GB804669A - Improvements in leather-like sheet material and preparation thereof - Google Patents

Improvements in leather-like sheet material and preparation thereof

Info

Publication number
GB804669A
GB804669A GB36038/55A GB3603855A GB804669A GB 804669 A GB804669 A GB 804669A GB 36038/55 A GB36038/55 A GB 36038/55A GB 3603855 A GB3603855 A GB 3603855A GB 804669 A GB804669 A GB 804669A
Authority
GB
United Kingdom
Prior art keywords
ethylene
polyesterurethane
polyester
specified
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB36038/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodrich Corp
Original Assignee
BF Goodrich Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BF Goodrich Corp filed Critical BF Goodrich Corp
Publication of GB804669A publication Critical patent/GB804669A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39Aldehyde resins; Ketone resins; Polyacetals
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them

Abstract

Polyesterurethanes for impregnating non-woven fabric to produce a leather-like material are made by reacting 1.2 to 2.0 mols. of organic diisocyanate with 1.0 mol. of a polyester comprising a glycol reacted with an aliphatic dicarboxylic acid, the said polyester having a molecular weight from 500 to 10,000. Specified organic di-isocyanates are hexamethylene, 1,5-naphthylene, di-phenyl methane-p,p1, triphenyl methane-p,p1, metatolylene, phenylene and benzidene diisocyanates. Specified glycols are ethylene, propylene, di-ethylene, tetramethylene, pentamethylene and octamethylene glycols. Specified aliphatic dicarboxylic acids are adipic, succinic, maleic, fumaric, methyl succinic, di-, tri- and tetra-methyl succinic, pimelic, glutaric, suberic, azelaic and sebacic acids. Bifunctional amine-containing reactants may also be included in the polyester-forming mixture, e.g. ethanolamine, aminobutanol, ethylene diamine or tetramethylene diamine. The impregnating solution comprises the polyesterurethane dissolved in a solvent, e.g. benzene, toluene, chlorobenzene, isopropyl acetate, methyl ethyl ketone, acetone, methyl isobutyl ketone, nitromethane or cyclohexanone and a colorant, e.g. a mixture of yellow iron oxide, red iron oxide and channel black may be added. Examples, describe the preparation of polyesterurethane by reacting hydroxyl poly (ethylene adipate) with paraphenylene di-isocyanate. Curing of the polyesterurethane may be accelerated by triethylamine or pyridine.
GB36038/55A 1954-12-29 1955-12-15 Improvements in leather-like sheet material and preparation thereof Expired GB804669A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US804669XA 1954-12-29 1954-12-29

Publications (1)

Publication Number Publication Date
GB804669A true GB804669A (en) 1958-11-19

Family

ID=22157558

Family Applications (1)

Application Number Title Priority Date Filing Date
GB36038/55A Expired GB804669A (en) 1954-12-29 1955-12-15 Improvements in leather-like sheet material and preparation thereof

Country Status (3)

Country Link
DE (1) DE1098909B (en)
FR (1) FR1145244A (en)
GB (1) GB804669A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3790437A (en) * 1972-04-20 1974-02-05 Dayco Corp Polyvinyl alcohol fiber reinforced polyurethane compositions and products therefrom
US3830685A (en) * 1970-09-10 1974-08-20 Dayco Corp Polyurethanes reinforced by polyvinyl alcohol cord

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB884604A (en) * 1958-05-13 1961-12-13 Balatum N V A process for the manufacture of a material resembling leather
NL132877C (en) * 1958-07-03 1900-01-01

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE894234C (en) * 1943-02-11 1953-10-22 Lissmann Alkor Werk Process for the production of fabrics with a leather-like texture
DE880585C (en) * 1944-12-10 1953-06-22 Lissmann Alkor Werk Process for the production of material, in particular leather replacement material
CH280195A (en) * 1947-06-10 1952-01-15 Svit Np Process for the production of artificial leather.

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3830685A (en) * 1970-09-10 1974-08-20 Dayco Corp Polyurethanes reinforced by polyvinyl alcohol cord
US3790437A (en) * 1972-04-20 1974-02-05 Dayco Corp Polyvinyl alcohol fiber reinforced polyurethane compositions and products therefrom

Also Published As

Publication number Publication date
DE1098909B (en) 1961-02-09
FR1145244A (en) 1957-10-23

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