calcium chlorides being water-leached from the ferric oxide and the so-formed solution dried between the two stages. The Provisional Specification is not restricted to the treatment of slags, or to final distillation but refers also to treating materials which will not respond to gaseous chloridizing below 400 DEG C. and in particular to treating ilmenite to obtain ferric chloride and leave (after the above described distillation or after leaching the dried residue with water) a residue of titanium dioxide formed as a result of hydrolysis during evaporation and drying. If so desired, the iron may be oxidized during drying to the ferric state by addition of an oxidizing component to the heating gases or heating may be continued to form ferric oxide or during distillation air or oxygen may be added to the hydrogen chloride employed. It is stated that the iron may be present in the dried residue as the oxychloride. Specification 701,797 also is referred to in the Provisional Specification.
Publications (1)
Publication Number | Publication Date |
---|---|
GB816609A true GB816609A (en) | 1959-07-15 |
Family
ID=1727398
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1340056A Expired GB816609A (en) | 1956-05-01 | Improvements relating to the recovery of vanadium from slag |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB816609A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2150549A (en) * | 1983-12-01 | 1985-07-03 | Pavel Hurt | Process for the separate recovery of metal chlorides from complex ores etc |
FR2691979A1 (en) * | 1992-06-05 | 1993-12-10 | Emc Services | Detoxification process of combustion residues by extraction of mobile toxic compounds and fixation - concentration of these same compounds from treatment solutions. |
CN110358909A (en) * | 2019-07-18 | 2019-10-22 | 北京科技大学 | A kind of green high-efficient utilizes the method for carbon and preenrichment vanadium in high-carbon type Rock coal containing alum |
CN112458298A (en) * | 2020-10-27 | 2021-03-09 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for extracting vanadium by direct sodium treatment of thermal vanadium slag |
CN113088687A (en) * | 2021-04-15 | 2021-07-09 | 攀钢集团攀枝花钢铁研究院有限公司 | Horizontal agitating unit suitable for vanadium slag leaches in succession |
CN113234935A (en) * | 2021-05-10 | 2021-08-10 | 北京科技大学 | Method for co-extracting vanadium, titanium and chromium from vanadium slag |
-
1956
- 1956-05-01 GB GB1340056A patent/GB816609A/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2150549A (en) * | 1983-12-01 | 1985-07-03 | Pavel Hurt | Process for the separate recovery of metal chlorides from complex ores etc |
FR2691979A1 (en) * | 1992-06-05 | 1993-12-10 | Emc Services | Detoxification process of combustion residues by extraction of mobile toxic compounds and fixation - concentration of these same compounds from treatment solutions. |
WO1993025716A1 (en) * | 1992-06-05 | 1993-12-23 | Emc Services | Method for detoxication of combustion residues by removing the movable toxic compounds and by binding and concentrating said compounds obtained from treatment solutions |
CN110358909A (en) * | 2019-07-18 | 2019-10-22 | 北京科技大学 | A kind of green high-efficient utilizes the method for carbon and preenrichment vanadium in high-carbon type Rock coal containing alum |
CN110358909B (en) * | 2019-07-18 | 2020-06-05 | 北京科技大学 | Method for green and efficient utilization of carbon in high-carbon vanadium-containing stone coal and pre-enrichment of vanadium |
CN112458298A (en) * | 2020-10-27 | 2021-03-09 | 攀钢集团攀枝花钢铁研究院有限公司 | Method for extracting vanadium by direct sodium treatment of thermal vanadium slag |
CN113088687A (en) * | 2021-04-15 | 2021-07-09 | 攀钢集团攀枝花钢铁研究院有限公司 | Horizontal agitating unit suitable for vanadium slag leaches in succession |
CN113088687B (en) * | 2021-04-15 | 2022-05-27 | 攀钢集团攀枝花钢铁研究院有限公司 | Horizontal agitating unit suitable for vanadium slag leaches in succession |
CN113234935A (en) * | 2021-05-10 | 2021-08-10 | 北京科技大学 | Method for co-extracting vanadium, titanium and chromium from vanadium slag |
CN113234935B (en) * | 2021-05-10 | 2022-04-01 | 北京科技大学 | Method for co-extracting vanadium, titanium and chromium from vanadium slag |
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