GB791667A - Method of producing electrically conductive and transparent layers on insulating bodies - Google Patents

Method of producing electrically conductive and transparent layers on insulating bodies

Info

Publication number
GB791667A
GB791667A GB27895/55A GB2789555A GB791667A GB 791667 A GB791667 A GB 791667A GB 27895/55 A GB27895/55 A GB 27895/55A GB 2789555 A GB2789555 A GB 2789555A GB 791667 A GB791667 A GB 791667A
Authority
GB
United Kingdom
Prior art keywords
coated
pict
electrodes
nozzle
iii
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27895/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
STC PLC
Original Assignee
Standard Telephone and Cables PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Telephone and Cables PLC filed Critical Standard Telephone and Cables PLC
Publication of GB791667A publication Critical patent/GB791667A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/04Coating on selected surface areas, e.g. using masks
    • C23C16/045Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23Oxides
    • C03C17/245Oxides by deposition from the vapour phase
    • C03C17/2453Coating containing SnO2
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/04Coating on selected surface areas, e.g. using masks
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40Oxides
    • C23C16/407Oxides of zinc, germanium, cadmium, indium, tin, thallium or bismuth
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors

Landscapes

  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Vessels And Coating Films For Discharge Lamps (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

Electrically conductive, optically transparent layers of tin oxide are deposited on an insulating base by thermal decomposition of vapours of tin tetra or dichloride in the presence of air, the thickness and distribution of the layer being controlled by the distribution and intensity of the heating to which the insulating body is subjected. As shown in Fig. 1, a glass bulb 1 is <PICT:0791667/III/1> <PICT:0791667/III/2> <PICT:0791667/III/3> <PICT:0791667/III/4> surrounded by an annular heat radiator 4 and SnCl4 vapour, preferably in a nitrogenous atmosphere is supplied through a nozzle 3 and removed by suction at 2. Air is drawn in around the nozzle 3. A uniform layer 5 corresponding to the area of the radiating body 4 is deposited on the bulb. According to Fig. 2, the bulb is heated by a heat radiator 4 and a mask 6 is interposed between the heater and the object to be coated whereby the deposit 5 is formed opposite the hole in the mask. The mask 6 may be cooled by liquids. In Fig. 3, a spiral heating filament enclosed in a tubular insulating body is passed around a tube 1 which is supplied by SnCl4 or SnCl2 from a nozzle 3 whereby a helical coating is formed on the inside wall of the tube 1. Similarly by arranging a heat radiating body of predetermined shape adjacent the object to be coated a predetermined distribution of layer thickness may be obtained. The body to be coated may be heated by di-electric heating as shown in Fig. 5 where the container 8 is fed with tin tetrachloride vapours through nozzle 3, and the body 1 to be coated is placed between two electrodes 7 supplied with high-frequency voltage. Depending on the shape of the electrodes or the relative movement of the body thereto, layers of different shape and thickness may be obtained. The arrangement may also be adapted to record variations in high-frequency energy by causing relative movement between the electrodes and the body to be coated whereby the variations are reproduced in the form of variations in the conductive layer. The conductive layers may be formed on the walls of electric discharge tubes to avoid wall charges or to obtain electrical screening, or to coat cathode-ray or tuning-indicator tubes, for the manufacture of helices or attenuator coatings for travelling wave tubes, for the manufacture of high power electrical resistors, particularly inside discharge tubes, to provide voltage supply to electrodes in electric discharge tubes and to establish electrical connections of elements of an electric circuit arranged on an insulating plate.
GB27895/55A 1954-10-01 1955-09-30 Method of producing electrically conductive and transparent layers on insulating bodies Expired GB791667A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1954L0020049 DE1072052B (en) 1954-10-01 1954-10-01 Process for the production of electrically conductive and transparent layers on glass bodies

Publications (1)

Publication Number Publication Date
GB791667A true GB791667A (en) 1958-03-05

Family

ID=6704753

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27895/55A Expired GB791667A (en) 1954-10-01 1955-09-30 Method of producing electrically conductive and transparent layers on insulating bodies

Country Status (2)

Country Link
DE (1) DE1072052B (en)
GB (1) GB791667A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3113039A (en) * 1959-08-05 1963-12-03 Landis & Gyr Ag Method of producing coatings on heatresisting supports

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4389970A (en) * 1981-03-16 1983-06-28 Energy Conversion Devices, Inc. Apparatus for regulating substrate temperature in a continuous plasma deposition process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3113039A (en) * 1959-08-05 1963-12-03 Landis & Gyr Ag Method of producing coatings on heatresisting supports

Also Published As

Publication number Publication date
DE1072052B (en) 1959-12-24

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