GB802731A - Improvements in or relating to ª‡-aluminium oxide - Google Patents
Improvements in or relating to ª‡-aluminium oxideInfo
- Publication number
- GB802731A GB802731A GB29295/54A GB2929554A GB802731A GB 802731 A GB802731 A GB 802731A GB 29295/54 A GB29295/54 A GB 29295/54A GB 2929554 A GB2929554 A GB 2929554A GB 802731 A GB802731 A GB 802731A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- heated
- alkali metal
- weight
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/02—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances
- H01B3/10—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances metallic oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/46—Purification of aluminium oxide, aluminium hydroxide or aluminates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/02—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances
- H01B3/025—Other inorganic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
- H01J1/02—Main electrodes
- H01J1/13—Solid thermionic cathodes
- H01J1/20—Cathodes heated indirectly by an electric current; Cathodes heated by electron or ion bombardment
- H01J1/22—Heaters
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
Abstract
An electrically non-conducting a -alumina powder contains at least one of the following components in the specified proportion by weight of the aluminium: 0.05-0.5 per cent silica, 0.01-0.1 per cent alkali metal oxide, 0.1-5 per cent calcium oxide, 0.1-5 per cent glass or other silicate containing less than 0.01 per cent of alkali metal. Where alkali metal oxide is present, at least 5 parts by weight of silica must also be present per part by weight of alkali metal. In a first embodiment, an alumina powder containing 0.3 to 0.8 per cent of sodium oxide and 0.05-0.5 per cent of silica, which has been calcined at about 1100 DEG C., is heated at a temperature between 1300 DEG and 1700 DEG C. until a substantial part of the sodium content of the powder is vaporized, and the product is washed with hot hydrochloric acid and hot water until its sodium oxide content is further reduced to 0.01 to 0.1 per cent by weight. The resultant powder may be ground together with 0.2 to 1 per cent of alkali free hard glass powder in dilute hydrochloric acid and then washed with hot hydrochloric acid and hot water and suction filtered or may be contacted with an aqueous solution of aluminium sulphate, chloride or nitrate or with sodium chloride and the product dried at 150 DEG to 650 DEG C. for subsequent use in coating electrical elements. In Example 1 alumina is heated at 1450 DEG C. and milled in the presence of aqueous hydrochloric acid with powdered hard glass; the mass is heated with nitric acid, filtered, washed with hot hydrochloric acid and hot water, dried, stirred with aluminium sulphate solution, filtered, dried and heated at 600 DEG C. Finally the powder is shaken with acetone and amyl alcohol, filtered, dried and screened for use in the coating of electrical elements by electrophoresis followed by firing in hydrogen at 1600 DEG C. In a second embodiment, aluminium hydroxide is precipitated from a solution of silica-free aluminium salt, mixed with sufficient calcium nitrate to provide a content of 0.1 to 0.5 per cent of calcium oxide in the finished product and then heated at 1300 DEG to 1600 DEG C. Example 2 describes a process in which aluminium hydroxide is precipitated from a solution of aluminium chloride with ammonia, the mixture boiled and filtered and the precipitate washed with aqueous ammonium nitrate made alkaline with ammonia. The precipitate is heated at 1000 DEG C., the product mixed with calcium nitrate solution and the mixture dried and then heated at 1500 DEG C. The cake thus formed is milled in the presence of water and extracted with hot hydrochloric acid and hot water; a solution of sodium chloride is added to the air-dry powder and the mixture dried, heated at 500 DEG C., ground and screened for use in the formation of coatings on electrical elements as in the first example. It is stated that where materials are prepared from alumina with ground glass, beryllium or magnesium oxides may also be added to counteract the effect of any sodium present. In addition to coating by electrophoresis (see Group XXXVI) an electrical element, e.g. a tungsten spiral, may be coated with or dipped into a suspension of the alumina in a binding agent, e.g. an amyl-acetate-acetone mixture containing collodion or methanol containing collodion. The electrical element is subsequently fired to form the final coating. The alumina may also be used for coating refractory articles such as ceramic crucibles and combustion boats.ALSO:A refractory body or coating for refractory articles such as combustion boats or ceramic crucibles may be prepared from a -alumina powder containing at least one of the following components in the specified proportion by weight of the aluminium: 0,05-0,5 per cent silica, 0,01-0,1 per cent alkali metal oxide, 0,1-5 per cent calcium oxide, 0,1-5 per cent glass or other silicate containing less than 0,01 per cent of alkali metal; where alkali metal oxide is present at least 5 parts by p weight of silica must also be present per part by weight of alkali metal oxide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HU802731X | 1953-10-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB802731A true GB802731A (en) | 1958-10-08 |
Family
ID=10980377
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB29295/54A Expired GB802731A (en) | 1953-10-10 | 1954-10-11 | Improvements in or relating to ª‡-aluminium oxide |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1071566B (en) |
FR (1) | FR1115587A (en) |
GB (1) | GB802731A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4822592A (en) * | 1987-02-05 | 1989-04-18 | Aluminum Company Of America | Producing alpha alumina particles with pressurized acidic steam |
EP0624550A1 (en) * | 1993-05-11 | 1994-11-17 | Exxon Research And Engineering Company | Heat transfer solids for high temperature fluidized bed reactions |
GB2306873A (en) * | 1995-10-26 | 1997-05-07 | Strix Ltd | Insulating heater substrate by electrostatic deposition |
EP0924738A1 (en) * | 1997-12-19 | 1999-06-23 | Matsushita Electronics Corporation | Methods of manufacturing heater and cathode-ray tube comprising the same |
US6242854B1 (en) | 1998-01-20 | 2001-06-05 | Matsushita Electronics Corporation | Indirectly heated cathode for a CRT having high purity alumina insulating layer with limited amounts of Na OR Si |
EP2119672A1 (en) * | 2006-12-15 | 2009-11-18 | Nippon Light Metal Company, Ltd. | Process for producing high-purity -alumina |
US20150368117A1 (en) * | 2012-12-17 | 2015-12-24 | Polar Sapphire Ltd. | Process for making high purity aluminum oxide |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD202311A5 (en) * | 1980-10-09 | 1983-09-07 | Vasipari Kutato Intezet | POWDER METALLURGICAL MATERIAL AND TOOL PRODUCED THEREFROM |
-
0
- DE DENDAT1071566D patent/DE1071566B/de active Pending
-
1954
- 1954-10-09 FR FR1115587D patent/FR1115587A/en not_active Expired
- 1954-10-11 GB GB29295/54A patent/GB802731A/en not_active Expired
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4822592A (en) * | 1987-02-05 | 1989-04-18 | Aluminum Company Of America | Producing alpha alumina particles with pressurized acidic steam |
EP0624550A1 (en) * | 1993-05-11 | 1994-11-17 | Exxon Research And Engineering Company | Heat transfer solids for high temperature fluidized bed reactions |
GB2306873A (en) * | 1995-10-26 | 1997-05-07 | Strix Ltd | Insulating heater substrate by electrostatic deposition |
GB2306873B (en) * | 1995-10-26 | 2000-06-21 | Strix Ltd | Manufacture of heaters |
EP0924738A1 (en) * | 1997-12-19 | 1999-06-23 | Matsushita Electronics Corporation | Methods of manufacturing heater and cathode-ray tube comprising the same |
US6294065B1 (en) | 1997-12-19 | 2001-09-25 | Matsushita Electric Industrial Co., Ltd. | Methods of manufacturing heater and cathode-ray tube comprising the same |
US6242854B1 (en) | 1998-01-20 | 2001-06-05 | Matsushita Electronics Corporation | Indirectly heated cathode for a CRT having high purity alumina insulating layer with limited amounts of Na OR Si |
EP2119672A1 (en) * | 2006-12-15 | 2009-11-18 | Nippon Light Metal Company, Ltd. | Process for producing high-purity -alumina |
EP2119672A4 (en) * | 2006-12-15 | 2013-08-14 | Nippon Light Metal Co | Process for producing high-purity -alumina |
US20150368117A1 (en) * | 2012-12-17 | 2015-12-24 | Polar Sapphire Ltd. | Process for making high purity aluminum oxide |
US9751775B2 (en) * | 2012-12-17 | 2017-09-05 | Polar Sapphire Ltd. | Process for making high purity aluminum oxide |
Also Published As
Publication number | Publication date |
---|---|
DE1071566B (en) | |
FR1115587A (en) | 1956-04-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4231893A (en) | Process for preparing aqueous dispersion of ceria and resulting product | |
US3761571A (en) | Production of ceria | |
GB802731A (en) | Improvements in or relating to ª‡-aluminium oxide | |
US2823134A (en) | Densifying magnesia | |
KR860007159A (en) | Neodymium Titanate or Barium Neodymium Titanate | |
JPH0323220A (en) | Preparation of white electrically- conductive zinc oxide | |
US3365314A (en) | Method of producing articles containing predominantly cordierite, anorthite, spinel and/or forsterite | |
ES256537A1 (en) | Silica-coated barium metaborate pigments and processes of producing the same | |
US2295104A (en) | Manufacture of normal lead trinitroresorcinate and double salts thereof | |
US3351436A (en) | Preparation of thorium pyrophosphate | |
JP2000185914A (en) | Production of barium carbonate and produced barium carbonate and barium titanate obtained from the barium carbonate | |
US2209907A (en) | Manufacture of pigments | |
US2525073A (en) | Magnesia-ceria and magnesiaberyllia catalysts | |
US3655339A (en) | Production of low-soda alumina | |
US2099019A (en) | Pigments and methods of making same | |
US2966406A (en) | Production of tungsten from tungsten oxides | |
US1312853A (en) | Clay-binder and process of making same. | |
Iida et al. | Sintering of High‐Purity Nickel Oxide, II | |
JPH0339968B2 (en) | ||
JPS6186421A (en) | Preparation of white electroconductive powder | |
YOE et al. | Gravimetric Determination of Tungsten With Anti-1, 5-di-(p-methoxyphenyl)-1-hydroxylamino-3-oximino-4-pentene | |
US2427682A (en) | Production of vitreous enamel opacifier | |
US3092452A (en) | Production of low-soda alumina | |
US2272480A (en) | Electric insulating material | |
SE311315B (en) |