GB795775A - Copolymers and esters thereof - Google Patents

Copolymers and esters thereof

Info

Publication number
GB795775A
GB795775A GB2433255A GB2433255A GB795775A GB 795775 A GB795775 A GB 795775A GB 2433255 A GB2433255 A GB 2433255A GB 2433255 A GB2433255 A GB 2433255A GB 795775 A GB795775 A GB 795775A
Authority
GB
United Kingdom
Prior art keywords
acrylate
polymerization
ethyl
methyl
allyl glycidyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2433255A
Inventor
Richard Michael Ringwald
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2433255A priority Critical patent/GB795775A/en
Publication of GB795775A publication Critical patent/GB795775A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Copolymers of allyl glycidyl ether with at least one acrylate of the general formula CH2=C(R)COOR1, where R is hydrogen or methyl and R1 is an aliphatic or cycloaliphatic radical, are prepared by polymerization through the unsaturated bonds of the ether and ester, in the presence of a chain stopping agent such as turpentine, phellandrene, chloroform, bromobenzene and carbon tetrachloride. The acrylate may be methyl, ethyl, propyl, n-butyl, isobutyl, b -ethoxy-ethyl, nonyl, lauryl or cyclohexyl acrylate or methacrylate. Polymerization may be effected by adding the acrylate and chain-stopping agent in equal portions over a period of ten hours to refluxing allyl glycidyl ether through which air is blown. The copolymer may be esterified with a drying oil acid such as those obtained by the saponification of linseed, dehydrated castor, soya bean, tung, oiticica, perilla, tobacco seed, sunflower or marine animal oil, and the resulting esters may be used as filmforming vehicles in coating compositions. Specification 758,920 is referred to.
GB2433255A 1955-08-24 1955-08-24 Copolymers and esters thereof Expired GB795775A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2433255A GB795775A (en) 1955-08-24 1955-08-24 Copolymers and esters thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2433255A GB795775A (en) 1955-08-24 1955-08-24 Copolymers and esters thereof

Publications (1)

Publication Number Publication Date
GB795775A true GB795775A (en) 1958-05-28

Family

ID=10210046

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2433255A Expired GB795775A (en) 1955-08-24 1955-08-24 Copolymers and esters thereof

Country Status (1)

Country Link
GB (1) GB795775A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2304623A1 (en) * 1975-03-20 1976-10-15 Mitsui Toatsu Chemicals IMPROVEMENTS TO THE METHODS FOR CARRYING OUT THE CONTINUOUS PREPARATION OF COPOLYMERS ENHANCED WITH REACTIVITY

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2304623A1 (en) * 1975-03-20 1976-10-15 Mitsui Toatsu Chemicals IMPROVEMENTS TO THE METHODS FOR CARRYING OUT THE CONTINUOUS PREPARATION OF COPOLYMERS ENHANCED WITH REACTIVITY

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