GB793152A - Lubricant additives - Google Patents
Lubricant additivesInfo
- Publication number
- GB793152A GB793152A GB24812/56A GB2481256A GB793152A GB 793152 A GB793152 A GB 793152A GB 24812/56 A GB24812/56 A GB 24812/56A GB 2481256 A GB2481256 A GB 2481256A GB 793152 A GB793152 A GB 793152A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oils
- solution
- hydrocarbon
- hours
- kerosene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003879 lubricant additive Substances 0.000 title 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 11
- 150000002430 hydrocarbons Chemical class 0.000 abstract 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 10
- 239000003921 oil Substances 0.000 abstract 9
- 239000002904 solvent Substances 0.000 abstract 9
- 239000004215 Carbon black (E152) Substances 0.000 abstract 8
- 239000000203 mixture Substances 0.000 abstract 8
- -1 P2S3 Chemical compound 0.000 abstract 7
- 239000004411 aluminium Substances 0.000 abstract 7
- 229910052782 aluminium Inorganic materials 0.000 abstract 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 7
- 239000007795 chemical reaction product Substances 0.000 abstract 7
- 239000002480 mineral oil Substances 0.000 abstract 7
- 239000000047 product Substances 0.000 abstract 7
- 239000003350 kerosene Substances 0.000 abstract 6
- 235000010446 mineral oil Nutrition 0.000 abstract 5
- 229910052757 nitrogen Inorganic materials 0.000 abstract 5
- 229920002367 Polyisobutene Polymers 0.000 abstract 4
- 239000010688 mineral lubricating oil Substances 0.000 abstract 4
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 abstract 3
- VKCLPVFDVVKEKU-UHFFFAOYSA-N S=[P] Chemical compound S=[P] VKCLPVFDVVKEKU-UHFFFAOYSA-N 0.000 abstract 3
- 239000000654 additive Substances 0.000 abstract 3
- 150000001298 alcohols Chemical class 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 150000002148 esters Chemical class 0.000 abstract 3
- 125000002534 ethynyl group Chemical class [H]C#C* 0.000 abstract 3
- 239000000706 filtrate Substances 0.000 abstract 3
- 239000010687 lubricating oil Substances 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 229920000642 polymer Polymers 0.000 abstract 3
- 229920000098 polyolefin Polymers 0.000 abstract 3
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 125000003158 alcohol group Chemical group 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 238000007664 blowing Methods 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
- 239000003599 detergent Substances 0.000 abstract 2
- 150000001993 dienes Chemical class 0.000 abstract 2
- 239000010685 fatty oil Substances 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000011261 inert gas Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 239000003208 petroleum Substances 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 238000005292 vacuum distillation Methods 0.000 abstract 2
- LJKQIQSBHFNMDV-UHFFFAOYSA-N 7-thiabicyclo[4.1.0]hepta-2,4-dien-6-ol Chemical class C1=CC=CC2(O)C1S2 LJKQIQSBHFNMDV-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 241001465754 Metazoa Species 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 abstract 1
- 239000003245 coal Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000010730 cutting oil Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000003925 fat Substances 0.000 abstract 1
- 229940013317 fish oils Drugs 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 238000011010 flushing procedure Methods 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 125000004836 hexamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 abstract 1
- 150000003014 phosphoric acid esters Chemical class 0.000 abstract 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 abstract 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 abstract 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229920000151 polyglycol Polymers 0.000 abstract 1
- 239000010695 polyglycol Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000010734 process oil Substances 0.000 abstract 1
- 230000035484 reaction time Effects 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 150000003873 salicylate salts Chemical class 0.000 abstract 1
- 229920002545 silicone oil Polymers 0.000 abstract 1
- 239000010802 sludge Substances 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- 235000007586 terpenes Nutrition 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- 239000010723 turbine oil Substances 0.000 abstract 1
- 235000013311 vegetables Nutrition 0.000 abstract 1
- 239000001993 wax Substances 0.000 abstract 1
- 239000012991 xanthate Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/04—Reaction products of phosphorus sulfur compounds with hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
- C10M137/10—Thio derivatives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
- C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/104—Aromatic fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/108—Residual fractions, e.g. bright stocks
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/14—Synthetic waxes, e.g. polythene waxes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/17—Fisher Tropsch reaction products
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/20—Natural rubber; Natural resins
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/027—Neutral salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/08—Aldehydes; Ketones
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
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Abstract
The invention comprises the reaction products of a phosphosulphurized hydrocarbon and an aluminium alcoholate, the alcohol residues of which may be the same or different and are derived from aliphatic, preferably saturated, alcohols containing 1-20, preferably 3-8 carbon atoms. Suitable hydrocarbons are paraffins, olefins, olefin polymers with a molecular weight of 100 to 50,000, diolefins, acetylenes, aromatics, alkylaromatics, cycloaliphatics, araliphatics and petroleum fractions. Preferred hydrocarbon materials are isobutylene polymers having molecular weights in the range 100 to 50,000, preferably 250 to 10,000, and more preferably 500 to 2000, and refined mineral lubricating oil bright stocks, preferably those which have been deasphalted, solvent extracted or acid treated, dewaxed and filtered, having S.S.U. viscosities at 210 DEG F. in the range 100 to 200, preferably 130 to 170. Phosphosulphurization is carried out by reacting the hydrocarbon with a phosphorus sulphide, e.g. P2S3, P2S5, P4S7, &c., preferably P2S5, at a temperature of 200 DEG to 600 DEG F., preferably 300 DEG to 550 DEG F., using from 1 to 10, preferably 2 to 5, molecular proportions of hydrocarbon to 1 molecular proportion of phosphorus sulphide, and advantageously in an inert atmosphere. The reaction time is not critical and from 2 to 10 hours may be required. If desired, the product may be blown with steam, alcohol, ammonia or an amine at 200 DEG to 600 DEG F. to improve its odour. 1 to 2 mols. of phosphosulphurized hydrocarbon is reacted with each mol. of aluminium alcoholate at a temperature of 150-450 DEG F., preferably 200-350 DEG F., more preferably 275-325 DEG F., for 0.2 to 10 hours, preferably 2-6, more preferably 3-5 hours. The reaction may be carried out in a solvent such as a mineral lubricating oil, preferably in such proportions as to form a composition containing 25 to 75 per cent active ingredient (reaction product). If desired the by-product alcohol may be removed, e.g. by blowing with an inert gas, or vacuum distillation. The products are added to lubricating and other oils, greases, hydraulic fluids and the like (see Group III). In an example: polyisobutylene (M.W. 1100) is heated with P2S5 at 425 DEG F. for 10 hours in a stream of nitrogen, the mixture cooled to 350 DEG F., a solvent extracted paraffinic mineral oil distillate added and the solution filtered; the filtrate is mixed with a solution of aluminium amylate in kerosene and the mixture heated to 300 DEG F. for 3 hours, nitrogen being blown through the solution during this period to remove amyl alcohol and kerosene.ALSO:Lubricating oil compositions contain the reaction products of a phosphosulphurized hydrocarbon and an aluminium alcoholate, the alcohol residues of which may be the same or different and are derived from aliphatic, preferably saturated, alcohols containing 1-20 carbon atoms. Suitable hydrocarbons are paraffins, olefins, olefin polymers, diolefins, acetylenes, aromatics, alkylaromatics, cycloaliphatics, araliphatics and petroleum fractions. Preferred hydrocarbon materials are isobutylene polymers and refined mineral lubricating oil bright stocks. (For preparation of the reaction products see Group IV (b)). The reaction products may be added to lubricating oils as detergents and inhibitors in proportions of 0.01 to 20 per cent by weight or more. It is convenient to prepare a concentrated oil solution containing 25 to 50 per cent by weight of additive. Other detergent additives may be present such as metal soaps, sulphonates, phenates, alcoholates, alkylphenol sulphides, organo phosphates, thiophosphates, phosphites, thiophisphites, salicylates, xanthates, thioxanthates, and thiocarbamates; amines; reaction products of metal phenates and sulphur or phosphorus sulphides; metal phenol sulphonates; phenols; phenol sulphides. Suitable oil base stocks include mineral oils, blends of animal, vegetable or fish oils or their hydrogenated or voltolized products with mineral oils and synthetic oils such as esters and complex esters, polyethers, polymerized olefines, oxo products, coal hydrogenation products, halocarbon oils (e.g. polychlorotrifluoroethylene), silicone oils, phosphate esters, sulphite esters, carbonate esters, mercaptals, formals, and polyglycols. Other agents may be present such as dyes, pour depressors; heat thickened fatty oils; sulphurized fatty oils; organo-metallic compounds; sludge dispersers; anti-oxidants; thickeners; viscosity index improvers; oiliness agents; resins; rubber; olefin polymers; volatolized fats; minerals oils and/or waxes; and colloidal solids such as graphite and zinc oxide; also solvents and assisting agents such as esters, ketones, alcohols, aldehydes and halogenated or nitrated compounds. The reaction products may be used in cutting oils, flushing oils, turbine oils, transformer oils, industrial oils, process oils and gear lubricants and greases. In an example: polyisobutylene (M.W. 1100) is heated with P2S5, a solvent extracted paraffinic mineral oil distillate added and the solution filtered; the filtrate is mixed with a solution of aluminium amylate in kerosene and the mixture heated to 300 DEG F., nitrogen being blown through the solution during heating to remove amyl alcohol and kerosene; the filtered product is blended with a mixture of approximately 75 per cent of a solvent extracted neutral mineral oil and 25 per cent of a solvent extracted mineral oil bright stock.ALSO:Oil-soluble lubricating oil additives are made by heating 1 to 2 mols. of a phospho-sulphurized hydrocarbon with 1 mol. of an aluminium alcoholate derived from aliphatic alcohols containing 1 to 20 carbon atoms. Suitable hydrocarbons are the polymers of ethylene, propylene, butylene, isobutylene, n- and iso-amylenes, 2-methyl- and 2-ethyl-butene-1 and hexenes, copolymers thereof and with butadiene, isoprene, chloroprene, cyclopentadiene,2,3-dimethylbutadiene, pentadiene-1,3, hexadienes-1,4 and -2,4,terpenes and acetylene. Polyisobutylenes having molecular weights of 100 to 50,000 are preferred. The reaction is carried out at 150-450 DEG F., e.g. in a solvent such as a mineral lubricating oil. The product may be purified by blowing with an inert gas at elevated temperature or by vacuum distillation. In the example polyisobutylene is heated with P2S5 at 425 DEG F. for 10 hours under nitrogen, the mixture cooled to 350 DEG F., a solvent extracted paraffinic mineral oil distillate added and the solution filtered. The filtrate is heated with a solution of aluminium amylate in kerosene at 300 DEG F. for 3 hours, nitrogen being blown through the solution to remove amyl alcohol or kerosene.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US537278A US2929828A (en) | 1955-09-28 | 1955-09-28 | Lubricant additives |
Publications (1)
Publication Number | Publication Date |
---|---|
GB793152A true GB793152A (en) | 1958-04-09 |
Family
ID=24141983
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB24812/56A Expired GB793152A (en) | 1955-09-28 | 1956-08-14 | Lubricant additives |
Country Status (4)
Country | Link |
---|---|
US (1) | US2929828A (en) |
DE (1) | DE1128423B (en) |
FR (1) | FR1158893A (en) |
GB (1) | GB793152A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1166191B (en) * | 1960-04-07 | 1964-03-26 | Kalk Chemische Fabrik Gmbh | Process for the preparation of metal complexes of dialkyldithiophosphines |
DE1137732B (en) * | 1960-04-23 | 1962-10-11 | Kalk Chemische Fabrik Gmbh | Process for the preparation of metal complexes of dialkyldithiophosphines |
CN113136256A (en) * | 2021-04-09 | 2021-07-20 | 西安航天动力试验技术研究所 | Coal-based anti-wear hydraulic oil and preparation method thereof |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2274302A (en) * | 1940-01-22 | 1942-02-24 | Standard Oil Co | Compounded oil |
US2422585A (en) * | 1944-05-08 | 1947-06-17 | Standard Oil Co | Lubricant |
US2427272A (en) * | 1944-05-18 | 1947-09-09 | Socony Vacuum Oil Co Inc | Mineral oil composition |
US2506570A (en) * | 1945-10-05 | 1950-05-09 | Socony Vacuum Oil Co Inc | Lubricating oil compositions |
NL75832C (en) * | 1949-04-23 | |||
DE843852C (en) * | 1950-08-06 | 1952-07-14 | Basf Ag | Process for the preparation of sulfur and phosphorus containing lubricating oil improvers |
US2688013A (en) * | 1950-11-04 | 1954-08-31 | Continental Oil Co | Light metal thiocyanate derivatives of phosphor-sulfurized aliphatic hydrocarbons |
US2724725A (en) * | 1954-01-26 | 1955-11-22 | Lubrizol Corp | Preparation of phosphinothioic halides from phosphinodithioic acids and hydrogen halides |
-
1955
- 1955-09-28 US US537278A patent/US2929828A/en not_active Expired - Lifetime
-
1956
- 1956-08-14 GB GB24812/56A patent/GB793152A/en not_active Expired
- 1956-09-08 DE DEE12929A patent/DE1128423B/en active Pending
- 1956-09-27 FR FR1158893D patent/FR1158893A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1128423B (en) | 1962-04-26 |
US2929828A (en) | 1960-03-22 |
FR1158893A (en) | 1958-06-20 |
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