GB808639A - Improvements in and relating to the oxidation of sulphur dioxide to sulphur trioxide and catalysts therefor - Google Patents

Improvements in and relating to the oxidation of sulphur dioxide to sulphur trioxide and catalysts therefor

Info

Publication number
GB808639A
GB808639A GB2468156A GB2468156A GB808639A GB 808639 A GB808639 A GB 808639A GB 2468156 A GB2468156 A GB 2468156A GB 2468156 A GB2468156 A GB 2468156A GB 808639 A GB808639 A GB 808639A
Authority
GB
United Kingdom
Prior art keywords
sodium
catalyst
silica
per cent
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2468156A
Inventor
Phineas Davies
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2468156A priority Critical patent/GB808639A/en
Priority to BE560004D priority patent/BE560004A/xx
Priority to FR1181164D priority patent/FR1181164A/en
Publication of GB808639A publication Critical patent/GB808639A/en
Priority to DEI17377A priority patent/DE1160410B/en
Priority to US350114A priority patent/US3186794A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/69Sulfur trioxide; Sulfuric acid
    • C01B17/74Preparation
    • C01B17/76Preparation by contact processes
    • C01B17/78Preparation by contact processes characterised by the catalyst used
    • C01B17/79Preparation by contact processes characterised by the catalyst used containing vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20Vanadium, niobium or tantalum
    • B01J23/22Vanadium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

A catalyst for the oxidation of sulphur dioxide to trioxide is prepared by impregnating a freshly-prepared silica gel containing sodium and/or potassium ions with freshly-precipitated vanadium pentoxide containing sodium and/or potassium ions, drying, treating with sulphuric acid and calcining, the amounts and compositions of the reactants being chosen to give a product containing 6-9 per cent vanadium pentoxide, 6-10 per cent potassium oxide and 1.5-6 per cent sodium oxide. Calcium or barium ions may also be introduced by washing the silica gel, before impregnation, with lime or baryta water. Freshly prepared silica is defined as silica gel which has not been allowed to dry out, i.e. it is used immediately after precipitation or is stored in an unfiltered state under conditions such that there is no loss of water. Additional quantities of silica, e.g. kieselguhr, up to 10 per cent of the total weight, may be introduced into the catalyst by mixing in after the impregnation step. The silica gel preferably contains sodium ions and is precipitated from sodium silicate solutions by addition of ammonium or aluminium sulphate, ammonium, sodium or magnesium acetate, ammonium bicarbonate, sodium carbonate, ammonium, sodium or calcium chloride, an alkali such as ammonia or an acid such as sulphuric (to a pH not less than 8). The gel is then washed to give the desired sodium content. The vanadium pentoxide preferably contains potassium ions and is prepared by dissolving vanadic acid in aqueous caustic potash or caustic potash and soda and sulphuric acid is added to give a red precipitate which is slurried with the silica and dried by removing supernatant water by evaporation and then heating the paste to 100-120 DEG C. The product is treated with aqueous sulphuric acid, preferably containing 10 per cent by weight of acid, in an amount sufficient to wet the catalyst, e.g. 1 litre per kilogram of catalyst. The mixture is redried and calcined at 300-400 DEG C. and may then be pelleted; alternatively if it is to be used in the fluidized state it may be introduced into the reactor prior to calcination and calcined in situ. The catalyst may be further activated by treatment with air at 550 DEG C. for 6-12 hours and stabilized by treatment with a reaction mixture at 650 DEG C. for one or more periods of 18-24 hours. The advantage of the catalyst over previous catalysts is particularly noticeable at 380-460 DEG C. as is illustrated by the examples. The Provisional Specification (24681/56) also refers to catalysts containing silica and compounds of vanadium, potassium and another alkali metal which need not be treated with sulphuric acid. This subject-matter does not appear in the Complete Specification.
GB2468156A 1956-08-13 1956-08-13 Improvements in and relating to the oxidation of sulphur dioxide to sulphur trioxide and catalysts therefor Expired GB808639A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB2468156A GB808639A (en) 1956-08-13 1956-08-13 Improvements in and relating to the oxidation of sulphur dioxide to sulphur trioxide and catalysts therefor
BE560004D BE560004A (en) 1956-08-13 1957-08-12
FR1181164D FR1181164A (en) 1956-08-13 1957-08-13 Improvements in the oxidation of sulfur dioxide to sulfur dioxide, and catalysts used for this purpose
DEI17377A DE1160410B (en) 1956-08-13 1959-12-16 Process for the production of catalysts containing vanadium, silica, sodium and potassium for the catalytic oxidation of sulfur dioxide to sulfur trioxide
US350114A US3186794A (en) 1956-08-13 1964-03-06 Oxidation of sulphur dioxide to sulphur trioxide and catalysts therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2468156A GB808639A (en) 1956-08-13 1956-08-13 Improvements in and relating to the oxidation of sulphur dioxide to sulphur trioxide and catalysts therefor

Publications (1)

Publication Number Publication Date
GB808639A true GB808639A (en) 1959-02-11

Family

ID=10215600

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2468156A Expired GB808639A (en) 1956-08-13 1956-08-13 Improvements in and relating to the oxidation of sulphur dioxide to sulphur trioxide and catalysts therefor

Country Status (1)

Country Link
GB (1) GB808639A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0020963A2 (en) * 1979-05-31 1981-01-07 BASF Aktiengesellschaft Process and catalysts for oxidizing sulphur dioxide
US4766104A (en) * 1984-01-19 1988-08-23 Metallgesellschaft Aktiengesellschaft Process for producing a V2 O5 -and-alkali-metal-sulfate-containing catalyst for oxidizing SO2 to SO3

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0020963A2 (en) * 1979-05-31 1981-01-07 BASF Aktiengesellschaft Process and catalysts for oxidizing sulphur dioxide
EP0020963A3 (en) * 1979-05-31 1981-09-02 BASF Aktiengesellschaft Process and catalysts for oxidizing sulphur dioxide
US4766104A (en) * 1984-01-19 1988-08-23 Metallgesellschaft Aktiengesellschaft Process for producing a V2 O5 -and-alkali-metal-sulfate-containing catalyst for oxidizing SO2 to SO3

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