GB799913A - Polymers and method of preparing the same - Google Patents
Polymers and method of preparing the sameInfo
- Publication number
- GB799913A GB799913A GB23346/56A GB2334656A GB799913A GB 799913 A GB799913 A GB 799913A GB 23346/56 A GB23346/56 A GB 23346/56A GB 2334656 A GB2334656 A GB 2334656A GB 799913 A GB799913 A GB 799913A
- Authority
- GB
- United Kingdom
- Prior art keywords
- butadiene
- vinyl
- polymerization
- solvent
- suspension
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/04—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/12—Esters of monocarboxylic acids with unsaturated alcohols containing three or more carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A coating composition comprises a polymer or copolymer of an alkenyl ester of a 3,4-epoxycyclohexane carboxylic acid (see Group IV (a)), a solvent such as methyl isobutyl ketone, xylene or toluene, and a pigment such as titanium dioxide, with or without a curing agent such as a polybasic organic or inorganic acid. The composition may be applied to surface of e.g. steel panels by dipping or spraying and heated to effect cross-linking.ALSO:Alkenyl esters of 3,4-epoxycyclohexane carboxylic acids may be polymerized alone or with a polymerizable monomeric material such as vinyl chloride, bromide, fluoride, acetate, butyrate, chloracetate, formate or caproate, acrylonitrile, methacrylonitrile, vinylidene chloride or fluoride, methyl acrylate or methacrylate, ethyl acrylate, 1,3-butadiene, isoprene, 2,3-dimethyl - 1,3 - butadiene, 1 - acetoxybutadiene, piperylene, 2-cyano-1,3-butadiene, 2-methoxy - 1,3 - butadiene, 2 - fluoro - 1,3-butadiene, acetylene or an acetylene derivative containing an acetylenic linkage, divinyl, diallyl or dimethallyl oxalate, maleate, malonate, citrate, tartrate, phthalate, isophthalate, terephthalate or naphthalene dicarboxylate, a vinyl, allyl or methallyl diether of ethylene glycol, trimethylene glycol, glycerol, mannitol or sorbitol, an acrylic or methacrylic polyester of ethylene glycol or vinyl triethoxy silane. Alkenyl esters specified are vinyl and allyl 3,4-epoxycyclohexane carboxylate and 3,4-epoxy-6-methylcyclohexane carboxylate. Polymerization may be effected in solution, emulsion, suspension or bulk, in the presence of a catalyst such as acetyl, benzoyl, lauroyl or benzoyl acetyl peroxide, tertiary-butyl or cumene hydroperoxide, tertiary-butyl perbenzoate or peracetate, potassium persulphate or azo bisisobutyronitrile. In solution polymerization the solvent may be acetone, tetrahydrofuran, dimethylformamide or benzene; in emulsion polymerization the emulsifying agent may be dioctyl sodium sulphosuccinate or sodium tetradecyl sulphate; in suspension polymerization the suspension agent may be hydroxy-ethyl cellulose. The polymers may be used for the production of floor coverings, wire coatings, plastic pipe, upholstery, raincoats, surface coatings and films. When producing a surface coating the polymer is dissolved in a solvent such as methyl isobutyl ketone, xylene or toluene with or without a curing agent such as a polybasic organic or inorganic acid and a pigment such as titanium dioxide, applied to the surface e.g. by dipping or spraying, and cross-linked by heating.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US799913XA | 1955-08-22 | 1955-08-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB799913A true GB799913A (en) | 1958-08-13 |
Family
ID=22154092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB23346/56A Expired GB799913A (en) | 1955-08-22 | 1956-07-27 | Polymers and method of preparing the same |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE550474A (en) |
| DE (1) | DE1061517B (en) |
| FR (1) | FR1164238A (en) |
| GB (1) | GB799913A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2314634A1 (en) * | 2008-08-08 | 2011-04-27 | Showa Denko K.K. | Epoxy-group-containing copolymer, epoxy (meth)acrylate copolymer using same, and processes for producing the copolymers |
| CN114524733A (en) * | 2022-01-26 | 2022-05-24 | 沈阳工业大学 | Water-soluble polyester monomer and preparation method and application thereof |
-
0
- BE BE550474D patent/BE550474A/xx unknown
-
1956
- 1956-07-27 GB GB23346/56A patent/GB799913A/en not_active Expired
- 1956-08-20 FR FR1164238D patent/FR1164238A/en not_active Expired
- 1956-08-21 DE DEU4081A patent/DE1061517B/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2314634A1 (en) * | 2008-08-08 | 2011-04-27 | Showa Denko K.K. | Epoxy-group-containing copolymer, epoxy (meth)acrylate copolymer using same, and processes for producing the copolymers |
| EP2314634A4 (en) * | 2008-08-08 | 2012-11-07 | Showa Denko Kk | Epoxy-group-containing copolymer, epoxy (meth)acrylate copolymer using same, and processes for producing the copolymers |
| CN114524733A (en) * | 2022-01-26 | 2022-05-24 | 沈阳工业大学 | Water-soluble polyester monomer and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1061517B (en) | 1959-07-16 |
| BE550474A (en) | |
| FR1164238A (en) | 1958-10-07 |
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