GB796006A - Improvements in unsaturated alkyd resins - Google Patents
Improvements in unsaturated alkyd resinsInfo
- Publication number
- GB796006A GB796006A GB26675/56A GB2667556A GB796006A GB 796006 A GB796006 A GB 796006A GB 26675/56 A GB26675/56 A GB 26675/56A GB 2667556 A GB2667556 A GB 2667556A GB 796006 A GB796006 A GB 796006A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- polyester
- styrene
- mixture
- olefinic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
A polymerizable or copolymerizable unsaturated polyester which is terminated at both ends of the molecule by groups of an allylic or methallylic monoester of a butenedioic acid containing 4-6 carbon atoms is made by (a) esterifying the monoallylic ester of the butenedioic acid with a hydroxy terminated linear polyester derived from a glycol, a non-olefinic dicarboxylic acid and, if desired, an olefinic dicarboxylic acid, at least 33 mol. per cent of the dibasic acid units in the final polyester being non-olefinic, or by (b) reacting 2 mols. of the mono-allylic ester of the butenedioic acid with a mixture of at least 2 mols. of a glycol and at least one mol. of at least one dicarboxylic acid, enough of said dicarboxylic acid being non-olefinic so that at least 33 mol. per cent of the dibasic acid units in the polyester are non-olefinic. In process (h) the mono-allyl ester may be made by reacting the anhydride of the butenedioic acid with the allyl or methallyl alcohol in presence of the non-olefinic dicarboxylic acid which acts merely as an inert diluent. The butendioic acid may be maleic, fumaric, citraconic, mesaconic, dimethyl maleic or ethyl maleic acid and the saturated dicarboxylic acid may be oxalic, malonic, succinic, glutaric, adipic, azelaic, sebacic, diglycolic, phthalic, isophthalic, terephthalic or naphthalene dicarboxylic acid. Reaction may be effected in presence of an azeotropic agent or an inhibitor (e.g. hydroquinone, quinone or p-tert.-butylcatechol). In examples: (1) a polyester made by heating a mixture of allyl alcohol and maleic anhydride in presence of adipic acid, followed by the addition of ethylene glycol and further heating was polymerized alone or with methyl methacrylate or styrene; (2) a polyester made by heating a mixture of mono-allyl maleate, succinic anhydride and ethylene glycol was polymerized either alone or with methyl methacrylate; (3) a polyester made by heating a mixture of mono-allyl maleate, phthalic anhydride and ethylene glycol was polymerized either alone or with styrene, diallyl phthalate or methyl methacrylate; (4) a polyester made by heating a mixture of maleic anhydride and allyl alcohol in presence of diglycolic acid followed by the addition of diethylene glycol and further heating was polymerised either alone or with styrene, diallyl phthalate or methyl methacrylate; (5) a polyester derived from adipic acid, maleic anhydride and ethylene glycol was heated with monoallyl maleate and the product polymerized alone or with styrene, diallyl phthalate or methyl methacrylate; (6) a polyester derived from adipic acid, phthalic anhydride, ethylene glycol and diethylene glycol was heated with monoallyl maleate and the product polymerized alone or with diallyl phthalate or styrene; (7) a polyester derived from adipic acid, phthalic anhydride, maleic anhydride, ethylene glycol and diethylene glycol was heated with mono-allyl maleate and the product polymerized alone or with diallyl phthalate or styrene. In all examples, the polymerization catalyst was a mixture of benzoyl peroxide and tricresyl phosphate.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US796006XA | 1955-11-07 | 1955-11-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB796006A true GB796006A (en) | 1958-06-04 |
Family
ID=22151571
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB26675/56A Expired GB796006A (en) | 1955-11-07 | 1956-08-31 | Improvements in unsaturated alkyd resins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB796006A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1199989B (en) * | 1958-06-16 | 1965-09-02 | Rohm & Haas | Process for the production of linear, high molecular weight, unsaturated block polyesters |
-
1956
- 1956-08-31 GB GB26675/56A patent/GB796006A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1199989B (en) * | 1958-06-16 | 1965-09-02 | Rohm & Haas | Process for the production of linear, high molecular weight, unsaturated block polyesters |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1022270A (en) | Improvements in or relating to polyester resins | |
US2467526A (en) | Curing of copolymers | |
US3221043A (en) | Ethylenically unsaturated dihydroxy diesters | |
US3619392A (en) | Process for the curing of molding and coating masses based on unsaturated polyesters and copolymerizable monomeric compounds by electron radiation and additionally containing phosphines, arsines and stibines | |
US2319799A (en) | Interpolymers of an unsaturated alkyd resin and a poly-(1-halogenoallyl) ester | |
GB780521A (en) | Improvements in or relating to copolymers of unsaturated polyesters | |
GB764463A (en) | Improvements relating to adhesive compositions | |
GB796006A (en) | Improvements in unsaturated alkyd resins | |
US2856378A (en) | Polymerizable unsaturated polyester resin compositions containing small amounts of certain saturated alkyd resins and process of preparing the same | |
GB861852A (en) | Compositions capable of hardening throughout at room temperature and containing condensation products of ª:ª-unsaturated compounds with methylol-aminotriazine allyl ethers | |
GB1241698A (en) | Process for the manufacture of unsaturated polyester resins | |
US2537375A (en) | Method of curing polyester resins | |
US3814724A (en) | Polymerizable liquid compositions for unsaturated polyester resins | |
US3163627A (en) | Modified polyester resins | |
GB914426A (en) | Solvent-resistant flexible polymerisation products on the basis of unsaturated polyester resins | |
US2822343A (en) | Ethylenically unsaturated polyester resinous compositions and the cure thereof in the presence of a catalytic promoter | |
US2445189A (en) | Polymerization of unsaturated compounds in the presence of a peroxide and a hydrogenhalide | |
US3176050A (en) | Fully curable unsaturated polyesters treated with allyl alcohol | |
GB658986A (en) | Improvements in or relating to resinous compositions | |
US3772406A (en) | Preparation of polyhalogenated polyesters from polyhalocyclopentadienes,carboxylic compounds and polyols or polyol forming materials | |
US3816561A (en) | Polyester compositions from transpiperylene-maleic acid adducts and hydrogenated bisphenol a | |
GB1082227A (en) | Process for preparation of polyester | |
GB708809A (en) | Improvements in the production of modified polyester resins | |
GB755321A (en) | Manufacture of copolymers | |
US2757158A (en) | Polyester resin compositions |