GB804069A - Improvements in or relating to polymeric compounds and products containing the same - Google Patents

Improvements in or relating to polymeric compounds and products containing the same

Info

Publication number
GB804069A
GB804069A GB31379/56A GB3137956A GB804069A GB 804069 A GB804069 A GB 804069A GB 31379/56 A GB31379/56 A GB 31379/56A GB 3137956 A GB3137956 A GB 3137956A GB 804069 A GB804069 A GB 804069A
Authority
GB
United Kingdom
Prior art keywords
monomers
azobis
group
copolymers
specified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31379/56A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB804069A publication Critical patent/GB804069A/en
Expired legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/85—Photosensitive materials characterised by the base or auxiliary layers characterised by antistatic additives or coatings
    • G03C1/89—Macromolecular substances therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/08—Homopolymers or copolymers of vinylidene chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/825—Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
    • G03C1/835—Macromolecular substances therefor, e.g. mordants

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Textile Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Water-soluble copolymers are made by copolymerizing in an inert solvent and in the presence of a polymerization initiator a mixture of monomers comprising a quaternary ammonium salt of an amino-alcohol ester of acrylic acid or an alpha-hydrocarbon substituted acrylic acid, wherein the amine nitrogen is tertiary, an ethylenically unsaturated aliphatic ether or ester containing an epoxide group and 0 to 40 per cent of a different polymerizable ethylenically unsaturated monomer, the temperature of polymerization being below that at which the epoxy group is reactive. The preferred quaternary ammonium monomer is beta-methacryloxyethylmethyldiethylammonium methyl sulphate; other monomers of this type are specified in U.S.A. Specification 2,677,699. Epoxide monomers specified are glycidyl acrylate, methacrylate and chloroacrylate and other monomers specified in U.S.A. Specifications 2,556,075 and 2,567,842. Other monomers which may be used to form three-component copolymers are vinyl and vinylidene chlorides, vinyl acetate, acrylonitrile and methyl and ethyl acrylates and methacrylates. Polymerization initiators specified are hydrogen peroxide, sodium peroxide, benzoyl, acetyl and ditert.-butyl peroxides, cumene and tert.-butyl hydroperoxides, sodium perborate and persulphate, ammonium persulphate-sodium bisulphite, hydrogen peroxide-thiourea, potassium persulphate-ferrous sulphate, azobis (isobutyronitrile), azobis (dimethylvaleronitrile), azobis (trimethylvaleronitrile), azobis (methylbutyronitrile) and azobis (isobutyramidine hydrochloride). Polymerization solvents specified are methanol t-butyl alcohol, acetone, methyl ethyl ketone and water/alcohol mixtures, which last should be used at a pH of about 7. The copolymers may be applied to films, fibres and fabrics and then cross-linked by heating to temperatures in excess of 100 DEG C. Specifications 475,131, 578,079, [both in Group IV], 648,959 and 718,422 also are referred to.ALSO:Fibres made from polyethylene terephthalate, polyacrylonitrile or polyamides are given an antistatic coating by applying thereto, from aqueous solution, a layer of a copolymer of a mixture of monomers comprising a quaternary ammonium salt of an amino alcohol ester of acrylic acid or an alpha-hydrocarbon substituted acrylic acid, wherein the amino nitrogen is tertiary, an ethylenically unsaturated ether or ester containing an epoxide group and 0-40 per cent of a different polymerizable ethylenically unsaturated monomer. Representative copolymers are beta-methacryloxyethylmethyldiethylammonium methyl sulphate/glycidyl methacrylate with vinylidene chloride as an optional constituent. Other monomeric constituents include glycidyl acrylate, glycidyl chloroacrylate, vinyl chloride, vinyl acetate, acrylonitrile, and methyl and ethyl acrylates and methacrylates. After application the copolymer layer may be cross-linked by heating to a temperature above 100 DEG C. The abovementioned copolymers may also be used as mordants for acid dyes. Specifications 475,131, 578,079, [both in Group IV], 648,959 and 718,422, [both in Group IV (a)], are referred to.
GB31379/56A 1955-11-09 1956-10-15 Improvements in or relating to polymeric compounds and products containing the same Expired GB804069A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US361401XA 1955-11-09 1955-11-09

Publications (1)

Publication Number Publication Date
GB804069A true GB804069A (en) 1958-11-05

Family

ID=21886869

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31379/56A Expired GB804069A (en) 1955-11-09 1956-10-15 Improvements in or relating to polymeric compounds and products containing the same

Country Status (6)

Country Link
BE (1) BE552231A (en)
CH (1) CH361401A (en)
DE (1) DE1097685B (en)
FR (1) FR1162763A (en)
GB (1) GB804069A (en)
NL (2) NL96978C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3339659A (en) * 1965-11-22 1967-09-05 Walter A Wolf Powered friction-driving device for vehicles

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE24164E (en) * 1951-03-21 1956-06-12 Quaternary ammonium polymers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3339659A (en) * 1965-11-22 1967-09-05 Walter A Wolf Powered friction-driving device for vehicles

Also Published As

Publication number Publication date
FR1162763A (en) 1958-09-17
DE1097685B (en) 1961-01-19
NL96978C (en)
BE552231A (en)
NL211934A (en)
CH361401A (en) 1962-04-15

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