GB793411A - Improvements in the production of alpha-chloroacrí¡í¡ acid esters - Google Patents

Improvements in the production of alpha-chloroacrí¡í¡ acid esters

Info

Publication number
GB793411A
GB793411A GB20963/56A GB2096356A GB793411A GB 793411 A GB793411 A GB 793411A GB 20963/56 A GB20963/56 A GB 20963/56A GB 2096356 A GB2096356 A GB 2096356A GB 793411 A GB793411 A GB 793411A
Authority
GB
United Kingdom
Prior art keywords
esters
alpha
activated carbon
dichloropropionic
butyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20963/56A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Badische Anilin and Sodafabrik AG filed Critical Badische Anilin and Sodafabrik AG
Publication of GB793411A publication Critical patent/GB793411A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/62Halogen-containing esters
    • C07C69/65Halogen-containing esters of unsaturated acids
    • C07C69/653Acrylic acid esters; Methacrylic acid esters; Haloacrylic acid esters; Halomethacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

The invention comprises a process for dehydrohalogenation of dichloropropionic esters containing at least one a -chlorine atom, by treating with salts of metals of the first sub-group to the 8th main group of the Periodic System, in the gas phase. In examples, methyl or butyl a -b -dichloro-propionates are passed over alumina impregnated with barium chloride, activated carbon with cupric chloride, kaolin, montmorillonite and activated carbon with barium chloride, to give methyl or butyl a -chloroacrylate. A list of other metal salts which may be used as catalyst on activated carbon is given, and other esters which may be used (including cycloalkyl and aralkyl esters) are specified. Silicates in the form of other clays are also mentioned, and mixtures thereof and with magnesium oxide. Alpha-alpha-dichloropropionic esters may also be used as starting-material.
GB20963/56A 1955-07-09 1956-07-06 Improvements in the production of alpha-chloroacrí¡í¡ acid esters Expired GB793411A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE793411X 1955-07-09

Publications (1)

Publication Number Publication Date
GB793411A true GB793411A (en) 1958-04-16

Family

ID=6709633

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20963/56A Expired GB793411A (en) 1955-07-09 1956-07-06 Improvements in the production of alpha-chloroacrí¡í¡ acid esters

Country Status (2)

Country Link
FR (1) FR1154634A (en)
GB (1) GB793411A (en)

Also Published As

Publication number Publication date
FR1154634A (en) 1958-04-14

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